气相分子吸收光谱法测定海水中氨氮的干扰因素识别及预处理方法研究

采用气相分子吸收光谱法测定海水样品中的氨氮,重点考察海水中共存离子对氨氮测定结果的影响规律,识别测定过程中主要的干扰因素,并提出消除干扰的预处理方法.研究结果表明,碘离子会对氨氮的测定产生负干扰,当样品中碘离子质量浓度达到0.0765 g/L时,氨氮的测定结果与标准值相比明显降低,且在碘离子质量浓度达到0.1910 g...     

Tracing the impact of stack configuration on interface resistances in reverse electrodialysis by in situ electrochemical impedance spectroscopy

• RED performance and stack resistance were studied by EIS and LSV. • Interface resistance were discriminated from Ohmic resistance by EIS. • Impacts of spacer shadow effect and concentration polarization were analyzed. • Ionic short current reduced the power density for more cell pairs. • The results enabled to predict RED performance with different configurations. Reverse electrodialysis (RED) is an emerging membrane-based technology for the production of renewable energy from mixing waters with different salinities. Herein, the impact of the stack configuration on the Ohmic and non-Ohmic resistances as well as the performance of RED were systematically studied by using in situ electrochemical impedance spectroscopy (EIS). Three different parameters (membrane type, number of cell pairs and spacer design) were controlled. The Ohmic and non-Ohmic resistances were evaluated for RED stacks equipped with two types of commercial membranes (Type I and Type II) supplied by Fujifilm Manufacturing Europe B.V: Type I Fuji membranes displayed higher Ohmic and non-Ohmic resistances than Type II membranes, which was mainly attributed to the difference in fixed charge density. The output power of the stack was observed to decrease with the increasing number of cell pairs mainly due to the increase in ionic shortcut currents. With the reduction in spacer thickness from 750 to 200 µm, the permselectivity of membranes in the stack decreased from 0.86 to 0.79 whereas the energy efficiency losses increased from 31% to 49%. Overall, the output of the present study provides a basis for understanding the impact of stack design on internal losses during the scaling-up of RED.     

Dust cloud evolution and flame propagation of organic dust deflagration under low wall influence

The present study discusses experiments on organic dust explosions in a setup with low wall influence. The proposed apparatus decouples the dust dispersion and the deflagration event in two separate compartments. The use of a continuous-wave laser to illuminate the centre plane of the observation chamber allows capturing both, the dust cloud and the flame during the same experiment and eliminates typical problems caused by the limited dynamic range of high-speed cameras. A k-means clustering method is used for image segmentation to obtain the spatial extent and the propagation velocities of the unreacted particle cloud and the flame zone. Spatially resolved velocities are calculated by the additional use of an optical flow method. The main goal of the presented setup and image processing method is to provide high quality validation data for the development of numerical models on dust deflagration.     

一种新型光路设计在重金属分析仪中的应用

针对在线重金属分析仪中电源波动、水体浊度等干扰问题,提出一种新型的光路设计方案。实验表明,采用该设计的在线水质分析仪PhotoTek 6000的抗干扰能力大大提高,电源稳定性达到0.6%;同时当试样中浊度变化4个数量级时,测量结果与实际值的相对偏差小于2%。     

Rainwater harvesting planning using geospatial techniques and multicriteria decision analysis

Growing water scarcity and global climate change call for more efficient alternatives of water conservation; rainwater harvesting (RWH) is the most promising alternative among others. However, the assessment of RWH potential and the selection of suitable sites for RWH structures are very challenging for the water managers, especially on larger scales. This study addresses this challenge by presenting a fairly robust methodology for evaluating RWH potential and identifying sites/zones for different RWH structures using geospatial and multicriteria decision analysis (MCDA) techniques. The proposed methodology is demonstrated using a case study. The remote sensing data and conventional field data were used to prepare desired thematic layers using ArcGIS© software. Distributed Curve Number method was used to calculate event-based runoffs, based on which annual runoff potential and runoff coefficient maps were generated in the GIS (geographic information system) environment. Thematic layers such as slope, drainage density, and runoff coefficient and their features were assigned suitable weights and then they were integrated in a GIS to generate a RWH potential map of the study area. Zones suitable for different RWH structures were also identified, together with suitable sites for constructing recharge structures (check dams and percolation tanks along the streams). It was found that the study area can be classified into three RWH potential zones: (a) ‘good’ (241 km²), (b) ‘moderate’ (476 km²), and (c) ‘poor’ (287 km²). About 3% of the study area (30 km²) is suitable for constructing farm ponds, while percolation tanks (on the ground) can be constructed in about 2.7% of the area (27 km²). Of the 83 sites identified for the recharge structures, 32 recharge sites are specially suited to the inhabitants because of their proximity. It is concluded that the integrated geospatial and MCDA techniques offer a useful and powerful tool for the planning of rainwater harvesting at a basin or sub-basin scale.     

PM2.5手工监测技术要点探讨

以重量法为原理的手工监测法是国内外监测环境空气PM2.5质量浓度的标准方法,在空气质量监测中具有重要应用。该文以2012年跨4个季度近150 d的PM2.5手工监测实际操作经验为基础,重点探讨了手工监测法各环节的监测技术要点,如手工监测采样器的操作技术、滤膜种类的选择及前处理要求、滤膜更换技术、滤膜平衡和称重条件、质量保证和质量控制技术等,以期为推广PM2.5手工监测法提供技术参考。     

环境样品中农药的前处理及检测技术研究进展

综述了近年来农药环境样品的前处理及检测技术,介绍了各种前处理和检测技术的应用情况,在此基础上对环境中残留农药的前处理及检测技术的发展进行了展望.     

气相分子吸收光谱法测定水中氨氮干扰因素的研究

气相分子吸收光谱法测定成分复杂氨氮实际样品时,干扰因素造成测定结果不准确,而现有的标准方法和文献对干扰物质的研究不全面,制约了仪器的应用。该文系统地开展干扰因素的研究,提出干扰因素的消除方法,用加标回收率验证消除的有效性。结果表明,亚硫酸盐、硫化物等还原性物质对测定产生负干扰;石油烃、N,N-二甲基甲酰胺(DMF)等挥发性有机物、有机胺类以及亚硝酸盐对测定产生正干扰。根据不同干扰类型,通过加入适量酸性重铬酸钾溶液、在酸性条件下加热煮沸、预蒸馏等方法可消除干扰,消除干扰后加标回收率为84%~120%。生活污水、石化企业废水等6种典型水样消除干扰后,气相分子吸收光谱法和纳氏试剂分光光度法测定氨氮有较好的可比性,干扰消除方式有效。     

Spectroscopic characterization and photochemistry of the Criegee intermediate CF3C(H)OO

Criegee intermediates (CIs), also known as carbonyl oxide, are reactive intermediates that play an important role in the atmospheric chemistry. Investigation on the structures and reactivity of CIs is of fundamental importance in understanding the underlying mechanism of their atmospheric reactions. In sharp contrast to the intensively studied parent molecule (CH₂OO) and the alkyl-substituted derivatives, the knowledge about the fluorinated analogue CF₃C(H)OO is scarce. By carefully heating the triplet carbene CF₃CH in an O₂-doped Ar-matrix to 35 K, the elusive carbonyl oxide CF₃C(H)OO in syn- and anti-conformations has been generated and characterized with infrared (IR) and ultraviolet-visible (UV-vis) spectroscopy. The spectroscopic identification is supported by ¹⁸O-labeling experiments and quantum chemical calculations at the B3LYP/6-311++G(3df,3pd) and MP2/6-311++G(2d,2p) levels. Upon the long-wavelength irradiation (λ > 680 nm), both conformers of CF₃C(H)OO decompose to give trifluoroacetaldehyde CF₃C(H)O and simultaneously rearrange to the isomeric dioxirane, cyclic-CF₃CH(OO), which undergoes isomerization to the lowest-energy carboxylic acid CF₃C(O)OH upon UV-light excitation at 365 nm. The O₂-oxidation of CF₃CH via the intermediacy of CF₃C(H)OO and cyclic-CF₃CH(OO) might provide new insight into the mechanism for the degradation of hydro-chlorofluorocarbon CF₃CHCl₂ (HCFC-123) in the atmosphere.