Application of a hydroxylamine nitrate stability model to plutonium purification process equipment

A mathematical model that predicts hydroxylamine nitrate (HAN) (NH₂OH·HNO₃) stability is applied to aqueous solutions containing HAN, nitric acid and plutonium that are used in plutonium purification processes. The model estimates the stability of these solutions with respect to the rapid, hazardous, autocatalytic reaction of HAN with nitric acid that generates heat and gas. It also accounts for reaction kinetics, temperature changes, gas generation rates, solution volumes and flow rates, and distribution of plutonium and nitric acid between aqueous and organic phases. The model is applied to three typical process vessels used in solvent extraction purification of plutonium – a countercurrent aqueous/organic plutonium stripping column, an oxidation column used for HAN and hydrazine destruction, and a plutonium rework tank. Both normal and off-normal process scenarios are modeled. Two of the off-normal scenarios lead to the rapid autocatalytic reaction of HAN with nitric acid where heat and gas are generated and that could lead to damage of the process equipment and/or release of hazardous plutonium solution from the vessel. In these two cases, stationary aqueous solutions containing HAN, Pu(III), and nitric acid were allowed to slowly react until conditions for the autocatalytic reaction were reached.     

利用IVE模型建立成都市轻型汽油客车排放清单

城市机动车污染物排放清单的建立是控制机动车污染的关键.本研究以2012年为基准年,通过对成都市轻型汽油客车技术水平分布、活动水平和保有量等数据的调查,将IVE模型本地化,计算了成都市2012年轻型汽油客车VOCs、PM、NOx、CO的排放清单,并分析了清单的不确定性.结果表明:成都市2012年轻型汽油客车排放的VOCs、PM、NOx和CO分别为2.23×104t、1.6×102t、1.26×104t和2.03×105t;轻型汽油客车中黄标车VOCs、PM、NOx、CO的排放量分别占排放总量的27.5%、18.1%、37.2%和42.5%,表明黄标车是轻型汽油客车污染物排放的主要来源;排放清单的不确定性主要来自于排放因子,VOCs、PM、NOx和CO清单的不确定性分别为-31.67%~32.35%、-54.75%~55.09%、-6.56%~6.76%和-12.22%~12.51%.     

考虑齐口裂腹鱼产卵需求的山区河流生态基流过程确定

在原型观测的基础上,应用生态水力学法与生境模拟法,建立对考虑齐口裂腹鱼产卵需求的山区河流水电工程生态基流过程的确定方法,并以四川中型山区河流杂谷脑河薛城电站为背景,对所构建方法进行应用分析。通过原型观测,对生态水力学的齐口裂腹鱼生境水力参数标准在杂谷脑河应用的适宜性进行分析;应用生态水力学方法,对不同河道流量下薛城电站减水河段的齐口裂腹鱼生境水力参数进行数值模拟,根据模拟结果,结合齐口裂腹鱼生境水力参数标准,分析得到薛城电站满足其生存的最小下泄流量;应用生境模拟法,对齐口裂腹鱼产卵期不同河道流量下薛城电站减水河段集中产卵场的可利用生境面积进行计算,得到最大可利用生境面积对应的下泄流量。综合最小下泄流量值与最大可利用生境面积所对应的下泄流量值,考虑齐口裂腹鱼产卵对水文情势的要求,建立薛城电站考虑齐口裂腹鱼产卵需求的生态基流过程。采用所构建方法得到的考虑鱼类产卵需求的水电工程生态基流过程,由于考虑了鱼类生存对最低流量以及产卵对水文情势的要求,能更好地满足鱼类产卵需求,可作为电站运行调度的约束。     

崇明岛中长期碳排放预测及其影响因素分析

为更好地推动崇明低碳生态岛的建设,在应用以自下而上的部门法为基础的区域范围温室气体排放评估核算方法,全面核算崇明岛能源消费及温室气体排放现状的基础上,应用LEAP模型,通过情景分析预测崇明岛中长期能源消费需求以及温室气体排放水平,并进一步应用对数平均指数法(LMDI)对影响崇明岛未来温室气体排放的主要因素进行了定量分析。研究表明:参考情景下,崇明岛能源消费总量从2010年的101万吨标煤增加到2050年的533万吨标煤,净碳足迹从2010年的238万吨CO2e增加到2050年的579万吨CO2e。崇明岛能源消费需求和碳排放增加的主要驱动因素是未来的经济发展、人口增长和生活水平的提高,但是通过一系列的优化,尤其是能源结构的变化和能耗强度的下降,减排情景下,崇明岛能源消费总量有可能在2039年左右达到峰值,并有望在2050年左右实现"零碳岛"的长期发展目标。结合定量分析的结论,进一步提出了实现崇明岛低碳发展中长期目标的可能性和重点发展领域。     

Land-use forecasting and hydrologic model integration for improved land-use decision support

This paper develops a methodology for integrating a land-use forecasting model with an event scale, rainfall-runoff model in support of improving land-use policy formulation at the watershed scale. The models selected for integration are loosely coupled, structured upon a common GIS platform that facilitates data exchange. The hydrologic model HEC-HMS is calibrated for a specific storm event that occurred within central Washington State. The land-use forecasting model, What If? is implemented to forecast future spatial distributions of low-density residential land-uses under low and high population growth estimates. Forecasted land-use distribution patterns for the years 2015, 2025, and 2050 are then used as land-use data input for the calibrated hydrologic model, keeping all other parameters constant. Impacts to the stream discharge hydrograph are predicted as the study area becomes increasingly developed as forecasted by What If?. The initial results of this integration process demonstrate the synergy that can be generated through the linkage of the selected models. The ability to quantifiably forecast the potential hydrologic implications of proposed land-use policies before their implementation offers land-use decision-makers a valuable tool for discerning which proposed land-use alternatives will be effective at minimizing storm water runoff.     

Conceptual Models as Hypotheses in Monitoring Urban Landscapes

Many problems and challenges of ecosystem management currently are driven by the rapid pace and spatial extent of landscape change. Parks and reserves within areas of high human population density are especially challenged to meet the recreational needs of local populations and to preserve valued environmental resources. The complex problem of managing multiple objectives and multiple resources requires an enormous quantity of information, and conceptual models have been proposed as tools for organizing and interpreting this information. Academics generally prefer a bottom-up approach to model construction that emphasizes ecologic theory and process, whereas managers often use a top-down approach that takes advantage of existing information to address more pragmatic objectives. The authors propose a formal process for developing, applying, and testing conceptual models to be used in landscape monitoring that reconciles these seemingly opposing perspectives. The four-step process embraces the role of hypothesis testing in the development of models and evaluation of their utility. An example application of the process to a network of national parks in and around Washington, DC illustrates the ability of the approach to systematically identify monitoring data that would both advance ecologic theory and inform management decisions.     

Roles of semivolatile and intermediate-volatility organic compounds in secondary organic aerosol formation and its implication: A review

Secondary organic aerosol (SOA) is a very important component of fine particulate matter (PM_2.5) in the atmosphere. However, the simulations of SOA, which could help to elucidate the detailed mechanism of SOA formation and quantify the roles of various precursors, remains unsatisfactory, as SOA levels are frequently underestimated. It has been found that the performance of SOA formation models can be significantly improved by incorporating the emission and evolution of semivolatile and intermediate-volatility organic compounds (S/IVOCs). In order to explore the roles of S/IVOCs in SOA formation, this study reviews some simulation models which could consider S/IVOCs for SOA formation as well as the development of emission inventories of S/IVOCs and S/IVOC modules for SOA formation. In addition, the future research directions for simulations of the effect of S/IVOCs on SOA formation are suggested.     

GSM移动通信基站电磁辐射环境影响分析

本文阐述了电磁辐射的相关理论、电磁辐射环境的评价标准以及基站的工作原理,对电磁环境进行了理论预测,对不同的天线增益下的电磁辐射功率密度值进行了计算,得到了在天线增益15dBi、17dBi和18dBi三种情况下与天线不同直线距离的预测点的功率密度预测值,并对功率密度预测值进行了分析。     

Quantification of nitrate leaching from German forest ecosystems by use of a process oriented biogeochemical model

Simulations with the process oriented Forest-DNDC model showed reasonable to good agreement with observations of soil water contents of different soil layers, annual amounts of seepage water and approximated rates of nitrate leaching at 79 sites across Germany. Following site evaluation, Forest-DNDC was coupled to a GIS to assess nitrate leaching from German forest ecosystems for the year 2000. At national scale leaching rates varied in a range of 0–>80 kg NO₃–N ha⁻¹ yr⁻¹ (mean 5.5 kg NO₃–N ha⁻¹ yr⁻¹). A comparison of regional simulations with the results of a nitrate inventory study for Bavaria showed that measured and simulated percentages for different nitrate leaching classes (0–5 kg N ha⁻¹ yr⁻¹:66% vs. 74%, 5–15 kg N ha⁻¹ yr⁻¹:20% vs. 20%, >15 kg N ha⁻¹ yr⁻¹:14% vs. 6%) were in good agreement. Mean nitrate concentrations in seepage water ranged between 0 and 23 mg NO₃–N l⁻¹.     

人口长期均衡发展及其评价监测模型的构建与应用

在借鉴已有理论的基础上,界定了人口长期均衡发展的内涵,提出人口长期均衡包含人口内部均衡和人口外部均衡两个方面,人口内部均衡包括人口数量、人口质量和人口结构三个维度,人口外部均衡包括人口与经济、人口与社会、人口与资源、人口与环境四个维度;在此基础上构建了人口长期均衡发展的指标体系和评价模型,指标体系设定为三级,第一级包括人口内部均衡和人口外部均衡两个方面,第二级由人口数量、人口质量、人口结构等七个部分构成;第三级指标包括反映内部均衡的7个指标以及反映外部均衡的13个指标.并使用层次分析法确定了指标的权重;采用2000-2007年31个省级单位的数据对人口长期均衡发展评价模型进行了验证,并对人口总体均衡水平以及影响人口均衡发展的关键要素进行了实证分析.结果表明.北京、上海和浙江分列前三,人口均衡发展程度最高.从影响均衡程度的关键因素看.人口质量和人口结构是制约人口自身均衡的主要因素,人口与社会的均衡状况对人口与外部系统均衡制约最大,其次是人口与经济的均衡状况.