新型绿色化学反应介质的研究进展

综述了绿色化学在反应介质方面的研究进展。新型的有机合成反应介质主要包括离子液体、超临界流体、水溶剂及微波无溶剂技术。这些新型反应介质不仅可以取代传统的挥发性有毒有害有机溶剂,同时还可提高反应的活性和选择性,加速反应的进行,且有利于催化剂的回收利用及产品的分离。新型绿色化学反应介质是实现有机合成绿色化的重要途径。     

液体浮选法回收废旧电脑线路板中铜的研究

本文用物理及化学方法研究了废旧电脑线路板的处理回收工艺.首先通过粉碎机将线路板破碎,在不同破碎时间和转速下,对筛分后各粒级的产物作累积产率曲线,得到理想的破碎时间和转速,然后利用液体对破碎的物料进行浮选,量化分析铜与非金属的解高程度,最后通过碘量法检测浮选后铜的回收情况.实验结果表明:在R＞2000 rpm的条件下线路板粉碎120s,采用三溴甲烷作浮选液,进行液体浮选,在dp＜0.074 mm的细粒级中,主要是玻璃纤维和碳化硅等非金属物质,线路板中的铜主要富集在0.84～0.125 mm粒级中,在0.84～0.42 mm粒级中,铜的回收率可达到97.89%.     

重金属离子-二乙基二硫代氨基甲酸钠螯合体系的HPLC分析方法研究

采用二乙基二硫代氨基甲酸钠(NaDDC)为螯合剂,对Cu(Ⅱ)、Hg(Ⅱ)、Pb(Ⅱ)、Zn(Ⅱ)、Cd(Ⅱ)、Cr(Ⅵ)六种重金属离子进行了螯合萃取分离体系的方法研究,用HPLC方法建立了上述金属离子的最佳分离条件及定性定量分析方法.结果表明,用C18反相柱(5μm,150×4.6mmi.d.)和流动相(V(乙腈):V(甲醇):V(水)=55:15:30)能有效分离上述重金属离子,最低检测限在0.1～1.6ng范围内,线性范围及线性关系满足定量分析要求.     

五日生化需氧量(BOD5)测定方法探讨

本文针对GB／T7488-1987《水质五日生化需氧量(BOD5)稀释与接种法》中BOD5的测定和计算时接种稀释水的空白扣除方法，提出了直接测接种液的BOD5值，按接种液的比例在水样中进行扣除的方法，提高了BOD5值的准确性。更能反应BOD5的真实性。     

Assessment of the maximum possible liquid superheat during flashing leak flow

During the discharge of flashing liquids through leaks due to abrupt depressurization a transient thermodynamic non-equilibrium in the form of a boiling delay in the superheated liquid flow can occur. As a consequence the actual mass flow quality is smaller than calculated under the assumption of an immediate adjustment of the thermodynamic equilibrium between the phases. For the prediction of the leak mass flow for a given pressure difference the magnitude of this self-adjusting mass flow quality is needed.

Most of the models cited in the literature include only the equilibrium mass quality as limiting quantity and ignore further effects as that of the depressurization velocity or the mean nucleus distance. For the assessment of the maximum possible liquid superheat during flashing only the conduction heat transfer from a stagnant liquid to the bubble surface is used to describe the bubble growth.

The sub-model for the bubble growth due to expansion and mass transfer necessary for the global prediction of the transient thermodynamic non-equilibrium in flashing liquids was validated using bubble radii measured by Hooper et al. [Bubble growth and pressure relationship in the flashing of superheated water. Technical publication 6904, Mechanical Engineering Department, University of Toronto, 1969] for the case of a sudden depressurization of initially saturated water. On this basis the calculated time-dependent temperature field, the actual mass quality, the mean liquid temperature and, in comparison to the corresponding values based on the assumption of immediate thermodynamic equilibrium, the maximum possible liquid superheat are predicted.     

酒精废水消化液预处理试验研究

高浓度酒精糟液经厌氧生物处理后排出的消化液COD浓度为4500—6000mg/L，SS浓度高这1500—2．600mg,／L，且由于微小沼气泡附着在厌氧污泥上，沉降性能很差，难以与消化液相分离，对后续处理十分不剁。本研兜采用预曝气．化学混凝沉淀组合工艺，对该消化液进行去除高浓度SS的顸处理试验，研究探讨了曝气时间、混凝剂种类和投加量对SS和COD去除效果的影响。试验结果表明，预曝气．化学混凝沉淀组合工艺对消化液SS的去除效果十分显著。当预曝气时间为6．0h，FeCl3投加量为100mg/L时，消化液的SS去除率75．4％，COD去除率24．3％，可为后续的好氧生物处理提供较为有利的水质和负荷条件。     

On the response of 500 gal propane tanks to a 25% engulfing fire

This paper presents detailed data on the thermal response of two 500 gal ASME code propane tanks that were 25% engulfed in a hydrocarbon fire. These tests were done as part of an overall test programme to study thermal protection systems for propane-filled railway tank-cars.

The fire was generated using an array of 25 liquid propane-fuelled burners. This provided a luminous fire that engulfed 25% of the tank surface on one side. The intent of these tests was to model a severe partially engulfing fire situation.

The paper presents data on the tank wall and lading temperatures and tank internal pressure. In the first test the wind reduced the fire heating and resulted in a late failure of the tank at 46 min. This tank failed catastrophically with a powerful boiling liquid expanding vapour explosion (BLEVE). In the other test, the fire heating was very severe and steady and this tank failed very quickly in 8 min as a finite rupture with massive two-phase jet release. The reasons for these different outcomes are discussed. The different failures provide a range of realistic outcomes for the subject tank and fire condition.     

液化气运输过程中的危险分析

应用各种爆炸后果估计模型对液化气运输过程中的爆炸后果进行了评估，并用ETA分析方法对存在的危险进行了分析，指出了控制措施。     

顶空气相色谱法测定食品中甜蜜素含量

采用顶空气相色谱法测定食品中甜蜜素含量,探讨了气液相平衡条件及色谱条件的选择,实验结果表明甜蜜素的标准溶液在0.1-0.4μg/l范围内具有良好的线性关系,回收率为87.5%-101.8%,相对标准偏差为2.6%.     

利用餐厨垃圾湿热处理脱出液制备液态菌肥研究

以餐厨垃圾湿热处理脱出液为发酵培养基,选用圆褐固氮菌(Azotobacter chroococcum)作为实验菌种制作固氮液态菌肥。测定了圆褐固氮菌的主要生理特性,将其接种于餐厨湿热处理脱出液中进行培养,确定最佳发酵时间,并分别测定发酵的最佳初始p H值、接种量、培养温度、摇床转速、装液量、脱出液与水的混合比例。结果表明:圆褐固氮菌在餐厨湿热处理脱出液中最佳发酵时间为36 h,发酵最佳初始p H值、接种量、培养温度、摇床转速、装液量、脱出液与水的混合比例依次为7.5、1%、30℃、150 r/min、50 m L(250 m L锥形瓶)、1∶1。圆褐固氮菌在餐厨垃圾湿热处理脱出液中进行培养后,可达到液态菌肥的活菌数标准。