常压法测定煤层瓦斯含量的误差分析

为了校正脱气法和常压法测量瓦斯含量的误差。通过理论分析、模型计算和实验对比的方法，研究煤样气体自然成分含二元和三元混合气体时的误差来源。查明气体成分为N2和CH4时，该误差可通过系数法进行修正；气体成分含CO2,CH4和N2 3种气体时，误差可通过扩展的langmuir模型修正。水分对测定误差的影响为:烟煤中含氧官能团与水优先结合后，影响煤孔网吸附点的可达性，导致水分与测定误差线性相关；无烟煤表面积大且表面官能团减少，水分的优先吸附使煤表面性质更均匀，水分与气体分子竞争煤表面的相同吸附点，水分与测定误差负相关。该结论对煤层瓦斯含量测定方法的选择和修正有重要意义。     

Morphological plasticity of submerged macrophyte Potamogeton wrightii Morong under different photoperiods and nutrient conditions

The morphological plasticity of the submerged macrophyte Potamogeton wrightii under different nutrient conditions and photoperiods was measured in a laboratory controlled experiment for 70 days in Japan. Six treatments were used in this experiment (3 × 2 factorial design with three replications) which consisted of three photoperiods and two nutrient conditions. Both photoperiod and nutrient condition had a pronounced effect on shoot and leaf morphology in P. wrightii. New shoot recruitment, and the length of main and new shoots gradually decreased with shortening photoperiod under both nutrient treatments. Plants under an 8 h photoperiod and high nutrient levels generated significantly more dead leaves (7.42 leaf·shoot^?1) and decomposed shoots (1.3 shoots·pot^?1) than plants under other treatments. Under short photoperiods (12 and 8 h) plants failed to produce flowering spikes in both nutrient conditions. In high nutrient conditions, P. wrightii produced shorter shoots, fewer leaves with shorter and narrower laminas, and smaller petioles compared with plants in the low nutrient condition. This may be adaptive under high nutrient conditions because it lowers foliar uptake and, thus, nutrient toxicity.     

利巴韦林对4种作物种子发芽的影响

利巴韦林作为一种强效抗病毒药物在畜禽养殖业中应用广泛,有着较高的生态环境风险。采用室内培养箱培养的方法,研究了利巴韦林对4种作物(小麦、白菜、萝卜和番茄)的种子发芽、根伸长和芽伸长的影响。结果表明,利巴韦林对4种作物的种子发芽率影响不大,但其浓度与4种作物的根伸长及芽伸长抑制率显著相关(P<0.01或P<0.05),作物的根伸长比芽伸长对利巴韦林的胁迫更敏感。土壤中利巴韦林浓度与4种作物根伸长抑制率之间呈现正相关关系。根伸长的抑制率达到10%所对应的利巴韦林浓度(IC10)分别为:IC10(白菜)=4.25mg·kg-1,IC10(番茄)=29.7mg·kg-1,IC10(萝卜)=33.2mg·kg-1,IC10(小麦)=49.4mg·kg-1。可以看出,4种作物对土壤中利巴韦林胁迫的敏感性依次是:白菜>番茄>萝卜>小麦。从利巴韦林对4种作物的根伸长和芽伸长抑制率综合来看,小麦对利巴韦林的耐受性最强,而白菜对利巴韦林最敏感。     

环丙沙星对3种作物的毒性

为了研究环丙沙星对作物的毒性效应,为其可能对农业生产带来的风险提供评价依据,采用急性毒性实验方法,研究了环丙沙星对3种作物(玉米、萝卜和小白菜)种子发芽、根伸长及芽伸长的影响。结果表明,在环丙沙星作用下,3种作物的根伸长抑制率和芽伸长抑制率与药物浓度显著相关(P<0.05),发芽抑制率与药物浓度不相关(P>0.05);药物对根伸长及芽伸长的抑制高于对种子发芽的抑制;环丙沙星对玉米、萝卜和小白菜的根伸长和芽伸长的ID50(抑制率为50%时污染物浓度)分别为7.97、2.51、1.48mg·kg-1和11.23、2.90、1.95mg·kg-1,3种作物在环丙沙星的胁迫下,其敏感性顺序为:小白菜>萝卜>玉米。     

新常态下山东省环境规制对工业结构调整及其大气环境效应研究

论文利用动态面板的系统GMM估计方法、LMDI分解模型、历史值外推模拟及线性规划约束模型等探究了新常态下山东省环境规制对工业结构调整的影响及其大气环境效应,得到以下结论：1）2001—2013年,山东省工业比重呈现先上升后下降的趋势,污染密集型行业比重整体呈现先下降后上升的趋势,二者的环境规制强度基本呈上升趋势;2）环境规制对山东省工业比重、污染密集型行业比重和高新技术产业比重的影响系数分别为-0.043、-0.451和0.523,说明山东省环境规制的实施对工业结构的优化调整具有正向作用;3）随着山东省环境规制强度的增加,工业结构效应和技术效率效应抑制了大气污染物排放量的增加,而污染密集型行业结构效应虽然是工业结构减排的主要原因,但其减排绝对量较小;4）对比宽松、适度、严格3种环境规制情景下的预测结果,新常态下山东省工业结构的调整力度和大气污染物减排潜力依次增大。值得指出的是,适度环境规制下山东省工业结构调整更有利于经济社会的可持续发展。     

磷酸三(1,3-二氯-2-丙基)酯对L-02肝细胞氧化应激及凋亡损伤机制

在各类环境介质及生物体甚至人体中都检测到有机磷阻燃剂磷酸三(1,3-二氯-2-丙基)酯(tris(1,3-dichloro-2-propyl)phosphate,TDCPP)的存在,为探究TDCPP对人体健康的毒性作用,选取人体正常肝细胞L-02细胞作为模型,考察在体外暴露条件下TDCPP对L-02细胞的细胞存活率、凋亡、氧化应激以及p53通路相关基因方面的影响。MTT结果显示,24 h、48 h、72h的半数致死浓度(LC50)分别为:116.56μmol·L~(-1)、81.89μmol·L~(-1)、65.11μmol·L~(-1)。TDCPP暴露24 h条件下,随着TDCPP暴露浓度的增加,细胞的凋亡率和活性氧(reactive oxygen species,ROS)水平也逐渐增加,100μmol·L~(-1)浓度条件下凋亡高达25.58%±1.61%,ROS水平是对照组的2.07±0.07倍。实时荧光定量PCR法检测线粒体凋亡通路相关基因的表达情况,在TDCPP刺激下,Bax、caspase-3、caspase-9、p53和Apaf-1相对表达量增加,Bcl-2相对表达量减少。蛋白免疫印迹法检测发现Bax/Bcl-2和caspase-3均随浓度增加而递增。本研究为综合评估TDCPP的生物和环境健康毒理效应提供了实验数据及理论支持。     

低温供热堆选址阶段的环境影响评价与分析

根据低温供热堆选址阶段环境影响评价的要求,结合工程具体设计方案,对低温供热堆在正常运行和事故工况下可能造成的环境影响进行分析、预测与评价,以作为审管当局决策的重要依据。低温供热堆在正常运行状态时,放射性气载流出物在大气中迁移和扩散及对公众的辐射剂量估算采用的是IAEA安全系列19号报告中给出的筛选模式(稀释模式);事故工况下保守考虑全堆熔事故作为选址假想事故,采用USNRC RG1.4中给出的最大可信事故(30d)的大气扩散因子计算方法,估算假想事故各时段的大气扩散因子。正常运行工况下,在半径1km的环形区域内烟囱排放和蒸发池排放叠加的最大个人有效剂量为7.84×10^-6 Sv/a,小于本工程对公众的剂量约束值0.03mSv/a;事故工况下,两厂址所致公众个人(成人)在整个事故持续时间内厂址边界处(150m)最大个人有效剂量为5.66mSv,甲状腺当量剂量为7.43mSv,均小于《小型压水堆核动力厂安全审评原则(试行)》要求。低温供热堆在正常运行和事故工况下,对周围环境和公众的影响均满足参考的相关标准要求,是可以接受的。     

粉煤灰复合材料砖的研制

提出了在常温下以粉煤灰为主要原料，研制高强度复合材料的方法。探讨了物料的成分配比、混料、成型和干燥的过程参数，并确定了材料的各项性能指标。     

SPATIAL VARIABILITY OF RANGELAND INFILTRATION RATES1

ABSTRACT: Spatial variability of infiltration rates was examined for a site in southern Idaho. Data used represented 13 sampling dates over a 5-year period. Samples initially were taken within a native big sagebrush community, again after plowing and seeding to crested and intermediate wheatgrass, and then while the seeded area was being grazed by domestic livestock. Results indicate that either a normal or log normal distribution may be adequate for describing measured infiltration rates.     

STOCHASTIC FLOW DURATION CURVES FOR EVALUATION OF FLOW REGIMES IN RIVERS1

ABSTRACT: A stochastic estimation of low flow in the upper reaches of streams is needed for the planning, development, and management of water resources and/or water use systems. In this paper, the definition and development procedure for the stochastic flow duration curve is presented and applied to five catchments located in eastern Japan and to two catchments in western Thailand. The probability distribution of N‐year daily discharge data is extracted at various percentages of time for which specified discharges are equaled or exceeded in a water year. Such a distribution is usually represented with a straight line on log‐normal probability paper. However, some of the probability plots for the annual minimum daily discharge are best represented with a straight line on Weibull probability paper. The effectiveness of the stochastic flow duration curve defined for the evaluation of flow regime is illustrated through its application. The ten year probability for the discharge exceeded 97 percent of the time may be recognized as an index of low flow. The recession shape of the lower part of the flow duration curve is dependent on the strength of low flow persistence.