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21.
研究了恒磁场对酪氨酸酶(TYR)活性及其催化降解酚类有机物的影响.结果显示,不同磁场强度(10~350 mT)处理下TYR酶活性均有提高,最佳磁场强度150mT下酶活力提高了27.1%.不同磁化时间下TYR酶活都有上升,但磁化60min后酶活上升幅度有所下降.酶经磁场处理后对温度、pH值稳定性增强,在温度为20~35 ℃、pH为5.0~10.0时均能保持较高活性,最佳温度为25℃,最佳pH为7.0;磁化后TYR酶的Michaelis常数Km为3.83 mmol·L-1,未磁化的Michaelis常数Km为2.65 mmol·L-1.磁场作用可促进TYR对酚类有机物邻苯二酚、苯酚、2,4-二氯酚的转化,反应速度依次递减,磁化处理对邻苯二酚反应的促进作用尤其明显;磁化处理后的酶对不同浓度苯酚和2,4-二氯酚的去除率均明显高于未磁化处理的酶,且随着酶用量增加,酚去除率提高.荧光发射光谱分析表明,磁化酪氨酸酶的荧光强度增强,构像发生了变化. 相似文献
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上海市大气气溶胶中铂元素污染状况调查 总被引:3,自引:0,他引:3
为调查上海市大气气溶胶中铂元素的污染状况,用PM10-2型可吸入颗粒物采样器采集了上海市大气气溶胶样品,采样时间分别为2003-12~2005-12.用微波消解密闭系统消解样品,电感耦合等离子体质谱法(ICP-MS)测定了大气气溶胶中Pt的含量.分析结果表明,同清洁对照点((0.65±0.16)pg·m-3)相比,上海市中心区大气中Pt((1.69±0.93)pg·m-3)的污染是明显的;装有三元催化转化器的汽车尾气中Pt的含量均在100ng·g-1以上,远远高于大气气溶胶样品(人民广场平均值21.7ng·g-1);不同交通密度区Pt含量分析结果表明,Pt含量与交通密度紧密相关,这说明装有三元催化器的汽车尾气是气溶胶中Pt污染的主要来源;此外,上海市大气气溶胶中Pt呈现季节性变化,并受气象条件影响.同世界其它城市相比,上海市气溶胶中铂元素污染程度还较低,但是这种潜在的重金属污染应该引起重视. 相似文献
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本法用Ag/S离子选择电极测定废水中的硫化物,测定浓度范围0.1~1000.0mg/l,方法精密度为4.3%,回收率为P2.5%,检出限为0.1mg/l。大多数离子不干扰测定,该法简便快速,适用于例行监测。 相似文献
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用催化吸附 KMnO4溶液吸收化合净化法处理稀土荧光灯生产过程中含汞废气 ,经该工艺处理 ,排放的净化气低于GB162 97 1996《大气污染物综合排放标准》中汞污染物排放标准 相似文献
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IntroductionInaquaticecosystemsbiologicalcommunitiesareremarkablycomplexinboththeiroperationandresponsetoanthropogenicactivities.Thishasledmanyinvestigatorstoconductlaboratoryandfieldstudiesforevaluatingtheecologicalriskposedbyhumanstoecosystem(Cairns… 相似文献
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《环境科学学报(英文版)》2023,35(3):388-400
Removing large concentrations of organic pollutants from water efficiently and quickly under visible light is essential to developing photocatalytic technology and improving solar energy efficiency. This study used a simple hydrothermal method to prepare a non-metallic, S-doped NaTaO3 (S-NTO) photocatalyst, which was then loaded onto biochar (BC) to form a S-NTO/BC composite photocatalyst. After uniform loading onto BC, the S-NTO particles transformed from cubic to spherical. The photogenerated electron-hole pair recombination probability of the composite photocatalyst was significantly lower than those of the NTO particles. The light absorption range of the catalyst was effectively widened from 310 nm UV region to visible region. In addition, a dual-effect catalytic system was constructed by introducing peroxymonosulfate (PMS) into the environment of the pollution to be degraded. The Rhodamine B, Methyl Orange, Acid Orange 7, tetracycline, and ciprofloxacin degradation efficiency at 40 mg/L reached 99.6%, 99.2%, 84.5%, 67.1%, and 70.7%, respectively, after irradiation by a 40 W lamps for 90 min. The high-efficiency visible-light catalytic activity of the dual-effect catalytic system was attributed to doping with non-metallic sulfur and loading of catalysts onto BC. The development of this dual-effect catalytic system provides new ideas for quickly and efficiently solving the problem of high-concentration organic pollution in aqueous environments, rationally and fully utilizing solar energy, and expanding the application of photocatalytic technology to practice. 相似文献
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The feasibility of decomplexation removal of typical contaminants in electroplating wastewater, complexed Cu(II) with 1-hydroxyethylidene-1,1-diphosphonic acid (Cu-HEDP), was first performed by a three-dimensional electric
reactor with activated biochar as particle electrodes. For the case of 50 mg/L Cu-HEDP, Cu(II) removal (90.7%) and PO
initial pH 7, acid-treated almond shell biochar (AASB) addition 20 g/L, and reaction time 180 min, with second-order rate constants of 1.10 × 10−3 and 1.94 × 10−5 min−1respectively. The growing chelating effect between Cu(II) and HEDP and the comprehensive actions of adsorptive accumulation, direct and indirect oxidation given by particle electrodes accounted for the enhanced removal of Cu-HEDP, even though the mineralization of HEDP was mainly dependent on anode oxidation. The performance attenuation of AASB particle electrodes was ascribed to the excessive consumption of oxygen-containing functionalities during the reaction, especially acidic carboxylic groups and quinones on particle electrodes, which decreased from 446.74 to 291.48 µmol/g, and 377.55 to 247.71 µmol/g, respectively. Based on the determination of adsorption behavior and indirect electrochemical oxidation mediated by in situ electrogenerated H2O2 and reactive oxygen species (e.g., •OH), a possible removal mechanism of Cu-HEDP by three-dimensional electrolysis was further proposed. 相似文献