An assessment of how distance and diesel oxidation catalyst will impact thermal decomposition behaviors of particles

Decomposition mass loss and pyrolysis products analyses of particles sampled at various locations along the tailpipe of a Euro-IV diesel engine were performed using a thermogravimetry in conjunction with Fourier transformation infrared spectrometry-mass spectrum. Diesel particles were collected at the same location with and without diesel oxidation catalyst (DOC) mounted on the test engine separately. The three poles in thermal gravity-differential thermal gravity images suggested that the decomposition process of diesel particles could be divided into three stages which correspond to the decompositions of lower boiling substances, higher boiling substances and soot respectively. It is noticed that no matter whether DOC was mounted or not, the further the particles were sampled away from the engine block, the lower the peak temperatures and the heavier the mass losses within the first two stages, which indicated that the soluble organic fraction in the particle samples increased and therefore lowering the activation energy of thermal decomposition. Hydroxyl, ammonia, C_xH_y fragments, benzene, toluene, and phenol were found to be the primary products of particle decomposition, which didn't change with the location of particle sample point. The employment of DOC increased the activation energy for particle oxidation and resulted in a higher peak temperature and lower mass loss within the first-stage. Moreover, the CO stretching bands of aldehyde and ketone at 1771 cm^?1 was only detected without a DOC, while the NO₂ peak at 1634 cm^?1 was solely noticed with the presence of DOC. Compared to the first-stage pyrolysis products, more polycyclic aromatic hydrocarbons and less C_xH_y fragments were seen in the second-stage.     

Heterojunctioned CuO/Cu2O catalyst for highly efficient ozone removal

In recent years, near surface ozone pollution, has attracted more and more attention, which necessitates the development of high efficient and low cost catalysts. In this work, CuO/Cu₂O heterojunctioned catalyst is fabricated by heating Cu₂O at high temperature, and is adopted as ozone decomposition catalyst. The results show that after Cu₂O is heated at 180°C conversion of ozone increases from 75.2% to 89.3% at mass space velocity 1,920,000 cm³/(g·hr) in dry air with 1000 ppmV ozone, which indicates that this heterojunction catalyst is one of the most efficient catalysts reported at present. Catalysts are characterized by electron paramagnetic resonance spectroscopy and ultraviolet photoelectron spectroscopy, which confirmed that the heterojunction promotes the electron transfer in the catalytic process and creates more defects and oxygen vacancies in the CuO/Cu₂O interfaces. This procedure of manufacturing heterostructures would also be applicable to other metal oxide catalysts, and it is expected to be more widely applied to the synthesis of high-efficiency heterostructured catalysts in the future.     

超声波处理石化厂剩余活性污泥

采用超声波处理石化污水处理厂的剩余活性污泥。介绍了超声波对污泥的作用机理，初步研究了超声波处理污泥的影响因素。大功率超声波可以降解生物污泥，释放出其中的有机物。小功率超声波能够改善污泥的膨胀特性、提高污泥沉淀特性和脱水能力、降低污泥的含水率，达到减量的目的。经超声波处理并简单过滤的污泥滤液，COD达到4200mg／L左右，污泥含水率由94％降至85％左右。     

贫燃条件下汽车尾气中NOx催化净化研究进展

汽车尾气排放的NOx(主要是NO)是城市大气的主要污染源之一。本综述了近l0年来贫燃条件下NOx催化转化为N2的催化剂研究进展。这些方法包括HC-SCR、NO直接催化分解、NOx吸附-还原等。讨论了不同催化剂的性能影响因素。新的负载材料MFI、MCM-41、SAPO-34的应用增强了催化剂的性能。双功能催化剂由于两种活性位的协同作用表现出较高的活性和选择性。新的纳米结构概念催化剂NOx吸附还原中发现有广泛应用。介绍了上述催化脱除NOx的各种机理并指出了今后研究的方向。     

强震仪观测资料在杨浦大桥养护监测中的运用

上海杨浦大桥是当时世界同类型桥梁中最长的斜拉索桥,为了掌握大桥的运行情况,确保运行安全,每年用在该桥上的养护管理费用相当可观,且程序繁琐。如何找到既简单实用,又节约费用,就能起到一定的养护监测作用的方法?是本文探讨的问题。本文运用强震观测资料,采用自回归移动平均ARMA模型,得到大桥的随机振动中某些振型的频率及阻尼比,在地震、台风过后或经一长段时间车辆运行之后,看其相应振型频率和阻尼比的变化,以达到维护监测的目的。从所得的结果看,此法具有较好的可操作性,可用于大桥主塔等的养护。     

关于建立许家峪生态农业示范村的可行性研究

生态农业示范村建设是进行综合生态农业示范体系研究的基础,也是神态农业经营理念和技术推广的重要途径。因此,地理、交通、自然和人文环境的选择,生产经营模式的确定对生态农业经营效益和示范影响效果至关重要。本文通过对许家峪村的现状和作为冀东生态农业示范村的优势和存在问题以及适宜的经营模式进行了剖析和阐述。     

英语写作中Chinglish的成因分析

在母语环境中学习外语的过程始终存在母语的干扰。针对大学英语写作中出现的Chinglish——中式英语的现象，从皮亚杰的发生认识论、母语负迁移及中西思维模式差异等方面分析了中式英语的成因。揭示其成因对于大学英语教师改进写作教学具有重要意义，从而更好地帮助学生用英语思维模式写出地道的英文。     

西江年最高水位的神经网络预报模型

对西江洪水发生的特征进行分析表明，洪水发生频率高，具有明显阶段性特征，并与流域面雨量密切相关。利用前期环流场、海表温度（SST）场及环流特征量资料选择初选预报因子，然后对初选预报因子作EOF分解构造综合预报因子，结合人工神经网络方法建立了西江年最高水位预报模型，并对预报模型进行独立样本试验。结果表明，该预报模型对历史样本拟合精度高，试报效果明显好于传统的逐步回归模型，可在汛期预测业务中应用。     

安全科技英语专业设置的可行性探索与研究

国家十分重视安全生产,安全生产已成为国家“十一五”规划的重要内容之一。如何适应安全科技教育发展的新机遇是安全教育工作者所关注的重要课题。笔者通过调查研究,在分析安全科技英语专业设置的必要性和重要意义的基础上,提出了安全科技英语专业人才的培养模式,构建了安全科技英语专业课程体系的基本框架,并就安全科技英语专业特色进行了研究和探索,指出了安全科技英语专业设置应注意的若干问题。