全文获取类型
收费全文 | 603篇 |
免费 | 57篇 |
国内免费 | 238篇 |
专业分类
安全科学 | 54篇 |
废物处理 | 22篇 |
环保管理 | 110篇 |
综合类 | 400篇 |
基础理论 | 111篇 |
污染及防治 | 121篇 |
评价与监测 | 43篇 |
社会与环境 | 35篇 |
灾害及防治 | 2篇 |
出版年
2024年 | 6篇 |
2023年 | 15篇 |
2022年 | 29篇 |
2021年 | 43篇 |
2020年 | 30篇 |
2019年 | 19篇 |
2018年 | 31篇 |
2017年 | 34篇 |
2016年 | 38篇 |
2015年 | 39篇 |
2014年 | 46篇 |
2013年 | 92篇 |
2012年 | 53篇 |
2011年 | 55篇 |
2010年 | 37篇 |
2009年 | 35篇 |
2008年 | 36篇 |
2007年 | 43篇 |
2006年 | 38篇 |
2005年 | 26篇 |
2004年 | 28篇 |
2003年 | 21篇 |
2002年 | 19篇 |
2001年 | 19篇 |
2000年 | 13篇 |
1999年 | 5篇 |
1998年 | 8篇 |
1997年 | 10篇 |
1996年 | 8篇 |
1995年 | 7篇 |
1994年 | 2篇 |
1993年 | 3篇 |
1992年 | 6篇 |
1991年 | 1篇 |
1990年 | 2篇 |
1979年 | 1篇 |
排序方式: 共有898条查询结果,搜索用时 194 毫秒
21.
实验室研制了低能光电子磁场增强电离(MEPEI)和单光子电离(SPI)复合电离源,该电离源具有电离化合物范围宽、碎片离子少、质谱图简单等优点,结合飞行时间质谱(TOF-MS)实现了聚氯乙烯(PVC)热分解/燃烧产物的在线分析.针对不同的目标化合物,MEPEI/SPI复合电离源通过调节电离区电场强度,可以快速在SPI和SPI-MEPEI之间切换.PVC热分解/燃烧产物中电离能大于光子能量(10.60 eV)的HCl和CO2(12.74 eV、13.77 eV)利用MEPEI模式电离;而烯烃、二氯乙烯、苯系物、氯苯、苯乙烯、茚满及萘系物等可通过SPI-MEPEI复合模式电离.通过实时监测PVC主要燃烧产物的信号强度随温度的变化趋势可推断出,PVC燃烧产物主要是通过两种机制生成:①250~370℃时,PVC发生脱氯及分子内环化反应,产生大量的HCl、苯和萘;②380~510℃时,PVC发生分子间交联反应,生成烷基芳烃,如甲苯和二甲苯/乙苯等.实验结果表明,SPI/SPI-MEPEI复合离子源TOF-MS分析速度快,应用范围广,在在线分析中具有广泛的应用前景. 相似文献
22.
人们通常强调新颖性和经济效用的一个创新,而忽略了对环境造成的影响。这一思想体现到制度设计专利制度。一般来说,如果能够通过三个条件:新颖性、实用性和创新性,可授予专利。这种制度设计制约思维过程中创新者的回报,他们努力发明一件新颖的且有利可图的专利,但是忽略了对环境造成的影响。因此,牺牲的最终是环境。在这项研究中,试图探索一种体制上的补救。在为了改变科技发展的方向,建议完善政策背景下的创新,特别是专利制度。引进一个新的考核标准,绿色专利制度,并探讨其可行性和可能带来的影响。通过把这项环保的关注到专利审查,专利制度可以鼓励创新发明的"创新,实用和绿色"的产品以及程序,称之为"绿色专利"。 相似文献
23.
近年来,越来越多的企业对其产品进行碳足迹评价,评价方法主要采用产品碳足迹评价标准提供的碳计量方程,如GHG Protocol、ISO14064、PAS 2050、TS Q 0010等。在介绍相关评价标准的基础上,分析了产品碳足迹的评价步骤,最后利用河北盛华化工有限公司生产的PVC产品为例,给出了基于生命周期的B2B模式的产品碳足迹评价的案例。为企业及相关机构开展碳足迹评价提供借鉴作用。 相似文献
24.
利用拟一级降解速率常数表征O3/H2O2对扑灭通(Prometon)的氧化效能,探讨了n(H2O2)/n(O3)、pH值、水质和碳酸氢根离子对去除的影响,对有机氧化产物进行了气相和液相质谱分析,以离子色谱法测定了反应过程中产生的NO3-,在此基础上对扑灭通降解途径进行了研究.结果表明,扑灭通初始浓度2 mg.L-1,反应温度25℃,O3投量13 mg.L-1时,最佳反应条件为n(H2O2)/n(O3)=0.7,体系pH为7~8;扑灭通在自来水中的去除效果好于纯水;HCO3-浓度>50 mg.L-1时,对扑灭通的氧化有明显的抑制作用.液质和气质的分析结果表明扑灭通并未开环,氧化过程中扑灭通三嗪环支链上的2个异丙基首先被氧化脱去,离子色谱检测到的NO3-是三嗪环支链胺基氧化的产物. 相似文献
25.
水产品中甲氰菊酯残留的ELISA快速检测 总被引:3,自引:0,他引:3
为快速检测水产品中甲氰菊酯的残留,应用水溶性碳化二亚胺(EDC)法将甲氰菊酸与牛血清白蛋白(BSA)和卵清蛋白(OVA)偶联,合成了甲氰菊酯的人工免疫抗原和包被抗原.免疫抗原经紫外扫描和聚丙烯酰胺电泳验证构建成功,用此抗原免疫试验兔子,获得了甲氰菊酯的多克隆抗体.经检测,抗体对甲氰菊酯具有较好的特异性和灵敏性.在此基础上建立了水产品中甲氰菊酯残留的间接ELISA检测法.理想的甲氰菊酯-OVA包被抗原质量浓度为1.6 mg/L,酶标二抗(羊抗兔IgG-HRP)的稀释度为1∶1000,多抗的稀释度为1∶3 200,最适检测范围为20~200 μg/kg,在实际样品检测时的最低检出限为20 μg/kg,接近或达到气相色谱法的测定水平,但检测速度大大提高,可在3 h内完成近百个样品的分析,适合甲氰菊酯的快速检测. 相似文献
26.
Aerobic degradation of methyl tert-butyl ether by a Proteobacteria strain in a closed culture system 总被引:4,自引:0,他引:4
The contamination of methyl ten-butyl ether (MTBE) in underground waters has become a widely concerned problem all over the world. In this study, a novel dosed culture system with oxygen supplied by H2O2 was introduced for MTBE aerobic biodegradation. After 7 d, almost all MTBE was degraded by a pure culture, a member of β-Proteobacteria named as PMI, in a closed system with oxygen supply, while only 40% MTBE was degraded in one without oxygen supply. Dissolved oxygen (DO) levels of the broth in closed systems respectively with and without H2O2 were about 5-6 and 4 mg/L. Higher DO may improve the activity of monooxygemase, which is the key enzyme of metabolic pathway from MTBE to tert-butyl alcohol and finally to CO2, and may result in the increase of the degrading activity of PM1 cell. The purge and trap GC-MS result of the broth in closed systems showed that tea-butyl alcohol, isopronol and acetone were the main intermediate products. 相似文献
27.
Bioaccumulation of heavy metals in fishes from Taihu Lake, China 总被引:9,自引:0,他引:9
The Cr,Zn,Cu,Cd,Pb contents were determined in Cyprinus carpio Linnaeus,Carassius auratus Linnaeus,Hypophthalmichthys molitrix and Aristichthys nobilis,which were caught from Meiliang Bay,Taihu Lake,a large,shallow and eutrophic lake of China.The results showed that:(1)the Cr,Cu,Pb,Cd contents in the edible parts of the four fish species were much lower than Chinese Food Health Criterion(1994),but the Zn contents were higher than the Criterion;(2)Cd contents were the highest in the liver of fish,Pb contents were almost the same in all organs of fish,Cr contents mainly enriched in the skin and gonads,Zn contents were the highest in the gonad(♀),and Cu contents were the highest in the liver;(3)the total metal accumulation was the greatest in the liver and the lowest in the muscle.The total metal accumulation was the highest in C.auratus L.This investigation indicated that fish products in Taihu Lake were still safe for human consumption,but the amount consumed should be controlled under the Chinese Food Health Criterion to avoid excessive intake of Zn. 相似文献
28.
29.
30.
Siriprapha Jangkorn Sinchai Kuhakaew Suwapee Theantanoo Harit Klinla-or Tongchai Sriwiriyarat 《环境科学学报(英文版)》2011,23(4):587-594
A coagulation-flocculation process is typically employed to treat the industrial wastewater generated by the consumer products
industry manufacturing detergents, soaps, and others. The expenditure of chemicals including coagulants and chemicals for pH
adjustment is costly for treating this wastewater. The objective of this study was to evaluate the feasibility of reusing the aluminum
sulfate (alum) sludge as a coagulant or as a coagulation aid so that the fresh alum dosage can be minimized or the removal e ciency can
be enhanced. The experiments were conducted in a jar-test apparatus simulating the coagulation-flocculation process for simultaneous
removals of organic matters, anionic surfactants, suspended solids, and turbidity. At the optimum initial pH value of 10 and the fresh
alum concentration of 400 mg/L, the total suspended solids (TSS), total chemical oxygen demand (TCOD), total anionic surfactants,
and turbidity removal e ciencies were 71.5%, 76.4%, 95.4%, and 98.2%, respectively. The addition of alum sludge as a coagulant
alone without any fresh alum addition could significantly remove the turbidity, TCOD, and anionic surfactants. The TSS was left in the
supernatants after the settling period, but would subsequently be removed by adding the fresh alum. The TSS, TCOD, and turbidity
removal e ciencies were also enhanced when both the alum sludge and the fresh alum were employed. The TCOD removal e ciency
over 80% has been accomplished, which has never fulfilled by using the fresh alum alone. It is concluded that the alum sludge could
be reused for the treatment of industrial wastewater generated by the consumer products industry. 相似文献