清洁生产理论基础

重点分析了清洁生产的物流基础、价值基础、经济基础,并与末端治理对比,从而论证了清洁生产是实现经济效益和环境效益的最佳模式,是实现可持续发展的必然选择。     

How do transformational leaders foster positive employee outcomes? A self‐determination‐based analysis of employees' needs as mediating links

Although followers' needs are a central aspect of transformational leadership theory, little is known about their role as mediating mechanisms for this leadership style. The present research thus seeks to integrate and extend theorizing on transformational leadership and self‐determination. In particular, we propose that the satisfaction of followers' basic needs (autonomy, competence, and relatedness) mediates the relationship between transformational leadership and employee outcomes (job satisfaction, self‐efficacy, and commitment to the leader). We tested this model in two studies involving employees from a broad spectrum of organizations in Germany (N = 410) and in Switzerland (N = 442). Results revealed largely consistent patterns across both studies. The need for competence fulfillment solely mediated the link between transformational leadership and occupational self‐efficacy; the need for relatedness fulfillment solely mediated the link between transformational leadership and commitment to the leader. The mediating pattern for the link between transformational leadership and job satisfaction varied slightly across studies. In Study 1, only the need for autonomy fulfillment was a significant mediator, whereas in Study 2, all three needs mediated this relationship. Taken together, our study integrates theorizing on transformational leadership and self‐determination by corroborating that need fulfillment indeed is a central mechanism behind transformational leadership. Copyright © 2012 John Wiley & Sons, Ltd.     

Prediction of minimum ignition energy of aerosols using flame kernel modeling combined with flame front propagation theory

Flammable aerosols have created many fire and explosion hazards in the process industry, but the flammability of aerosols has not been fully understood. The minimum ignition energy has been widely used as an indicator for flammability of combustible mixtures, but the amount of experimental data on the minimum ignition energy of aerosols is very limited. In this work, the minimum ignition energy of tetralin aerosols is predicted using an integrated model. The model applies the flame front propagation theory in aerosol systems to the growth of the flame kernel, which was created during the spark discharge in the ignition process. The aerosol minimum ignition energy was defined as the minimum level of energy in the initial flame kernel to maintain the kernel temperature above the minimum ignition temperature of 1073 K specific for tetralin aerosols during the kernel growth. The minimum ignition energy obtained in the model is influenced by the fuel-air equivalence ratio and the size of the aerosol droplets. For tetralin aerosols of 40 μm diameter, E_min decreases significantly from 0.32 mJ to 4.3 × 10 e⁻³ mJ when the equivalence ratio rises from 0.57 to 1.0. For tetralin aerosols of 0.57 equivalence ratio, E_min increases from as 0.09 mJ to 0.32 mJ when the droplet diameter rises from 10 μm to 60 μm. The trends are in agreement with previous experimental observations. The method used in current work has the potential to prediction of the minimum ignition energy of aerosol.     

基于证据理论的煤矿瓦斯涌出组合预测

为提高煤矿瓦斯涌出量预测的准确度,引入证据理论组合预测方法。根据瓦斯涌出量及其主要影响因素间的实验数据,采用3个不同的粒子群神经网络模型对涌出量进行初步预测。并由BP、RBF网络对预测误差及预测点的影响因素进行分析建模,以获取每个模型的可信度。再利用证据理论对其进行合成,确定组合模型的权值,最终实现对瓦斯涌出量的组合预测。实例结果表明,该组合预测方法的平均绝对误差、均方误差分别为18.5%、5.8%,均小于神经网络组合法及等权平均法的相应预测误差,适用于煤矿瓦斯涌出量预测。     

基于熵权物元可拓模型的隧道瓦斯等级评价

为准确预测穿越煤层的隧道瓦斯等级,以有助于降低隧道施工过程中瓦斯事故的风险。通过分析国内外大量瓦斯隧道工程案例,选取地层岩性、地质构造、煤层厚度、隧道埋深、水文地质条件等5个分级指标作为隧道瓦斯等级评价指标,将熵权法引入可拓学理论中,建立熵权物元可拓模型,并应用该模型对10条穿越煤层的隧道进行瓦斯等级评价。结果表明:应用该模型得到的隧道瓦斯等级与其实际等级完全吻合,准确率达到100%。     

基于尺寸效应的采空区危险度RS-TOPSIS法辨识

为准确预测地下采空区危险性,选用采空区结构的跨度、暴露面积、高度、埋深、矿柱尺寸布置等5个采空区危险度结构尺寸影响因素作为评价指标,建立采空区危险度粗糙集-逼近理想解排序法(RS-TOPSIS)综合评价体系。基于粗糙集理论(RS)中的粗糙依赖度,通过计算评价指标与评价等级间的粗糙依赖度得到指标权重。以40个采空区探测系统(CMS)实测采空区作为评价对象,根据单指标分类区间下限构造5个不同等级的典型采空区,结合逼近理想解的排序法(TOPSIS),实现采空区危险度5级贴近度的分类,并辨识实测采空区危险度。研究结果表明,用为采空区群矿山建立的采空区危险度基于结构尺寸效应的RS-TOPSIS法,能够实现危险度5级分类辨识,辨识结果与采空区危险度数值分析结果吻合度为92.5%。     

城市安全生产影响因素及其预测分析——以上海为例

为研究我国城市安全生产的影响因素及预测城市安全生产的发展趋势,以上海市为例,对2004—2010年期间与安全生产相关的数据进行灰色关联度分析,提取影响安全生产状况的主要经济社会因素,并与工矿商贸死亡人数之间建立回归模型。研究结果表明,工矿商贸死亡人数与第二产业比重、GDP增长率、教育支出占GDP比重以及私营及个体工商户比例均呈现负相关。基于2007—2011年各月份上海市的安全生产死亡人数,运用Winters乘法模型,预测上海市安全生产发展趋势。     

基于三角模糊理论的尾矿库风险评价研究

根据尾矿库的特点和我国现行的尾矿库安全生产监督管理法律法规及标准规范的要求,构建了尾矿库风险评价指标体系。综合考虑评价指标对风险发生可能性及后果严重程度的不同影响来确定指标权重,同时考虑到权重确定和指标赋值中的模糊性和不确定性等问题,选用三角模糊理论建立了尾矿库风险评价模型,并以本溪某尾矿库为例进行说明。理论分析和实例计算表明,该方法对尾矿库风险评价有很好的适用性。     

生物法净化挥发性有机废气的吸附-生物膜理论模型与模拟研究

针对挥发性有机废气的生物法净化过程,进行了吸附-生物膜新型理论的相关动力学模型研究.经采用实验室数据和工业应用试验结果的对比验证表明,该模型对描述实际过程有很好的适用性.应用该模型对人口气体甲苯浓度、气体流量及生物膜填料层高度等主要因素的影响进行模拟研究,模拟计算值与实验值之间有较好的相关性,相关系数r为0.80～0.97.     

Barriers to worldwide institutionalization of social and environmental disclosure

This study analyzes how groups of organizations that share their social and environmental information are formed in a similar way to identify barriers to the homogenization of social and environmental disclosure (SED) at the international level. Based on a sample of observations of listed firms from six different countries, results suggest that SED does not homogenize globally, spontaneously, because of cultural and geographical barriers. The institutions of environmental disclosure (ED) and social disclosure (SD) are different, thus forming different organizational fields at the international level. The spoken language is a barrier to the international isomorphism of ED and therefore to its comparability. However, language is a less important barrier to SD. When cultural institutions are weaker or have the same roots as North American institutions, cultural diversity does not stop the homogenization of the SD. Moreover, the ED is more isomorphic/comparable at the global level than SD, while the SD is more isomorphic/comparable at the level of culturally distinguishable subsets than ED.