Sorption mechanisms of cephapirin, a veterinary antibiotic, onto quartz and feldspar minerals as detected by Raman spectroscopy

Raman spectroscopy was used to investigate sorption mechanisms of cephapirin (CHP), a veterinary antibiotic, onto quartz (SiO₂) and feldspar (KAlSi₃O₈) at different pH. Sorption occurs by electrostatic attraction, monodentate and bidentate complexation. The zwitterion (CHP^o) adsorbs to a quartz⁽⁺⁾ surface by electrostatic attraction of the carboxylate anion group (-COO⁻) at low pH, but adsorbs to a quartz⁽⁻⁾ surface through electrostatic attraction of the pyridinium cation, and possibly COO⁻ bridge complexes, at higher pH. CHP⁻ bonds to quartz⁽⁻⁾ surfaces by bidentate complexation between one oxygen of -COO⁻ and oxygen from carbonyl of an acetoxymethyl group. On a feldspar^(+/−) surface, CHP^o forms monodentate complexes between CO, and possible -COO⁻ bridges and/or electrostatic attachments to localized edge (hydr)oxy-Al surfaces. CHP⁻ adsorbs to feldspar⁽⁻⁾ through monodentate CO complexation. Similar mechanisms may operate for other cephalosporins. Results demonstrate, for the first time, that Raman techniques can be effective for evaluating sorption mechanisms of antibiotics.     

Isolation and identification of an anti-algal compound from Artemisia annua and mechanisms of inhibitory effect on algae

The goals of this work were to isolate and identify an anti-algal compound from extracts of Artemisia annua and study its mode of action on Microcystis aeruginosa. The anti-algal compound was isolated from the extracts using column chromatography and activity-guided fractionation methods. Artemisinin with strong anti-algal activity was identified by gas chromatography-mass spectrometry and ¹H Nuclear Magnetic Resonance. The EC₅₀ of artemisinin on M. aeruginosa was 3.2 mg L⁻¹. Artemisinin decreased the soluble protein content and increased the superoxide dismutase activity and ascorbic acid content of M. aeruginosa, but exerted no effect on soluble sugar content. The results suggested the mode of action of artemisinin on algae may primarily be the increasing level of reactive oxygen species in algae cells. The results of our research could aid in the development of new anti-algal substances and lead to further study of mechanisms of inhibitory effect on algae.     

土壤环境质量标准在工程应用中的局限性分析

为贯彻落实《中华人民共和国环境保护法》,加强建设用地土壤环境监管,管控污染地块对人体健康的风险,保障人居环境安全,生态环保部组织相关部门编制了土壤环境质量标准,并于2018年8月1日起开始实施。在标准实施的过程和应用过程中发现新发布的标准存在一些局限性。本文以土壤污染机理为基础,结合现行的治理技术,论述土壤质量标准在时间、空间及应用中的局限性。     

合成碳羟基磷灰石对水中双酚A的吸附性能研究

利用废弃蛋壳为原料、尿素为添加剂，合成纳米碳羟基磷灰石(CHAP)用于吸附水中双酚A（BPA）。利用红外光谱、扫描电镜和X射线能谱测试技术对CHAP样品表面化学进行了表征，同时考察了环境因子pH值、吸附时间和BPA初始浓度对吸附的影响。实验结果表明，CHAP对BPA去除率在酸性（pH=3～6）溶液中较好，而在中性和碱性环境中减弱。通过静态吸附实验数据计算分析得知，CHAP对BPA吸附符合Langmuir和Freundlich等温式，准二级动力学模型比准一级动力学模型能更好地描述CHAP对BPA吸附动力学行为。     

VA菌根菌与植物的抗病性

VA菌根菌（VAM菌）与植物土传病害的关系受到广泛的研究。本文从VAM菌对植物抗病性的影响及其可能性机理和相应的农业管理措施等方面进行了介绍和评述,同时提出问题和展望，并强调该方面的研究在可持续发展农业中的重要性。     

The interaction mechanisms of co-existing polybrominated diphenyl ethers and engineered nanoparticles in environmental waters:A critical review

This review focuses on the occurrence and interactions of engineered nanoparticles(ENPs)and brominated flame retardants(BFRs) such as polybrominated diphenyl ethers(PBDEs)in water systems and the generation of highly complex compounds in the environment.The release of ENPs and BFRs(e.g. PBDEs) to aquatic environments during their usage and disposal are summarised together with their key interaction mechanisms. The major interaction mechanisms including electrostatic, van der Waals, hydrophobic, ...     

准市场条件下的水权交易双层动态博弈定价机制实证研究

在经济新常态背景下,水资源的准公共产品特征具有更加重要的管理价值,如何依托市场与行政的两手发力,提升我国水资源管理水平,更好地服务于"两个百年"奋斗目标,具有十分重要的理论与现实意义。水权交易制度是利用市场与行政手段提高水资源利用率,解决人水冲突的重要技术手段,如何在准市场条件下构建符合我国国情的水权交易定价机制已成为实现水权交易制度的核心技术。因此,针对政府-企业-公众等多利益相关者参与下的水权交易定价问题,本文引入生态经济学理论构建了水权价值测度模型,进而引入合作博弈理论,构建了准市场条件下的水权交易双层动态博弈定价模型,主要包括买方政府和卖方政府的微分博弈模型,以及买方政府与水务公司的Nash-Bargaining合作定价模型,运用HJB条件求解多利益相关者合作框架下的水权交易均衡水价空间,进而以江西省萍乡市水权交易实践为例开展实证研究,结果表明:均衡水价主要受上级政府协调能力k、水量需求系数β影响,且均为正相关,针对萍乡实践而言,由于水量需求主要体现在中长期发展规划阶段,上级政府协调能力显著性强于水量需求系数;均衡水价随着上级政府协调能力k值增大呈现由快转慢再转快的趋势,整体服从逻辑函数分布,均衡水价随着水量需求系数β的增大呈现由快转慢趋势,整体服从对数函数分布,针对萍乡实践而言,水权交易中市场与行政力量的两手发力存在稳定状态,二者缺一不可;随着议价能力系数提高,Nash-Bargaining的水权交易价格随之升高,表明政府与公司之间的合作关系对水价具有直接的影响能力。     

中国工业点源水排污许可证制度框架设计

水排污许可证制度是点源排放的基本和综合的管理制度,是污染源的守法文件,也是政府对污染源的监管文书。按照政策设计的一般方法,借鉴发达国家和地区的经验,以保障点源的"连续达标排放"为目标设计中国工业点源水排污许可证制度框架。提出将点源按排放规模进行分类和分级,建立相应的管理机制,包括信息机制、资金机制、监督核查机制和问责处罚机制;建立注册环境管理工程师制度以满足实施排污许可证对专业人才的需求;以排污许可证制度为基础整合点源排放相关政策,提高相关政策间的协调,减少冲突,提高政策效率。     

三氯杀螨醇的雌激素效应及其机制的研究进展

三氯杀螨醇(dicofol，DCF)是现代农牧业生产中广泛使用的一种杀虫剂，许多实验证据表明它对动物和人体有雌激素效应，如导致美洲鳄(Alligator mississippiensis)发生雌性化现象、使美洲鹰(Falco sparverius)的卵壳变薄、引起小鼠子宫增重、促进人类乳癌细胞(MCF7)增殖等。有关它的作用机制研究目前主要集中在下丘肛-垂体-性腺轴中的激素受体上，本文对DCF的雌激素效应及其作用机制研究进展做了回顾。     

The ecohealth system and the community engagement movement in foundations: A case study of mutual benefits from grants funded by the United Nations Foundation

Ecohealth is a process for identifying key environmental determinants causing mortality or morbidity and combating them by mobilizing multiple social sectors. Evolving out of the concept of environmental health, ecohealth provides a framework for long‐term sustainability. The health outcomes anticipated by environmental interventions are part of a long‐term agenda and require fundamental groundwork for the growth of community‐driven development. Building long‐term sustainability requires that two key approaches be developed through ecohealth. The first is the strengthening of local community institutions, whether formal or informal. The second is building financial mechanisms that are more diversified and less reliant on a single donor. As a result, the ecohealth system provides an opportunity for foundations to empower communities, build cross‐cutting cooperation, and gain knowledge through projects. If people's environmental behaviour is to change and be sustained in the long term to produce desired health outcomes, this will require all members of society to be capable of functioning within the existing institutional infrastructure. This means that not only do formal institutions need to become more accessible but also that concepts relating to local informal institutions must be incorporated into ecohealth projects. It is imperative that we identify and understand relevant local institutions and how they can be transformed so that new environmental forms of behaviour can be sustained and result in positive health outcomes. The intersection of environmental and health concerns provides an ideal area in which the gap between government and civil society can be bridged — not only providing solutions to ecohealth concerns, but building government capacity in general and making these positive changes sustainable in the long term. This article is a case study, based on several United Nations Foundation grants. It outlines the significance of traditional community organizations, the breadth of their long‐term relations with communities, their resources, and the adoption of sustained forms of behaviour. In addition, the article highlights the role that international foundations can play in creating innovative financing mechanisms through community‐based foundations.