全文获取类型
收费全文 | 1227篇 |
免费 | 82篇 |
国内免费 | 457篇 |
专业分类
安全科学 | 90篇 |
废物处理 | 55篇 |
环保管理 | 107篇 |
综合类 | 734篇 |
基础理论 | 200篇 |
污染及防治 | 411篇 |
评价与监测 | 78篇 |
社会与环境 | 43篇 |
灾害及防治 | 48篇 |
出版年
2024年 | 1篇 |
2023年 | 17篇 |
2022年 | 42篇 |
2021年 | 38篇 |
2020年 | 33篇 |
2019年 | 33篇 |
2018年 | 43篇 |
2017年 | 58篇 |
2016年 | 58篇 |
2015年 | 82篇 |
2014年 | 108篇 |
2013年 | 121篇 |
2012年 | 105篇 |
2011年 | 105篇 |
2010年 | 104篇 |
2009年 | 67篇 |
2008年 | 71篇 |
2007年 | 69篇 |
2006年 | 73篇 |
2005年 | 42篇 |
2004年 | 46篇 |
2003年 | 44篇 |
2002年 | 53篇 |
2001年 | 53篇 |
2000年 | 49篇 |
1999年 | 45篇 |
1998年 | 48篇 |
1997年 | 44篇 |
1996年 | 25篇 |
1995年 | 23篇 |
1994年 | 21篇 |
1993年 | 14篇 |
1992年 | 13篇 |
1991年 | 3篇 |
1990年 | 4篇 |
1989年 | 2篇 |
1988年 | 2篇 |
1987年 | 1篇 |
1986年 | 2篇 |
1985年 | 1篇 |
1984年 | 2篇 |
1981年 | 1篇 |
排序方式: 共有1766条查询结果,搜索用时 328 毫秒
101.
102.
介质阻挡放电联合催化臭氧化降解甲苯 总被引:4,自引:2,他引:2
采用介质阻挡放电区后结合MnOx/Al2O3/发泡镍去除甲苯,考察甲苯进气方式、臭氧产生方法及湿度对甲苯与O3同时去除的影响。结果表明,O3是等离子体区后催化降解甲苯的主要物种,介质阻挡放电联合催化臭氧化可实现甲苯及O3的同时高效去除。输入电压为9.0 kV时,甲苯的去除效率达92.8%,在80 min内O3的去除效率维持在99%以上。水蒸气对催化剂催化分解臭氧的活性没有直接的影响,O3浓度较高时湿度对甲苯降解效率的影响很小。GC-MS分析结果表明,甲苯降解的主要气相副产物有烷烃、酸、酮和含苯环有机物,提出了甲苯的降解途径。 相似文献
103.
Characteristic, composition, and sources of TSP investigated by HRTEM/EDS and ESEM/EDS 总被引:1,自引:0,他引:1
Zhai Y Fu Z Wang L Zeng G Li C Chen H Lan Y Lu P 《Environmental monitoring and assessment》2012,184(11):6693-6707
Total suspended particle (TSP) collected at the fifth floor of House Dust in Hunan University, China, was analyzed in terms of microscopic morphology and chemical composition. The fine particles (50?nm-2?μm) in the TSP were analyzed by a high-resolution transmission electron microscope equipped with an energy-dispersive X-ray analyzer (HRTEM/EDS). Results showed that the particles were in shapes of plate, irregular and agglomerate. Based on EDS results, these fine particulate matter was primarily composed of Fe-rich (35.82-61.29%), Ca-rich (30.18-36.77%) and Si-rich (18.95-32.28%) particles. Other elements mainly including Mg (0.47-4.97%), Al (0.45-14.57%), S (0.45-4.73%), K (1.13-2.13%) and Zn (0.67-3.85%) were also observed. The sources analysis indicated that the HRTEM particles mainly originated from coal combustion, traffic emission, vehicles exhaust emission and fugitive soil or cement particulate matter. The coarse particles (4-50?μm) were detected by environmental scanning electron microscopy coupled with energy-dispersive X-ray detector (ESEM/EDS). Based on a simple algorithm, ESEM particles were categorized into five groups: C-bearing (46.15%, 67% and 86.98%), Si + Ca-bearing (21.48?+?11.80%, 16.51?+?10.81% and 16.32?+?10.62%), Si + Al-bearing (20.06?+?12.40%, 20.16?+?11.22% and 15.31?+?11.25%), Si-bearing (34.40%, 26.92% and 27.15%) particles and aggregates, most of which exhibit obvious crystalline structure, and these ESEM particles mainly derived from vehicles exhaust emission, coal combustion, soil, and biomass burning, while the aggregates are indicative of atmospheric reaction progress. HRTEM/EDS and ESEM/EDS are mutual complementary in analyzing the characteristic and determining the sources of TSP. 相似文献
104.
A new direct thermal desorption-GC/MS method: Organic speciation of ambient particulate matter collected in Golden, BC 总被引:1,自引:0,他引:1
Luyi C. Ding Fu Ke Daniel K.W. Wang Tom Dann Claire C. Austin 《Atmospheric environment (Oxford, England : 1994)》2009,43(32):4894-4902
Particulate matter having an aerodynamic diameter less than 2.5 μm (PM2.5) is thought to be implicated in a number of medical conditions, including cancer, rheumatoid arthritis, heart attack, and aging. However, very little chemical speciation data is available for the organic fraction of ambient aerosols. A new direct thermal desorption-gas chromatography/mass spectrometry (TD-GC/MS) method was developed for the analysis of the organic fraction of PM2.5. Samples were collected in Golden, British Columbia, over a 15-month period. n-Alkanes constituted 33–98% by mass of the organic compounds identified. PAHs accounted for 1–65% and biomarkers (hopanes and steranes) 1–8% of the organic mass. Annual mean concentrations were: n-alkanes (0.07–1.55 ng m−3), 16 PAHs (0.02–1.83 ng m−3), and biomarkers (0.02–0.18 ng m−3). Daily levels of these organics were 4.89–74.38 ng m−3, 0.27–100.24 ng m−3, 0.14–4.39 ng m−3, respectively. Ratios of organic carbon to elemental carbon (OC/EC) and trends over time were similar to those observed for PM2.5. There was no clear seasonal variation in the distribution of petroleum biomarkers, but elevated levels of other organic species were observed during the winter. Strong correlations between PAHs and EC, and between petroleum biomarkers and EC, suggest a common emission source – most likely motor vehicles and space heating. 相似文献
105.
Songjun Guo Sheng Wen Xinming Wang Guoying Sheng Jiamo Fu Ping Hu Yingxin Yu 《Atmospheric environment (Oxford, England : 1994)》2009,43(22-23):3489-3495
Formaldehyde and acetaldehyde are two most abundant carbonyls in ambient air. Biogenic emission has been proposed as a significant source other than anthropogenic emissions and atmospheric secondary formation. Here at a forest site in South China, the carbon isotopic compositions of formaldehyde and acetaldehyde emitted from leaves of three tree species (Litsea rotundifolia, Canarium album and Castanea henryi) were measured in comparison with the bulk carbon isotopic compositions of tree leaves. δ13C data of the emitted aldehydes (from ?31‰ to ?46‰) were quite different for tree species, which were all more depleted in 13C than the tree-leaf bulk δ13C values (from ?27‰ to ?32‰). Formaldehyde in ambient air at the forest site had δ13C values different from those of leaf-emitted formaldehyde, indicating other sources for ambient formaldehyde apart from direct emission from leaves, most probably the photooxidation of biogenic hydrocarbon like isoprene and monoterpene. The δ13C differences of acetaldehyde between ambient data and those of tree leaves emission were less than 1‰, implying direct biogenic emission as the dominant source. 相似文献
106.
Qinsong Xu Han Qiu Weiyue Chu Yongyang Fu Sanjuan Cai Haili Min Sha Sha 《Environmental science and pollution research international》2013,20(12):8672-8679
Laboratory experiments were conducted to investigate copper (Cu) subcellular distribution and toxicity in Hydrilla verticillata. Fronds were subjected to different concentrations (15, 75, and 150 μM) of Cu for 7 days. Cu grains were found in cell walls, plasmodesmata, and within the nuclei and chloroplasts using the autometallographic technique. Subcellular fractionation of Cu-containing tissues indicated that in leaves subjected to high Cu concentrations, 59–65 % of the element was located in the cell wall fraction, followed by cell organelles (21–30 %) and the soluble fraction (10–14 %). The levels of K, P, Zn, and Mg declined under all Cu concentrations, but Ca, Mn, and Fe contents reached their peak at 15 μM Cu and decreased thereafter. F v/F m, F 0, and F m fell significantly in line with the decrease in pigment content. Cu exposure also caused significant damage to the chloroplasts, mitochondria, and nuclei, including disintegration of the chloroplasts and vacuolization of the mitochondria and nuclei, all of which suggested that Cu hastened plant senescence. The Cu maximum permissible concentration for H. verticillata was 10 μM, which was less than the existing general water quality standard. This suggested that H. verticillata could be used to assess Cu phytotoxicity. 相似文献
107.
镍的作物效应及临界值研究 总被引:11,自引:0,他引:11
在三种紫色土(酸性,中性,石灰性)上添加Ni(0,10,30,60,100,200mg/kg土)进行莴笋盆栽试验,结果表明:低浓度的Ni能刺激作物生长,而高浓度的Ni则阻碍作物生长,使叶片黄化。三种土因性质及本身肥力水平的差异,使酸性紫色土上作物Ni最敏感,石灰性紫色土上次之,中性紫色土上最不敏感,且Ni在作物体内分配规律也有所不同,比较了土壤全Ni,有效Ni,植株根Ni作为的临界值的优越性,结果 相似文献
108.
中国生态农业与绿色食品 总被引:8,自引:0,他引:8
本文从农业环境问题和食品安全性出发,阐述了中国生态农业的兴起及特点,绿色食品生产的要求,生态农业与绿色食品的关系。介绍了几种可用于开发绿色食品的优化生态模式。 相似文献
109.
对1224个工种(岗位)的工人接触生产性毒物、粉尘、高温的状况以及部分工种(岗位)的工人体力劳动强度状况进行了调研,初步了解到机械工业的主要职业危害因素、危害分布、危害程度和特征。 相似文献
110.
五氯酚对环境污染及居民健康影响研究 总被引:2,自引:0,他引:2
中国长期以来使用五氯酚纳盐杀灭亡血吸虫的中间宿主──—钉螺.为评价它对环境的污染及居民健康危害,1990-1993年在我省开展了五氯酚环境污染及对居民健康影响研究.在研究区采集环境样品(空气、水体、土壤及底泥、蔬菜、肉、蛋、鱼等)共173份;生物材料(人血、尿)共457份,分析五氯酚浓度.结果在明,在五氯酚使用区,环境中PCP浓度稍高于对照区,而生物材料尿、血中PCP浓度明显高于对照区.全血胆碱脂酶活性用药区明显低于对照区,统计学分析有显著差异(P<0.001),证实了长期低剂量使用可造成环境及生物蓄积. 相似文献