危化品企业安全信用内涵的探讨

现代市场经济是信用经济,信用需要用制度来保障.对危化品企业就"信用"与"信用制度"进行了探讨,给出了危化品企业安全信用概念,并简单阐述危化品企业安全信用制度内涵.最后,对建立危化品企业安全信用制度的可能性与必要性进行了分析.     

化学品危险性鉴别分类研究的现状与展望

从对GHS(化学品分类及标记全球协调制度)化学品危险性鉴别分类的分析出发,归纳和总结了联合国、欧盟、美国以及中国的化学品危险性鉴别分类研究现状;提出化学品危险性鉴别分类是获取化学品安全信息、评估化学品的固有危险性的重要手段;给出化学品危险性鉴别分类试验必须满足OECD(经济合作与发展组织)的各项标准和准则;对化学品危险性鉴别分类的应用前景及未来工作进行评述和展望;指出为化学品安全管理、事故应急救援、事故调查及做好基础数据的积累是今后研究工作的努力方向;提出了借鉴GHS,REACH(化学品注册、评估、许可和限制)等先进化学品安全监管法规,对完善我国的化学品安全监管制度,化学品鉴别分类标准的重要现实意义。     

组合阳极联合气体扩散阴极电催化降解苯胺

采用气体扩散电极为阴极，钛基氧化物（Ti／SnO2-Sb2O5-IrO2）和金属铁构成组合阳极，构建了新型电化学氧化体系用于降解有机污染物。利用该氧化体系，在不同实验条件下考察了苯胺降解的效果与降解过程的相关规律。结果表明，阴极电位、铁阳极通电时间以及苯胺初始浓度均显著影响苯胺的降解效果。当阴极电位为-0．7V，pH3．0，铁阳极通电时间20min时，电化学处理200mg／L苯胺480min，TOC的去除效率达到80．4％，矿化电流效率（MCE）为8．6％，显示了该氧化体系具有良好的有机物降解能力。此外，苯胺降解过程中氨氮和硝态氮浓度的变化表明，苯胺分子中的氮主要转化为NH4和NO3^-。     

Distribution and bioaccumulation of steroidal and phenolic endocrine disrupting chemicals in wild fish species from Dianchi Lake, China

The distribution and bioaccumulation of steroidal and phenolic endocrine disrupting chemicals (EDCs) were studied in various tissues of wild fish species from Dianchi Lake, China. In muscle tissue, 4-tert-octylphenol, 4-cumylphenol, 4-nonlyphenol and bisphenol A were detected in fish from each sampling site, with maximal concentrations of 4.6, 4.4, 18.9 and 83.5 ng/g dry weight (dw), respectively. Steroids (estrone, 17β-estradiol 17α-ethynylestradiol and estriol) were found at lower levels (<11.3 ng/g dw) and less frequently in muscle samples. The highest concentrations of steroids and phenols were found in liver, followed by those in gill and the lowest concentration was found in muscle. The field bioconcentration factors (BCFs) of phenols were calculated in fish species ranged from 18 to 97. Moreover, the measured tissue concentrations were utilized in order to estimate water concentration of steroids (4.4-18.0 ng/L). These results showed that steroidal and phenolic EDCs were likely ubiquitous contaminants in wild fish.     

Sulfate removal from waste chemicals by precipitation

Chemical oxidation using Fenton's reagent has proven to be a viable alternative to the oxidative destruction of organic pollutants in mixed waste chemicals, but the sulfate concentration in the treated liquor was still above the acceptable limits for effluent discharge. In this paper, the feasibility of sulfate removal from complex laboratory wastewaters using barium and calcium precipitation was investigated. The process was applied to different wastewater cases (two composite samples generated in different periods) in order to study the effect of the wastewater composition on the sulfate precipitation. The experiments were performed with raw and oxidized wastewater samples, and carried out according to the following steps: (1) evaluate the pH effect upon sulfate precipitation on raw wastewaters at pH range of 2-8; (2) conduct sulfate precipitation experiments on raw and oxidized wastewaters; and (3) characterize the precipitate yielded. At a concentration of 80 g L(-1), barium precipitation achieved a sulfate removal up to 61.4% while calcium precipitation provided over 99% sulfate removal in raw and oxidized wastewaters and for both samples. Calcium precipitation was chosen to be performed after Fenton's oxidation; hence this process configuration favors the production of higher quality precipitates. The results showed that, when dried at 105 degrees C, the precipitate is composed of hemidrate and anhydrous calcium sulfate ( approximately 99.8%) and trace metals ( approximately 0.2%: Fe, Cr, Mn, Co, Ag, Mg, K, Na), what makes it suitable for reuse in innumerous processes.     

Liquid household hazardous wastes in the United States: Identification,disposal, and management plan

Present methods of disposal of today's hazardous household chemicals in the United States are frequently not acceptable because of pathways to groundwater, surface water, and the atmosphere. This report identifies potentially hazardous liquid waste in the household, notes current disposal practices, and recommends an improved management plan that utilizes consumer education, manufacturer cooperation, and governmental intervention. Laws requiring uniform disposal labeling on packaging are critical. Local, county, and state governments must be encouraged to coordinate the necessary infrastructure. Managing hazardous household wastes now will mitigate potential disposal problems.     

生物难降解有机污染物的治理对策

针对废水中难降解化学合成有机污染物的种类和数量不断增加，生物处理出水达标困难的现状，总结了国内外的经验和研究成果，对现有处理装置改造提出了若干建议，并介绍了几种国外废水处理新技术。     

公路运输化学事故应急救援体系研究

以动态源的定义为基础 ,结合危化品公路运输特殊性 ,阐述了危化品在公路运输过程中发生化学事故后应急救援的原则、工作特点与基本要求 ;提出化学事故应急救援中的基本任务是控制危险源 ,抢救受害人员 ,指导并组织群众疏散、自救和做好事故现场清理洗消工作 ,消除危害后果 ;提出公路运输化学事故应急救援预案系统建设的总体目标是 ,在应用ITS智能交通系统对动态源精确定位的基础上 ,建立公路运输化学事故应急救援预案动态库及应急救援组织保障系统和应急救援技术支持系统 ,一旦事故发生 ,能够做到尽快有效处理 ,最大限度地减小或消除事故损失。     

饮用水源突发性苯胺污染应急处理技术研究

分别从水样浓度、pH、反应时间、药剂投加量以及两者联用时的投加顺序等方面研究了粉末活性炭、高锰酸钾以及两者联合使用时对苯胺的去除效果.结果表明,当污染发生时,高锰酸钾和粉末活性炭联用处理技术是可行的；先投加粉末活性炭再加高锰酸钾处理比先投加高锰酸钾再投加活性炭的去除效果好；当水样pH在中性条件下,粉末活性炭和高锰酸钾联用处理技术的去除效果好；应急处理的反应时间是30 min.     

江苏省危险化学品生产状况调查分析及监管对策

根据《危险化学品名录》,分析江苏省取得危险化学品安全生产许可证的1774家企业的化学品种类、数量、生产企业类型分布情况.结果表明,江苏省危险化学品生产企业在地域分布上苏南多于苏北;化工、建材行业的危险化学品生产企业所占比例较高;危险化学品涉及除爆炸品外的6大类,达3 790种,以生产易燃液体的企业数目为最多;有31家企业生产10种以上危险化学品.笔者建议,通过评估摸清企业安全生产状况,严格控制危险化学品企业安全生产许可证发放,实现危险化学品运输企业的动态管理,建立安全监测预警技术平台.