Isomeric analysis of PCDD/PCDF in waste incinerator fly ash by GC-MS/MS

The development of an analytical method for the analysis of PCDD/PCDF in flyash using a bench analytical system comprising of a gas chromatograph fitted with an ion trap detector operated in the tandem MS mode is described. The optimum settings for the most important MS/MS parameters are given, including those for the less reported mono- to tri-chlorinated dioxin and furan congener groups. Flyash samples from three waste incineration plants representing a decommissioned 1970s plant design, an upgraded and still operating plant originally designed in the 1970s, and a modern 1990s design operating plant have been analysed for PCDD/PCDF. The flyash samples were analysed for PCDD/PCDF using the methods developed and the total PCDD/PCDF, I-TEQ values and isomeric profiles are reported. The flyash from the older decommissioned incinerator had very significantly higher concentrations of PCDD/PCDF compared to the modern incinerator flyash.     

Sorption of organic compounds to activated carbons. Evaluation of isotherm models

Sorption to ‘hard carbon’ (black carbon, coal, kerogen) in soils and sediments is of major importance for risk assessment of organic pollutants. We argue that activated carbon (AC) may be considered a model sorbent for hard carbon. Here, we evaluate six sorption models on a literature dataset for sorption of 12 compounds onto 12 ACs and one charcoal, at different temperatures (79 isotherms in total). A statistical analysis, accounting for differences in the number of fitting parameters, demonstrates that the dual Langmuir equation is in general superior and/or preferable to the single and triple Langmuir equation, the Freundlich equation, a Polanyi–Dubinin–Manes equation, and the Toth equation. Consequently, the analysis suggests the presence of two types of adsorption sites: a high-energy (HE) type of site and a low-energy (LE) type of site. Maximum adsorption capacities for the HE domain decreased with temperature while those for the LE domain increased. Average Gibbs free energies for adsorption from the hypothetical pure liquid state at 298 K were fairly constant at −15 ± 4 and −5 ± 4 kJ mol⁻¹ for the HE and LE domain, respectively.     

Determination and distribution characteristics of degradation products of nonylphenol polyethoxylates in the rivers of Taiwan

Concentrations of degradation products of nonylphenol polyethoxylates (NPEOs) were analyzed in river water samples in order to determine the distribution characteristic of these alkylphenolic compounds in 18 major rivers of Taiwan. The degradation products of NPEOs were detected in all river samples, with the dicarboxylates alkylphenolic degradation products (CAPEC) being detected most frequently and at the highest concentrations. Concentrations of NP and NP1EO in rivers ranged from n.d. to 5.1 μg l⁻¹ and n.d. to 0.5 μg l⁻¹, respectively. The total concentrations of shortened carboxylates (i.e., NP1EC + NP2EC + NP3EC) and dicarboxylates alkylphenolic degradation products (CAP1EC + CAP2EC) ranged from n.d. to 63.6 μg l⁻¹ and n.d. to 94.6 μg l⁻¹, respectively. Concentrations of NP2EC, NP3EC and all CAPEC residues were determined semi-quantitatively by comparing with the internal standard. Significantly higher concentrations of CAPEC residues were detected in the river waters as compared to those of NP, NP1EO and NPEC degradation products and the average proportions of these compounds in the samples of the rivers were as follows: NP + NP1EO was 5 ± 2.5%, total NPEC was 25 ± 12%, and total CAPEC was 70 ± 12%. The high concentration ratios of CAPEC/NPEC illustrate that aerobic biodegradation plays a main route in the fate of NPEO in the rivers of Taiwan.     

Characterization of polycyclic aromatic hydrocarbons in urban stormwater runoff flowing into the tidal Anacostia River, Washington, DC, USA

To investigate the sources, fate, and transport dynamics of PAHs (polycyclic aromatic hydrocarbons) in stormwater runoff that is a leading source of pollution in urban watersheds, storm and base flow samples were collected in six branches along the lower Anacostia River. PAHs in storm flow (1510-12,500 ng/L) were significantly enriched in the particle phase, which accounted for 68-97% of the total PAHs. It suggests that reducing particles in stormwater using post-treatment system would decrease PAHs considerably. The solid-water distribution coefficients (KD) of PAHs in the storm flow samples were up to 340 times higher than predicted values. A greater portion of high molecular weight PAHs and their distribution patterns indicate higher contribution of automobile originated pyrogenic PAHs. Total suspended solids in storm flow had a positive relationship with flow rates and exceeded benchmark level for the protection of aquatic biota in some samples.     

A new and integrated hydro-economic accounting and analytical framework for water resources: a case study for North China

Water is a critical issue in China for a variety of reasons. China is poor of water resources with 2300m(3) of per capita availability, which is less than 13 of the world average. This is exacerbated by regional differences; e.g. North China's water availability is only about 271m(3) of per capita value, which is only 125 of the world's average. Furthermore, pollution contributes to water scarcity and is a major source for diseases, particularly for the poor. The Ministry of Hydrology [1997. China's Regional Water Bullets. Water Resource and Hydro-power Publishing House, Beijing, China] reports that about 65-80% of rivers in North China no longer support any economic activities. Previous studies have emphasized the amount of water withdrawn but rarely take water quality into consideration. The quality of the return flows usually changes; the water quality being lower than the water flows that entered the production process initially. It is especially important to measure the impacts of wastewater to the hydro-ecosystem. Thus, water consumption should not only account for the amount of water inputs but also the amount of water contaminated in the hydro-ecosystem by the discharged wastewater. In this paper we present a new accounting and analytical approach based on economic input-output modelling combined with a mass balanced hydrological model that links interactions in the economic system with interactions in the hydrological system. We thus follow the tradition of integrated economic-ecologic input-output modelling. Our hydro-economic accounting framework and analysis tool allows tracking water consumption on the input side, water pollution leaving the economic system and water flows passing through the hydrological system thus enabling us to deal with water resources of different qualities. Following this method, the results illustrate that North China requires 96% of its annual available water, including both water inputs for the economy and contaminated water that is ineligible for any uses.     

Comparison of community composition and species diversity of understorey and overstorey tree species in a dry tropical forest of northern India

The study focuses on understorey-overstorey plant community dynamics in a dry tropical forest to facilitate appropriate management decisions. We compare community composition and species diversity of the understorey vegetation among five dry tropical forest sites in northern India. A total of 1500 quadrats distributed over 15 one-ha permanent plots in five sites differing in the degree of disturbance, were used to enumerate the understorey tree species and the results were compared with overstorey tree layer. The non-metric multidimensional scaling (NMS) ordination revealed that human disturbance intensity, as well as the overall disturbance regimes, and soil water holding capacity controlled the organisation of dry tropical forest understorey composition through effects on soil organic matter. The alpha-diversity and its components decreased with increasing human disturbance intensity, reflecting utilisation pressure and decreased soil fertility, as also revealed by the analysis of overstorey tree layer. There was a significant positive relationship between overstorey and understorey diversity. Results suggest that in the future, the existing understorey tree communities may replace the current dry tropical forest communities under prevailing environmental conditions. The study also asserts that the rate of species accumulation will be greater in more disturbed sites as well as at small spatial scale within each disturbance level.     

Effect of cycle time on biodegradation of azo dye in sequencing batch reactor

The effects of cycle time on the biodegradation of the azo dye remazol brilliant violet 5R (RBV-5R) were investigated in an anaerobic–aerobic sequencing batch reactor (SBR). System performance was determined by monitoring chemical oxygen demand (COD), color, anaerobic enzyme (azo reductase) and aerobic enzyme (catechol 2,3-dioxygenase), and aromatic amine concentration. SBR was operated in three different total cycle times (48 h, 24 h and 12 h), fed with a synthetic textile wastewater. In this study, the anaerobic period of SBR was found to allow the reductive decolorization of azo dye and the aerobic period was found to be effective on further COD removal after the anaerobic period. The percentage reductions in color by the anaerobic stage of the SBR were at 72%, 89% and 86% for the 24-h, 12-h and 6-h cycle times, respectively. Total COD removal efficiencies were over 75% for all operational conditions and about 70% of the COD removal was achieved in the first 3 h of anaerobic stages. During the decolorization of RBV-5R, two sulfonated aromatic amines (benzene-based and naphthalene-based) were formed and detected by HPLC. Aerobic phases of SBR with total cycle times of 48 h, 24 h and 12 h were able to remove benzene-based aromatic amines with removal efficiency of 64%, 92% and 89%, respectively. The results indicated that the best SBR performance in terms of color removal and aromatic amine degradation was achieved from total cycle time of 24 h.     

Model-Based Assessment of Aspen Responses to Elk Herbivory in Rocky Mountain National Park,USA

In Rocky Mountain National Park (RMNP), aspen (Populus tremuloides Michx.) has been observed to be declining on elk (Cervus elaphus nelsoni) winter range for many decades. To support elk management decisions, the SAVANNA ecosystem model was adapted to explore interactions between elk herbivory and aspen dynamics. The simulated probability of successful vegetative regeneration for senescent aspen stands declines sharply when elk densities reach levels of 3–5 elk/km², depending on model assumptions for the seasonal duration of elk foraging activities. For aspen stands with a substantial component of younger trees, the simulated regeneration probability declines more continuously with increasing elk density, dropping below 50% from densities at 8–14 elk/km².At the landscape scale, simulated aspen regeneration probability under a scenario of extensive seasonal use was little affected by elk population level, when this level was above 300–600 elk (25%–50% current population) over the ca. 107 km² winter range. This was because elk distribution was highly aggregated, so that a high density of elk occupied certain areas, even at low population levels overall. At approximately current elk population levels (1000–1200 elk), only 35%–45% of senescent aspen stands are simulated as having at least a 90% probability of regeneration, nearly all of them located on the periphery of the winter range. Successful management for aspen persistence on core winter range will likely require some combination of elk population reduction, management of elk distribution, and fencing to protect aspen suckers from elk browsing.     

UNIT HYDROGRAPHS DERWED FROM THE NASH MODEL1

ABSTRACT: Unit hydrograph ordinates are often estimated by deconvoluting excess rainfall pulses and corresponding direct runoff. The resulting ordinates are given at discrete times spaced evenly at intervals equal to the duration of the rainfall pulse. If the new duration is not a multiple of the parent duration, hydrograph interpolation is required. Linear interpolation, piece-wise nonlinear interpolation and graphical smoothing have been used. These interpolation schemes are expedient but they lack theoretical basis and can lead to undesirable results. Interpolation can be avoided if the instantaneous unit hydrograph (IUH) for the watershed is known. Here two issues connected with the classic Nash IUH are examined: (1) how should the Nash parameters be estimated? and (2) under what conditions is the resulting hydrograph able to reasonably represent watershed response? In the first case, nonlinear constrained optimization provides better estimates of the IUH parameters than does the method of moments. In the second case, the Nash IUH gives good results on watersheds with mild shape unit hydrographs, but performs poorly on watersheds having sharply peaked unit hydrographs. Overall, in comparison to empirical interpolation alternatives, the Nash IUH offers a theoretically sound and practical approach to estimate unit hydrographs for a wide variety of watersheds.     

Development of a Model for Simulation of Solute Transport in a Stream–Aquifer System

A model for simulation of solute transport in a dynamic stream–aquifer system is developed by integrating four existing sub-models. Interface packages are created to link the sub-models. The developed model is successfully used to simulate chloride transport in the stream–aquifer system of the Arkansas River and the Equus Beds Aquifer in Kansas and demonstrates that chloride concentration in the aquifer decreases in the vicinity of the simulated channel over time.