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71.
72.
Shane Morrin Paola Lettieri Chris Chapman Richard Taylor 《Waste management (New York, N.Y.)》2014,34(1):28-35
Often perceived as a Cinderella material, there is growing appreciation for solid waste as a renewable content thermal process feed. Nonetheless, research on solid waste gasification and sulphur mechanisms in particular is lacking. This paper presents results from two related experiments on a novel two stage gasification process, at demonstration scale, using a sulphur-enriched wood pellet feed.Notable SO2 and relatively low COS levels (before gas cleaning) were interesting features of the trials, and not normally expected under reducing gasification conditions. Analysis suggests that localised oxygen rich regions within the fluid bed played a role in SO2’s generation. The response of COS to sulphur in the feed was quite prompt, whereas SO2 was more delayed. It is proposed that the bed material sequestered sulphur from the feed, later aiding SO2 generation. The more reducing gas phase regions above the bed would have facilitated COS – hence its faster response. These results provide a useful insight, with further analysis on a suite of performed experiments underway, along with thermodynamic modelling. 相似文献
73.
Junyi Hu Yu Shen Song Pang Yun Gao Guoyong Xiao Shujun Li Yingqian Xu 《环境科学学报(英文版)》2013,(S1):S32-S35
The decay of wood and other cellulosic materials by fungi cause significant economic loss. The widely used chromated copper arsenate was prohibited for the environmental impact and safety of arsenic and chromium. It was found that natural product hinokitiol (HK) had fungicidal and insecticidal activities, and its toxicity was bearable for the environment. We described the practical synthesis of HK-K salt. According to the GB/T18261-2000 and LY/T1283-1998, wood preservative performance of HK-K salt was tested. The results showed that the best inhibitory concentration of HK-K salt was 50 mg/L, for which the prevention effectiveness on mold is better, the killed value is between 0 and 1, and the corrosion-resistant for wood-rotting fungi is grade A. 相似文献
74.
Guofeng Shen Miao Xue Siye Wei Yuanchen Chen Qiuyue Zhao Bing Li Haisuo Wu Shu Tao 《环境科学学报(英文版)》2013,25(9):1808-1816
Controlled combustion experiments were conducted to investigate the influence of fuel charge size, moisture, air ventilation and feeding rate on the emission factors (EFs) of carbonaceous particulate matter, parent polycyclic aromatic hydrocarbons (pPAHs) and their derivatives from residential wood combustion in a typical brick cooking stove. Measured EFs were found to be independent of fuel charge size, but increased with increasing fuel moisture. Pollution emissions from the normal burning under an adequate air supply condition were the lowest for most pollutants, while more pollutants were emitted when an oxygen deficient atmosphere was formed in the stove chamber during fast burning. The impacts of these factors on the size distribution of emitted particles was also studied. Modified combustion efficiency and the four investigated factors explained 68%, 72%, and 64% of total variations in EFs of PM, organic carbon, and oxygenated PAHs, respectively, but only 36%, 38% and 42% of the total variations in EFs of elemental carbon, pPAHs and nitro-PAHs, respectively. 相似文献
75.
有机负荷对醋糟厌氧消化系统启动的影响 总被引:2,自引:2,他引:0
本研究通过醋糟的中温产甲烷潜力测试实验,考察了有机负荷对醋糟厌氧消化反应器启动的影响.并通过对不同有机负荷条件下的甲烷产量、液相组分的对比分析,结合热重、X射线衍射和红外光谱学方法进行差异表征,结果发现:1较低的有机负荷有利于缓解醋糟中有机物水解酸化过程中VFAs的积累和pH的下降,保证产甲烷过程的稳定进行.当接种物与基质VS比为1∶1[即有机负荷(以VS计)为1.78 g·(L·d)~(-1),pH=7.60]时的累积甲烷产量最高,达2 249.7 m L.随着有机负荷的提高,VFAs的累积浓度随之升高,使产甲烷过程受到不同程度的抑制并相继终止,且在接种物与基质VS比为1∶4时[即有机负荷为7.12 g·(L·d)~(-1),pH=5.52]实现了乙酸和乳酸的同步发酵(分别可达到8 000 mg·L~(-1)和2 650 mg·L~(-1)).2醋糟中木质纤维素类物质为短程有序的微晶结构或非晶结构,与富含纤维素类晶体结构物质的玉米秸秆等相比,其VS的降解率更高.醋糟中的木质素、纤维素、半纤维素的降解率随着有机负荷的降低而逐渐升高. 相似文献
76.
醋糟高效厌氧消化体系构建 总被引:4,自引:0,他引:4
运用高固态厌氧消化模式,通过提高反应体系均质程度和沼液回流等手段,逐步提升物料负荷,对未经预处理的醋糟进行厌氧消化处理,成功构建了醋糟高效厌氧消化体系.结果表明,在反应体系物料负荷达到6.15 g·(L·d)~(-1)时表现出最佳的厌氧消化性能,单位干物料产沼气量为396 m L·g~(-1),单位干物料产甲烷量为211 m L·g~(-1).该物料负荷下半纤维素降解率达到63.66%,是醋糟厌氧消化性能提高的主要原因.纤维素、木质素的降解率分别为21.46%、24.43%,较低的降解效率主要是由于木质素中的苯环结构难以降解,并阻碍纤维素酶的水解作用,对纤维素降解产生屏蔽效应. 相似文献
77.
Roger A. Nichols Gary L. Ketcheson 《Journal of the American Water Resources Association》2013,49(6):1367-1384
A federal, state, and private partnership leveraged resources and employed a long‐term, systematic approach to improve aquatic habitat degraded by decades of intensive forest management in Finney Creek, a tributary to the Skagit River of Northwest Washington State. After more than a decade of work to reduce sediment sources and the risk of landslides within the watershed, log jam installation commenced in 1999 and progressed downstream through 2010. Log jam design was adapted as experience was gained. A total of 181 log jams, including 60 floating log ballasted jams, were constructed along 12 km of channel. The goal was to alter hydraulic processes that affect aquatic habitat formation along 39 km of stream with emphasis on 18.5 km of lower Finney Creek. Aquatic habitat surveys over a five‐year period show an increase in the area of large pools and an accompanying increase in residual and maximum pool depth in the lower river reach. Channel cross sections show a generally deeper channel at the log jams, better channel definition in the gravel deposits at the head of the log jams, and improved riffle and thalweg development below the log jams. Stream temperature in the upper river decreased by 1.0°F in the first three years, and 1.1°F in the lowest treated reach over nine years. There is a trend of less stream heating over the restoration time period. Photo points show that riparian vegetation is recolonizing gravel bars. 相似文献
78.
Biomarkers are widely known to occur in the fossil record, but the unaltered biomolecules are rarely reported from sediments
older than Paleogene. Polar terpenoids, the natural products most resistant to degradation processes, were reported mainly
from the Tertiary conifers, and the oldest known are Cretaceous in age. In this paper, we report the occurrence of relatively
high concentrations of ferruginol derivatives and other polar diterpenoids, as well as their diagenetic products, in a conifer
wood Protopodocarpoxylon from the Middle Jurassic of Poland. Thus, the natural product terpenoids reported in this paper are definitely the oldest
polar biomolecules detected in geological samples. The extracted phenolic abietanes like ferruginol and its derivatives (6,7-dehydroferruginol,
sugiol, 11,14-dioxopisiferic acid) are produced only by distinct conifer families (Cupressaceae s. l., Podocarpaceae and Araucariaceae),
to which Protopodocarpoxylon could belong based on anatomical characteristics. Therefore, the natural product terpenoids are of great advantage in systematics
of fossil plant remains older than Paleogene and lacking suitable anatomical preservation. 相似文献
79.
基于UD-PLS对牛粪堆制Cu和Zn钝化预测模型的研究 总被引:1,自引:0,他引:1
选取钝化材料木醋液和影响堆肥质量的关键因素:含水量和C/N,每个因素安排6个水平,利用均匀设计进行多因素多水平试验,对试验结果进行偏最小二乘回归分析,建立对重金属的钝化预测模型.结果表明:木醋液添加比例为0.50%、含水量为40%和C/N为40时,Cu和Zn的钝化效果均达到最大值,分别为13.5%和30.2%;其中重金属Cu的钝化预测模型为 ,其中交叉有效性为 ,模型达到精度要求;重金属Zn的钝化预测模型为 ,其中交叉有效性为 ,模型达到精度要求.针对多因素多水平的复杂堆肥系统中,将均匀设计与偏最小二乘法有机耦合,有效地解决了试验次数多、因素间多重相关性的问题,从而使模型精度和实用性都得到提高. 相似文献
80.