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81.
Arsenic in groundwaters of the Lower Mekong 总被引:1,自引:0,他引:1
Stanger G Truong TV Ngoc KS Luyen TV Thanh TT 《Environmental geochemistry and health》2005,27(4):341-357
Increasing incidence and awareness of arsenic in many alluvial aquifers of South-east Asia has raised concern over possible
arsenic in the Lower Mekong Basin. Here, we have undertaken new research and reviewed many previous small-scale studies to
provide a comprehensive overview of the status of arsenic in aquifers of Cambodia and the Cuu Long Delta of Vietnam. In general
natural arsenic originates from the Upper Mekong basin, rather than from the local geology, and is widespread in soils at
typical concentrations of between 8 and 16 ppm; (dry weight). Industrial and agricultural arsenic is localised and relatively
unimportant compared to the natural alluvial arsenic. Aquifers most typically contain groundwaters of no more than 10 μg L−1, although scattered anomalous areas of 10 to 30 μg L−1 are also quite common. The most serious, but possibly ephemeral arsenic anomalies, of up to 600 μg L−1, are associated with iron and organic-rich flood-plain sediments subject to very large flood-related fluctuations in water
level, resulting in transient arsenopyrite dissolution under oxidizing conditions. In general, however, high-arsenic groundwaters
result from the competing interaction between sorption and dissolution processes, in which arsenic is only released under
reducing and slightly alkaline conditions. High arsenic groundwaters are found both in shallow water-tables, and in deeper
aquifers of between 100 and 120 m depth. There is no evidence of widespread arsenicosis, but there are serious localised health-hazards,
and some risk of low-level arsenic ingestion through indirect pathways, such as through contaminated rice and aquaculture.
An almost ubiquitous presence of arsenic in soils, together with the likelihood of greatly increased groundwater extraction
in the future, will require continuing caution in water resources development throughout the region. 相似文献
82.
含砷废水净化剂的制备及其应用研究 总被引:1,自引:0,他引:1
本文描述了用黄铁矿和还原铁粉或其代用品为原料制备含砷废水净化剂-硫化亚铁的新方法,获得了制备的最佳条件,探讨了其在含砷废水处理中的应用条件和影响因素,结果表明,该净化剂的生产及其处理含砷废水的工艺简单,经济高效,具有良好的开发应用前景。 相似文献
83.
Palumbo-Roe B Cave MR Klinck BA Wragg J Taylor H O'Donnell KE Shaw RA 《Environmental geochemistry and health》2005,27(2):121-130
Jurassic ironstones outcropping over parts of eastern England give rise to soils with arsenic concentrations in excess of
the UK soil guideline value of 20 mg kg−1 for residential areas. Total arsenic concentrations were determined for 73 ironstone derived soils and bioaccessible arsenic
determined using an in vitro physiologically based extraction test. The bioaccessible arsenic concentration for these soils was found to be well below
the soil guideline value with a mean concentration of 4 mg kg−1 and a range of 2–17 mg kg−1. The bioaccessible fraction ranges from 1.2 to 33%. Data from a sequential extraction test based on the use of aqua regia
as the main extractant is presented for a subset of 20 of the soils. Chemometric data reduction is used to demonstrate that
the bioaccessible arsenic is mainly contained within calcium iron carbonate (sideritic) assemblages and only partially iron
aluminosilicates, probably berthierine, and iron oxyhydroxide phases, probably goethite. It is suggested that the bulk of
the non-bioaccessible arsenic is bound up with less reactive iron oxide phases. 相似文献
84.
85.
This paper reports on the major cations(Ca, Mg, Na and K) and arsenic(As) compositions of surface waters collected from major creeks, rivers and lakes in Central Victoria (Australia). The surface waters were found to be neutral to alkaline (pH 6.7-9.4), oxidised (average redox potential (Eh) about 130 mV) and showed variable concentrations of dissolved ions (EC, about 51-4386 /μS/cm). The concen- trations of dissolved major cations in surface waters were found to be in the order of Na〉〉Mg〉Ca〉K and in soils the contents of metals followed an order of abundance as: Ca〉Mg〉〉K〉Na. While Na was the least abundant in soils, it registered the highest dissolved cation in surface waters. Of the four major cations, the average concentration ofNa(98.7 mg/L) was attributed to the weathering of feldspars and atmospheric input. Relatively highly dissolved concentrations of Na and Mg compared with the world average values of rivers reflected the weathering of rock and soil minerals within the catchments.
The As soil level is naturally high(linked to lithology) as reflected by high background soil values and mining operations are also considered to be a contributory factor. Under relatively alkaline-oxidative conditions low mobility of dissolved As (average about 7.9 μg/L) was observed in most of the surface waters with a few higher values(〉15 μg/L) around a sewage disposal site and mine railings. Arsenic in soils is slowly released into water under alkaline and/or lower Eh conditions. The efficient sink of Fe, AI and Mn oxides acts as a barrier against the As release under near neutral-oxidising conditions. High As content (average about 28.3 mg/kg) in soils was found to be associated with Fe-hydroxides as revealed by XRD and SEM analysis. The dissolved As concentration was found to be below the recommended maximum levels for recreational water in all surface waters(lakes and rivers) in the study area. Catchment lithology exerted the fundamental control on surface water chemistry. Sites impacted by mining waste dumps showed a decline in water quality. 相似文献
86.
根据污染源现场调研结果,结合现有污染控制工艺所能达到的技术水平,建议污水排放标准中As浓度由现国家排放标准的0 5mg/L调整为0 1mg/L;Pb不变为1 0mg/L。大气污染物排放标准中As和Pb不变为1 0mg/L。大气污染物排放标准As和Pb的浓度限值分别是为0 5mg/m3和0 7mg/m3。 相似文献
87.
88.
89.
高温下氧化焙烧细磨后的砷华生产废渣,利用软锰矿浆吸收产生的SO2气体,吸收液经净化除杂、浓缩结晶等工序可制备工业产品硫酸锰。适宜的焙烧条件如下:焙烧温度为650℃,焙烧时间为60min,废渣粒度为-97μm。选择合适的吸收工艺,Mn的浸出率可达96.20%,此时SO2脱除率为87.20%。 相似文献
90.
土壤砷与土壤微生物相互作用是土壤砷形态转化中需要重点关注的内容之一.为了研究砷氧化菌对胡敏酸络合三价砷[HA-As(Ⅲ)]的作用,设置了不同p H值反应体系,研究砷氧化菌HN-2对HA-As(Ⅲ)作用下,砷的形态变化及其在固液两相中的分配.结果表明,在HA与As(Ⅲ)络合过程中,HA可以将一部分游离态As(Ⅲ)氧化为As(Ⅴ).其中,在p H=7的体系中,As(Ⅲ)被HN-2和HA氧化成As(Ⅴ)的效率最高.在含有砷氧化菌株和不含砷氧化菌株的体系中,0~10 h振荡过程中,HA-As材料均可以释放一部分As(Ⅲ)及As(Ⅴ)进入液相中,同时砷氧化菌可以快速地将As(Ⅲ)氧化为As(Ⅴ),而胡敏酸可以较缓慢地将As(Ⅲ)氧化为As(Ⅴ);反应10~24 h期间,HN-2砷氧化菌可以将络合态HA-As(Ⅲ)转化为游离态As(Ⅲ)并氧化为As(Ⅴ);48 h后反应逐渐达到平衡.固相同步辐射结果可以进一步证明HN-2砷氧化菌对络合态As(Ⅲ)的释放及氧化作用. 相似文献