基于可拓云模型的区域生态安全预警模型及应用——以祁连山冰川与水源涵养生态功能区张掖段为例

针对区域生态安全预警中的不确定性问题,考虑生态安全等级边界信息的随机性、模糊性及动态性,利用可拓学中兼具定性和定量分析及动态性的物元理论和具有不确定推理特性的云模型,提出了基于可拓云模型的区域生态安全预警模型;运用该模型对祁连山冰川与水源涵养生态功能区张掖段2005—2015年生态安全进行了定量评估,并对2017年生态安全环境进行动态预警。结果表明:祁连山生态功能区张掖段2005—2015年的生态安全整体水平均处于"理想"以下,其变化趋势为"较差"到"一般"再到"良好";2017年祁连山冰川与水源涵养生态功能区张掖段生态安全为"蓝色"预警,但有向"黄色"转变的趋势,其中工业三废、环保投入强度、森林覆盖率及人均水资源量是影响祁连山冰川与水源涵养生态功能区张掖段生态安全的主要因素。     

Kinetic and mechanism studies of the ozonolysis of three unsaturated ketones

Reaction rate constants and products of 1-octen-3-one, 3-octen-2-one and 4-hexen-3-one with ozone were studied in a 100-L fluorinated ethylene propylene (FEP) Teflon film bag using absolute rate method at 298 ± 1 K and atmospheric pressure. The rate constants were (1.09 ± 0.12) × 10^?17, (3.48 ± 0.36) × 10^?17 and (5.70 ± 0.60) × 10^?17 cm³/(molecule?sec), respectively. According to the obtained rate constants, the effects of carbonyl were discussed. The carbonyl group in β position has a net withdrawing effect with respect to an olefinic bond, then causing the decline of rate constants. The quantum chemical calculation was used to explain the results of rate constants. The products of ozonolysis were mainly aldehydes, which have significant influence on the formation of SOA, and hence play an important role in the atmosphere. In this work, we detected the main products of reaction and proposed the reaction mechanism by combining the results of quantum chemical calculations. Atmospheric lifetime for three unsaturated ketones reacted with ozone was 36.4, 11.4 and 6.9 hr for 1-octen-3-one, 3-octen-2-one and 4-hexen-3-one, respectively.     

基于可拓和组合赋权的泥石流危险性评价

基于可拓学物元理论,结合层次分析主观赋权法与灰色关联度客观赋权法,对评价因子进行组合赋权,避免单一赋权方法的片面性,建立泥石流危险性评价模型。影响泥石流危险性的因子有很多,通过现场实际调查,选取一次泥石流最大冲出量、发生频率、24 h最大降雨量等8个因子对泥石流进行危险性评价。运用该模型对卡拉地区7条泥石流沟进行危险性评价,评价结果与实际情况相吻合,表明此方法可为泥石流危险性评价提供参考。     

城市综合防灾应急能力可拓评价模型构建及应用

城市综合防灾应急能力可以衡量一个城市在面临灾害时的抗御能力及恢复能力,并且是辅助城市灾害决策的重要依据.以城市灾害发生时及其后所展开的各种紧急救援工作所涉及的城市防灾建设状况作为评价依据,按照一定的指标选取原则,构建出包括消防能力、避难安置能力、医疗救护能力、物资供应能力、治安防护能力、环卫能力、协调能力7个1级评价指标及17个2级评价指标的指标体系.根据国际通用或相关规范规定的救灾资源配置标准进行等级划分,利用可拓学理论及其特点建立可拓评价模型.并将评价模型应用于长沙城市综合防灾应急能力的评价,得出长沙市城市综合防灾应急能力等级为"差",以及长沙需要重点加强的指标:消防车数量、人均避难面积、城市综合防灾管理体系完备度.     

基于可拓云理论的泥炭质土场地沉降风险评价

为更好地研究泥炭质土场地地铁车站基坑周边沉降问题,预测和评估施工时及施工后的沉降风险,在分析了泥炭质土的特点后,选择土层厚度、有机质质量分数、重度、天然含水率、孔隙比、土层埋深和压缩模量7个指标,建立沉降风险评估指标体系,并根据改进层次分析法和改进熵权法求出主观权重与客观权重,最后用理想点法耦合主客观权重求出各评价指标的综合权重;根据沉降等级分类标准,生成每个评价指标的云滴图,计算得到各评价因子的可拓云矩阵,进而将综合权重向量与可拓云矩阵相乘得到综合确定度,根据综合确定度最大原则确定样本沉降风险等级。以昆明某地铁车站施工监测数据为例,用建立的可拓云模型对泥炭质土场地的沉降风险进行评价,最终评价结果与实际监测结果吻合较好,验证了分析方法的合理性及可行性。该评价方法充分考虑了多种因素影响,明确了沉降的风险等级,评价结果为泥炭土场地上建(构)筑物的设计施工及应急处理提供了理论依据。     

Guidelines for life extension process management in oil and gas facilities

Facilities life extension has caught the attention among the capital-intensive industries, like oil and gas. By extending the life cycle of the industrial assets, a wide range of benefits is obtained, comparing with other life ending management strategies. This article first contextualizes the implementation of the life extension concept in the oil and gas industry, showing global data about life extension. Despite the importance of the ageing process, due to its great economic impact and the risk it poses to the production sector, regulatory entities, even in countries more advanced in that sector or that have already experienced the extension process, developed only superficial material about the topic without defining a structured methodology for the assessment of the possibility of useful life extension. The available references do not allow a comprehensive analysis of that possibility, which highlights the importance the methodology proposed. Thus, this article proposes a guideline for the life extension process management, strengthening a framework containing the main evaluation stages, aiming to facilitate the analysis of issues related to ageing and to support the decision-making process. Lastly, real case studies regarding current life extension processes submitted to the Brazilian regulatory body were evaluated against the proposed framework stages, evidencing their lack of necessary details to support the decision-making. Upon the realization that the real cases identified do not allow for the assessment of the contribution and adequacy of the proposed framework in its entirety, the same was also applied to a hypothetical case. The latter was developed based on facts reported by a major operator in Brazil. The result was the determination that the use of the proposed methodology transformed the assessment of the possibility of life extension into a systematic and transparent process, leading to easier and better-founded decision-making procedures, and improving the management of the asset during its extended life.     

Polycyclic aromatic hydrocarbons in urban soils of Beijing: status, sources, distribution and potential risk

We studied the source, concentration, spatial distribution and health risk of 16 polycyclic aromatic hydrocarbons (PAHs) in urban soils of Beijing. The total mass concentration of 16 PAHs ranged from 93 to 13 141 μg kg⁻¹ with a mean of 1228 μg kg⁻¹. The contour map of soil PAH concentrations showed that the industrial zone, the historical Hutong district and the university district of Beijing have significantly higher concentrations than those in remainder of the city. The results of sources identification suggested that the primary sources of PAHs were vehicle exhaust and coal combustion and the secondary source was the atmospheric deposition of long-range transported PAHs. The incremental lifetime cancer risks (ILCRs) of exposing to PAHs in the urban soils of Beijing for adult were 1.77 × 10⁻⁶ and 2.48 × 10⁻⁵, respectively under normal and extreme conditions. For child, they were 8.87 × 10⁻⁷ and 6.72 × 10⁻⁶, respectively under normal and extreme conditions.     

An Analysis of Young Driver Crash Types and the Associated Lifetime Care Cost in Victoria,Australia

Objective: The elevated crash involvement rate of young drivers is well documented. Given the higher crash risk of young drivers and the need for innovative policy and programs, it remains important to fully understand the type of crashes young drivers are involved in, and knowledge of the lifetime care cost of crashes can support effective policy development. The aim of this article is to document the number and type of young driver crashes, as well as the associated lifetime care cost over a 9-year period (2005–2013) in Victoria, Australia.

Methods: In Victoria, Australia, the Transport Accident Commission (TAC) has legislated responsibility for road safety and the care of persons injured in road crashes, irrespective of fault. TAC claims data for the period 2005–2013 were used to document the number and type of young driver crashes. Lifetime care costs (past and future payment liabilities) were calculated by Taylor Fry actuarial consultancy. License and population data were used to define the crash involvement rate of young drivers.

Results: Over the 9-year period, 16,817 claims were lodged to the TAC by drivers 18–25 years of age following a crash. There were 646 fewer drivers aged 18–25 killed and injured in 2013, compared to 2005, representing an unadjusted change of ?28.7% (?29.8% males; ?28.4% females). The total lifetime care cost of young drivers killed and injured in Victoria for the period 2005–2013 was estimated to be AU$634 million (US$493 million). Differences between males and females, single- and multivehicle crashes, and fatalities and injuries were found to be statistically significant. Run-off-road crashes and crashes from opposing direction were overrepresented in the lifetime care costs for young driver claimants. Twenty-eight injured drivers were classified as high-severity claims. These 28 claimants require additional long-term care, which was estimated to be AU$219 million; of these 28, 24 were male (85.7%). The long-term care costs for these 28 drivers (0.16%) accounts for 34.5% of the total lifetime care cost of all 18- to 25-year-old injured drivers.

Conclusions: By using no-fault lifetime care costs that account for medical and like expenses, rehabilitation, and social reintegration costs, a more accurate understanding of the cost of young driver crashes can be determined. Application of these costs to specific crash types highlights new priorities and opportunities for developing programs to reduce young driver crashes.     

Management of life extension for topsides process system of offshore platforms in Chinese Bohai Bay

Technological advances in exploration and production mean that production platforms in Chinese Bohai Bay have many developments that are now operating beyond their original design life. As equipment ages, there are increasing challenges to maintain its integrity. Issues related to LE management of offshore facilities in government regulations, industrial associations and international oil companies were investigated. The results showed that emphasizing the requirements of labor union and industrial associations was a great feature in Norway, which was practical in Chinese Bohai Bay. Therefore, with the combination of the LE management system in Norway with the current situation in Chinese Bohai Bay, LE management model which integrates RBI, RCM, FMECA, and SIL risk assessment methods together was designed in order to improve understanding and ensure that LE issues were addressed across all aspects of asset management during the entire LE period. Finally, an example of three production offshore platforms on a gas field in the Bohai Bay was used to go through the LE management process and address the issues in each phase. The suggestions for improving LE management and technologies were given.     

贮存使用环境对导弹性能的影响机理

目的分析影响导弹性能的主要环境因素及影响机理。方法根据导弹的贮存条件和环境因素的重要性,分析影响导弹性能的主要环境因素,分析总结其影响机理。结果影响导弹性能的主要环境因素包括温度、湿度、振动与冲击、重力、气压和静电,其中温度的主要影响机理是引起力学性能、电器性能、气体和液体对容器的压力、化学反应速度的变化,湿度的影响机理是水膜、凝露的形成和产品的吸湿,振动与冲击的影响机理是疲劳损伤和极限破坏,重力影响固体发动机粘接界面的机理是药柱温度小于平衡温度引起的扯离应力,气压的影响机理是空气压力、空气密度和空气含氧量的变化,静电的影响机理是静电放电和静电引力。结论环境影响导弹性能的机理,对通过设计提高导弹的环境适应能力和使用环境控制都很重要。