Effects of arsenic on nitrate metabolism in arsenic hyperaccumulating and non-hyperaccumulating ferns

This study investigated the effects of arsenic on the in vitro activities of the enzymes (nitrate reductase and nitrite reductase) involved in nitrate metabolism in the roots, rhizomes, and fronds of four-month old Pteris vittata (arsenic – hyperaccumulator) and Pteris ensiformis (non-arsenic--hyperaccumulator) plants. The arsenic treatments (0, 150, and 300 μM as sodium arsenate) in hydroponics had adverse effects on the root and frond dry weights, and this effect was more evident in P. ensiformis than in P. vittata. Nitrate reductase and nitrite reductase activities of arsenate-treated plants were reduced more in P. ensiformis than in P. vittata. This effect was accompanied by similar decreases in tissue NO₃^? concentrations. Therefore, this decrease is interpreted as being indirect, i.e., the consequence of the reduced NO₃^? uptake and translocation in the plants. The study shows the difference in the tolerance level of the two Pteris species with varying sensitivity to arsenic.     

A Time-Dependent System for Evaluating Groundwater Contamination Hazard Rating of Municipal Solid Waste Dumps

In developing countries, several old municipal solid waste dumps (unlined landfills) exist adjacent to large cities, releasing contaminants to the underlying aquifer, thus posing the hazard of groundwater contamination. These uncontrolled waste dumps need to be prioritized in terms of the groundwater contamination hazard posed by them, so that necessary control and remedial measures can be undertaken in a phased manner. This paper presents a time-dependent system for evaluating groundwater contamination hazard rating of municipal solid waste dumps. The system is based on source–pathway–receptor relationships and evaluates the relative value of hazard posed by a site over its entire leaching life, on a scale of 0–1,000. The system parameters have been selected based on literature and expert opinions. The Delphi technique is used to derive the relative importance weights of the system parameters. The proposed system is compared with six selected existing hazard rating systems. The comparison, made by way of score range analysis, shows that the proposed system exhibits a much wider range of hazard scores for various scenarios of site conditions, and hence the proposed system is more sensitive to varied site conditions. The application of different systems to six municipal solid waste dumps located in four cities of India shows that, whereas the existing systems individually produce clustered scores and return the same rank to more than one site, the proposed system produces significantly varying scores and return different ranks to different sites. This demonstrates that the proposed system improves decision making and makes a better basis for prioritization of municipal solid waste dumps for adopting control and remedial measures.     

Soil adsorption studies of a rice herbicide,cyhalofop-butyl,in two texturally different soils of India

The ability of herbicides to be adsorbed by the soil and sediment and their tendency to be desorbed are some of the most important factors affecting soil and water contamination. Therefore, a sorption study was conducted to evaluate the adsorption of cyhalofop-butyl, butyl (2R)-2-[4-(4-cyano-2-fluorophenoxy) phenoxy] propanoate, in the sandy clay loam and clayey soils using a batch equilibrium method. The adsorption of cyhalofop-butyl was found positively related with the clay and organic carbon content. Freundlich constants (K _f) of cyhalofop-butyl in the clayey and sandy clay loam were found to be 13.39 and 2.21, respectively. Sorption coefficients (K _oc) and distribution coefficients (K _d) were found to be 265.38 and 2,092.79, and 1.38 and 11.48, for sandy clay loam and clayey soils, respectively. The adsorption isotherm suggested a relatively higher affinity of cyhalofop-butyl to the adsorption sites at low equilibrium concentrations. The low value of the soil organic carbon partition coefficient (K _oc) of cyhalofop-butyl in the sandy loam soil suggested its weaker adsorption in soil and thus increased its risk of mobility into water sources; hence, it should be used judiciously to prevent groundwater contamination     

Monitoring changes in soil organic carbon pools, nitrogen, phosphorus, and sulfur under different agricultural management practices in the tropics

Soil organic matter not only affects sustainability of agricultural ecosystems, but also extremely important in maintaining overall quality of environment as soil contains a significant part of global carbon stock. Hence, we attempted to assess the influence of different tillage and nutrient management practices on various stabilized and active soil organic carbon pools, and their contribution to the extractable nitrogen phosphorus and sulfur. Our study confined to the assessment of impact of agricultural management practices on the soil organic carbon pools and extractable nutrients under three important cropping systems, viz. soybean–wheat, maize–wheat, and rice–wheat. Results indicated that there was marginal improvement in Walkley and Black content in soil under integrated and organic nutrient management treatments in soybean–wheat, maize–wheat, and rice–wheat after completion of four cropping cycles. Improvement in stabilized pools of soil organic carbon (SOC) was not proportional to the applied amount of organic manures. While, labile pools of SOC were increased with the increase in amount of added manures. Apparently, green manure (Sesbania) was more effective in enhancing the lability of SOC as compared to farmyard manure and crop residues. The KMnO₄-oxidizable SOC proved to be more sensitive and consistent as an index of labile pool of SOC compared to microbial biomass carbon. Under different cropping sequences, labile fractions of soil organic carbon exerted consistent positive effect on the extractable nitrogen, phosphorus, and sulfur in soil.     

210-Polonium studies in some environmental and biological matrices of Domiasiat uranium deposit area, West Khasi Hills, Meghalaya, India

The study was performed using a silicon surface barrier alpha spectrometer at Bhabha Atomic Research Centre, Mumbai, India. Through the study, the observed ²¹⁰Po activity in water sample from different locations in the Domiasiat area ranges from 0.04 to 0.69 Bq/l. The daily and annual intake of ²¹⁰Po through water was also estimated and the mean value of 0.72 and 263.61 Bq, respectively, were observed. It is observed that the effective doses through water were higher than the World Health Organization recommended dose of 0.05 mSv/year. The total annual effective doses through terrestrial ingestion for all the locations was studied and the mean annual effective dose was observed to be 0.315 mSv, which, when compared to the worldwide and the Indian values, was observed to be slightly higher. The mean activity in soil is found to be 124.8 ±5.7 Bq/kg and in meat the activity is 0.43 ±0.05 Bq/kg. In fishes, an activity of 0.48 ±0.07 Bq/kg in Garra lamta, 0.29 ±0.02 Bq/kg in Neolissocheilus hexaganolepis, and 3.3 ±0.1 Bq/kg in Macrobrachium sp. is observed. Activity concentration in plant samples was analyzed and the activity ranges from 0.020 ±0.002 to 9.69 ±0.35 Bq/kg. Committed effective dose by the adult population of the Domiasiat area through intake of ²¹⁰Po through these food items was also determined and compared with the Indian average value and the worldwide average value.     

Effectiveness of the Local Adaptation Plan of Action to support climate change adaptation in Nepal

A key challenge in climate change adaptation in developing countries as a whole, and to handling global change in particular, is to link local adaptation needs on the one hand, with national adaptation initiatives on the other, so that vulnerable households and communities can directly benefit. This study assesses the impact of the Nepal government’s efforts to promote its Local Adaptation Plan of Action (LAPA) and its applicability to other least developed countries (LDCs). Based on data gathered from two field studies in Nepal, the research shows that the Nepal’s LAPA has succeeded in mobilizing local institutions and community groups in adaptation planning and recognizing their role in adaptation. However, the LAPA approach and implementation have been constrained by sociostructural and governance barriers that have failed to successfully integrate local adaptation needs in local planning and increase the adaptive capacity of vulnerable households. This paper describes the mechanisms of suitable governance strategies for climate change adaptation specific to Nepal and other LDCs. It also argues the need to adopt an adaptive comanagement approach, where the government and all stakeholders identify common local- and national-level mainstreaming strategy for knowledge management, resource mobilization, and institutional development, ultimately using adaptation as a tool to handle global change.     

Value addition of vegetable wastes by solid-state fermentation using Aspergillus niger for use in aquafeed industry

Vegetable waste typically has high moisture content and high levels of protein, vitamins and minerals. Its value as an agricultural feed can be enhanced through solid-state fermentation (SSF). Two experiments were conducted to evaluate the nutritional status of the products derived by SSF of a mixture of dried vegetable waste powder and oil cake mixture (soybean flour, wheat flour, groundnut oil cake and sesame oil cake at 4:3:2:1 ratio) using fungi Aspergillus niger S₁4, a mangrove isolate, and A. niger NCIM 616. Fermentation was carried out for 9 days at 35% moisture level and neutral pH. Significant (p < 0.05) increase in crude protein and amino acids were obtained in both the trials. The crude fat and crude fibre content showed significant reduction at the end of fermentation. Nitrogen free extract (NFE) showed a gradual decrease during the fermentation process. The results of the study suggest that the fermented product obtained on days 6 and 9 in case of A. niger S₁4 and A. niger NCIM 616 respectively contained the highest levels of crude protein.     

Effects of Regional Reductions in Sulphur Deposition on the Chemical and Biological Recovery of Lakes within Killarney Park, Ontario, Canada

The lakes in KillarneyProvincial Park, located 40–60 km southwest ofSudbury, Ontario, were some of the first lakesin North America to be acidified by atmosphericpollutants. Acidification affected thousandsof fish and invertebrate populations in dozensof lakes. Since the 1970's, water quality hasimproved in response to atmospheric pollutionreductions and some lakes have alreadyrecovered to approximately their pre-industrialpH levels, as inferred from diatom microfossilsin lake sediments. Since the 1970's, fishspecies richness has not changed substantially,but zooplankton species richness has increasedin acidified lakes. The critical sulphur load,the amount of SO₂-derived acid depositionthat can occur while still maintaining suitable water quality, was estimated to beexceeded in 38% of the park area in 1997. Depending on which of four possible NorthAmerican emission control scenarios (CLR =currently legislated reduction; CLR + 25%; CLR+ 50%; CLR + 75%) is achieved by 2010, theprojected critical loads will be exceeded inabout 0-30% of the park area in the future. There are many factors that can affectbiological recovery rates of damaged lakes, butit is expected that biological recovery willlag considerably behind observed chemicalrecovery rates.     

酸沉降作用的降低和安大略省基拉尼湖泊的化学恢复

毗邻加拿大安大略省萨德伯里市的基拉尼公园中的湖泊都表现出明显的水质变化,其中包括pH值和碱度的普遍增加,SO2- 4、碱基阳离子和金属浓度的减少.经过数十年的改善,尽管一些湖泊的pH值已经大于6,但仍有许多湖泊的湖水酸度却一直很高.过去,萨德伯里金属冶炼厂排放引起的过高的硫沉降左右了这一地区的酸化过程.然而,自从冶炼厂的硫排放被严格控制之后(排放量降低了90%),萨德伯里地区的硫排放就不再是该地区最主要的硫沉降源了.目前,基拉尼地区的SO2- 4湿沉降和湖水中SO2- 4浓度已经十分接近约200km外的安大略省多赛特地区,这就表明基拉尼地区的硫沉降现在主要来自于长距离传输,而不是当地污染源.对基拉尼湖泊的研究揭示了化学恢复过程的复杂本质.一旦湖水的酸度降低,就会引起一系列的变化,包括Ca2+浓度的减少,透明度增加和热力学状态改变.这些变化可能会潜在地影响一些生态体系.因此很明显需要对基拉尼湖泊的恢复在多胁迫因子的框架内继续进行评价.     

Corrosion and polarization behavior of carbon steel in MEA-based CO2 capture process

This work reveals levels of corrosion rate and polarization behavior of carbon steel immersed in aqueous solutions of monoethanolamine (MEA) used in the absorption-based carbon dioxide (CO₂) capture process for greenhouse gas reduction from industrial flue gas streams. Such information was obtained from electrochemical-based corrosion experiments under a wide range of the CO₂ capture process conditions. The corrosion of carbon steel was evaluated in respect to process parameters including partial pressure of oxygen (O₂), CO₂ loading in solution, solution velocity, solution temperature, MEA concentration and metal surface condition. Results show that the aqueous MEA solution containing CO₂ provides a favorable condition for the corrosion of carbon steel to proceed. Corrosion rate is increased by all tested process parameters. These parametric effects were explained by the electrochemical kinetic data obtained from polarization curves and by the thermodynamic data obtained from Pourbaix diagram.