Modeling Flow Through a One-Dimensional Multi-Layered Soil Profile Using the Method of Lines

The vertical flow of water through horizontal layers of soil is considered using the Method of Lines. Continuity of mass principles are used to develop the interface boundary conditions, by introducing fictitious points at the interface, and the boundary conditions are handled using explicit and iterative approximations. Both the pressure based, and the water content based forms of Richards' equation are solved using the Method of Lines. The solutions obtained are compared with some particular analytic solutions obtained from the literature, and the results show that good accuracy can be achieved. It is also shown that the water content model can handle a large discontinuity at the interface when compared against the analytical solution. This result is also confirmed against a numerical example from the literature, and was effective for relatively dry initial conditions.     

Initial Changes in Refilled Lysimeters Built with Metal Polluted Topsoil and Acidic or Calcareous Subsoils as Indicated by Changes in Drainage Water Composition

Soil translocation for recultivation of soil removed from construction sites and for the preparation of refilled lysimeters inevitably involves disturbance of soil structure, and, if intermediate storage is included, also drying and rewetting of the soil. We report on an experiment with model forest ecosystems, where uncontaminated forest subsoils were covered with non-contaminated or freshly heavy metal (mainly Zn and Cu) contaminated topsoil in large lysimeters. Monitoring of the chemical composition of the drainage water revealed two distinct soil conditioning phases. During an initial phase of about a year strongly elevated nitrate and sulfate concentrations occurred that were attributed to a mineralisation flush caused by the increased accessability of mineralisable nitrogen and sulfur in destroyed aggregates. These effects were significantly larger in lysimeters with calcareous subsoil than in those with acidic subsoil. The second phase was characterised by a gradual decrease in dissolved organic carbon and sulfate concentrations, in particular in the acidic subsoil. This decrease may be attributed to the depletion of pools made accessible during aggregate destruction or the formation of new aggregates. These chemical changes had only little effects on the concentrations of copper and zinc in the drainage water. Based on our results, it can be concluded that large refilled lysimeters can be used for many purposes without risk of compromised results, if a conditioning phase of about 1 year with sufficiently moist soil conditions is respected. Nevertheless, gradual changes in soil chemical characteristics still occur after this initial phase. Implications for the recultivation of sites using relocated soils are discussed.     

SnAgCu焊料中Sn元素在模拟土壤溶液中的浸出行为

研究了Sn-3.5Ag-0.75Cu无铅焊料及其与Cu基板的钎焊接头在模拟土壤的NaCl,NaCl-Na2SO4和NaCl-Na2SO4-Na2CO3溶液中Sn元素的浸出行为.结果表明:焊料在NaCl-Na2SO4-Na2CO3溶液中Sn的浸出相对严重;而接头在NaCl溶液中Sn的浸出量最多.在Sn浸出量多的焊料和接头表面形成厚而疏松的腐蚀产物,XRD分析表明其产物主要由SnO,SnO2和Sn4(OH)6Cl2组成.动电位极化测试分析表明接头中Cu基板与焊料合金之间的电偶腐蚀是焊料合金与接头在同种溶液中Sn元素浸出差异的主要原因.     

直升机机载产品环境鉴定试验故障分析

目的探究机载产品在鉴定试验阶段故障频发的原因,并改进机载产品研制流程中的不足之处。方法收集某型直升机机载产品50项环境鉴定试验故障,并对环境试验故障进行分析。结果环境试验故障主要为三防及振动试验故障,其故障发生的原因主要为材料及表面处理方法选用不当、设计缺陷和质量控制程序不够严格。结论针对该分析结果提出机载产品在设计过程中,需要通过尽早安排环境研制性试验、建立环境数据库、模拟仿真进行环境适应性设计和加强质量管理等措施,避免机载产品在鉴定试验阶段故障频发的问题。     

Using Ion-Exchange Resins to Study Soil Response to Experimental Watershed Acidification

Ion-exchange resins (IER) offer alternative approaches to measuring ionic movement in soils that may have advantages over traditional approaches in some settings, but more information is needed to understand how IER compare with traditional methods of measurement in forested ecosystems. At the Bear Brook Watershed in Maine (BBWM), one of two paired, forested watersheds is treated bi-monthly with S and N (28.8 and 25.2kgha⁻¹yr⁻¹ of S and N, respectively). Both IER and ceramic cup tension lysimeters were used to study soil solution responses after ∼11 years of treatment. Results from both methods showed treatments resulted in the mobilization of base cations and Al, and higher SO₄—S and inorganic N in the treated watershed. Both methods indicated similar differences in results associated with forest type (hardwoods versus softwoods), a result of differences in litter quality and atmospheric aerosol interception capacity. The correlation between lysimeter and IER data for individual analytes varied greatly. Significant correlations were evident for Na (r=0.75), Al (r=0.65), Mn (r=0.61), Fe (r=0.57), Ca (r=0.49), K (r=0.41) and NO₃—N (r=0.59). No correlation was evident between IER and soil solution data for NH₄—N and Pb. Both IER and soil solution techniques suggested similar interpretations of biogeochemical behavior in the watershed.     

ADSORPTION IN MULTICOMPONENT SOLUTION BY ACTIVATED CARBON

It was found that the total adsorptive capacity of activated carbon was enhanced by using a multicomponent solution with glucose, peptone and phenylphosphonic acid. A maximum use of the carbon adsorptive capacity is possible if the carbon is used for tertiary treatment followed by treating a stronger waste.     

Effect of humic substances on the precipitation of calcium phosphate

For phosphorus （P） recovery from wastewater, the effect of humic substances （HS） on the precipitation of calcium phosphate was studied. Batch experiments of calcium phosphate precipitation were undertaken with synthetic water that contained 20 mg/L phosphate （as P） and 20 mg/L HS （as dissolved organic carbon, DOC） at a constant pH value in the range of 8.0-10.0. The concentration variations of phosphate, calcium （Ca） and HS were measured in the precipitation process; the crystalline state and compositions of the precipitates were analysed by powder X-ray diffraction （XRD） and chemical methods, respectively. It showed that at solution pH 8.0, the precipitation rate and removal efficiency of phosphate were greatly reduced by HS, but at solution pH ≥9.0, the effect of HS was very small. The Ca consumption for the precipitation of phosphate increased when HS was added; HS was also removed from solution with the precipitation of calcium phosphate. At solution pH 8.0 and HS concentrations ≤3.5 mg/L, and at pH ≥ 9.0 and HS concentrations ≤ 10 mg/L, the final precipitates were proved to be hydroxyapatite （HAP） by XRD. The increases of solution pH value and initial Ca/P ratio helped reduce the influence of HS on the precipitation of phosphate.     

回收法氧化镁湿法烟气脱硫机理和工艺基础研究

以氧化镁浆液作为吸收液,对空气与SO₂混合气的鼓泡吸收做了全过程的实验观察.测试分析表明,在高效而稳定的脱硫过程中,吸收液的酸化是由HSO₃^-所致;酸化趋势与SO₂水解规律相一致,由初期高pH值下SO₃^2-为主的缓变到低pH值下HSO₃^-为主的剧变;吸收液温度对脱硫率的影响不敏感;MgSO₃相对高的溶解度和易氧化性及MgSO₄良好的水溶性保持了MgO脱硫的高效率(>98%)和高利用率.燃煤烟气脱硫工业试验确认了MgSO₄经吸收液循环可提浓至实验温度(40～50℃)下的饱和浓度而不产生有害影响,脱硫率因脱硫活性物质的富集反而提高,从而显示出回收工艺的技术经济可行性.     

Theoretical equation of gas desorption of particle coal under the non-uniform pressure condition and its analytical solution

Based on the second Fick’s law, the theoretical equation of gas desorption of particle coal under the non-uniform pressure condition was developed in this paper. The analytical solution of the theoretical equation and the method of gas desorption quantity of particle coal under non-uniform pressure condition were obtained.     

管制员安全能力模型研究

为准确评价管制员安全能力,基于能力的定义和管制员工作职责,界定管制员安全能力的内涵;依据该内涵及其工作特性,建立由身体素质、业务素质和意识3个结构维度组成的管制员安全能力模型。其中,身体素质包括生理状况和心理状况;业务素质包括教育状况、培训状况、技能状况和经验状况;意识包括安全意识和工作意识。在各项指标性质差异较大情况下,利用功效系数法实现评价指标的标准化以减小误差,客观反映指标情况,同时采用G1-法和熵值法集成的主客观综合赋权法确定指标的权重,在一定程度上弥补主客观单一赋权的不足,最后通过逼近理想解排序法(TOPSIS)评价管制员安全能力。结果表明,按照从大到小排序对管制员安全能力的影响因素依次为意识、身体素质和业务素质。就对所论能力的影响而言,心理状况强于生理状况;技能状况强教育、培训和经验状况;安全意识对意识的影响大于工作意识。