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991.
Jurdi M Korfali SI Karahagopian Y Davies BE 《Environmental monitoring and assessment》2002,77(1):11-30
The increased demand on water resources in Lebanon as a resultof: progressive urbanization, socio-economic growth, agriculturalactivities and development of industries is, according to the national authorities, a major critical factor by the year 2010.Political difficulties in earlier years imply a dearth of pertinent data. The objective of this study was to evaluate water quality of the Qaraaoun Reservoir of the Litani River andassess its feasibility for multi-purpose usage as one of the solutions to the aggravated water problems in Lebanon. Sampleswere collected from 18 sampling sites at several dates duringthe dry season. Parameters analysed were, pH, electrical conductivity, TDS, turbidity, alkalinity, Ca, Mg, TH, Cl-, SO4
2-, NH3, NO3
-,PO4
3-, Fe, Al, Na, Zn, Cr, Cu and As. The reported data were in compliancewith WHO guidelines, USEPA regulation and EEC directives. Statistical analysis of the data defined three distinct environmental zones and water quality in the central, main zone satisfied most criteria. It is concluded that the reservoir water is fit for multipurpose uses, namely, drinking, domestic,recreational activities, irrigation, fisheries, livestock and industrial, and should be properly managed accordingly. 相似文献
992.
Gossett R Baird R Christensen K Weisberg SB 《Environmental monitoring and assessment》2003,81(1-3):269-287
Quality assurance procedures to ensure consistency among chemistry laboratories typically involves the use of standard methods and state certification programs that require laboratories to demonstrate their ability to attain generic performance criteria. To assess whether these procedures are effective for ensuring comparability when processing local samples with potentially complex matrices, seven experienced, state-certified laboratories participated in an intercalibration exercise. Each laboratory was permitted to use their typical methodology for quantifying PAH, PCB and DDT on shared samples collected from Santa Monica Bay and the Palos Verdes Shelf, two sites with a complex mix of constituents. In the initial intercalibration exercise, results from these laboratories differed by as much as an order of magnitude for all three chemical groups. Much, but not all, of the difference was attributable to differences in detection capability. A series of studies was conducted to identify the reasons for the observed differences, which varied among laboratories and included methodological differences, instrument sensitivity differences, and differing interpretations of chromatograms. Following these investigations and resulting modifications to laboratory procedures, the exercise was repeated. The average coefficient of variation among laboratories across all chemical parameters was reduced to less than 30%. Our results suggest that performance-based chemistry can produce comparable results, but the certification processes presently in place that focus on general laboratory procedures and simple matrices are insufficient to achieve comparability. 相似文献
993.
Quantifying chemical variability in different lake types is important for the assessment of both chemical and biological responses to environmental change. For monitoring programs that emphasize a large number of lakes at the expense of frequent samples, high variability may influence how representative single samples are of the average conditions of individual lakes. Intensive temporal data from long-term research sites provide a unique opportunity to assess chemical variability in lakes with different characteristics. We compared the intra- and inter-annual variability of four acidification related variables (Gran alkalinity, pH, sulphate concentration, and total base cation concentration) in four lakes with different flushing rates and acid deposition histories. Variability was highest in lakes with high flushing rates and was not influenced by historic acid deposition in our study lakes. This has implications for the amount of effort required in monitoring programs. Lakes with high flushing rates will require more frequent sampling intervals than lakes with low flushing rates. Consideration of specific lake types should be included in the design of monitoring programs. 相似文献
994.
995.
Synthetic pyrethroids have been detected in recent California surface water monitoring. Filtration is avoided during sample
workup because pyrethroids are extremely hydrophobic, tending to sorb to most surfaces. The resultant analytical pyrethroid
concentrations reflect both dissolved pyrethroid and pyrethroid associated with suspended sediment in the water column. Such
“whole-water” analytical data are not directly comparable to aquatic acute toxicity effect concentrations measured in laboratory
sediment-free water. Consequently, any potential aquatic toxicity risk is indeterminate. In this study a simple probabilistic
model was developed to allow a screening-level assessment of pyrethroid whole-water monitoring data. The results suggest that
water column toxicity of pyrethroids is possible in California's agriculturally-dominated tributaries, and indicate that additional
monitoring to better characterize pyrethroid water-column concentrations are warranted. Model refinement will depend on future
work that more firmly establishes the relationship between pyrethroid partitioning and bioavailability, and that addresses
the potential influence of dissolved organic carbon on pyrethroid sorption and bioavailability. 相似文献
996.
本文综述了我国大气污染化学研究的概况。阐明了大气颗粒物(气溶胶)的表征研究,包括颗粒物的物理化学特性和环境化学行为;大气污染物的迁移、转化和归宿的规律,包括化学过程和大气化学模式的研究等。介绍了某些大气污染物的特殊分析测试方法和采样技术,对今后发展大气化学的展望和战略作了讨论。 相似文献
997.
998.
以制备的无定型水合氧化锰对实验室配水进行了混凝试验研究,探讨了其在给水处理中应用的可行性;采用多种分析测试技术从粒子的化学组成、比表面积、界面官能团特征、粒子的物相等方面对该水合氧化锰粒子进行了表征.研究表明:该水合氧化锰粒子具有丰富的羟基化表面,比表面积为219.0411 m2/g,是一种无定型水合物,表现了优良的吸附污染物的界面特性;低投量(2 mg)的该水合氧化锰对于实验室配水具有优良的混凝性能,特别适用于高浊度原水的混凝处理. 相似文献
999.
1000.