Relationship between electric spark sensitivity and activation energy of the thermal decomposition of nitramines for safety measures in industrial processes

This study presents a new simple correlation between electric spark sensitivity of nitramines and their activation energies of thermolysis, which are important for safety measures in industrial processes. The new correlation can help to elucidate the mechanism of initiation of energetic materials by electric spark. It can be used to predict the magnitude of electric spark sensitivity of new nitramines, which is difficult to measure. The methodology assumes that electric spark sensitivity of a nitramine with general formula C_aH_bN_cO_d can be expressed as a function of its activation energy of thermal decomposition as well as optimized elemental composition and the contribution of specific molecular structural parameters. The new correlation has the root mean square and the average deviations of 1.37 and 1.09 J, respectively, for 21 nitramines with different molecular structures. The proposed new method is also tested for 16 nitramines so that there is no experimental data of electrostatic sensitivity for them.     

Incendiary characteristics of electrostatic discharge for dust and gas explosion

Paying attention to the ignition potentiality of static electricity, the relation between the discharge characteristics and the ignition of a dust cloud and the gas produced was studied, applying an electrical power supply of which the electrical circuit is adjustable. The effect of ignition characteristics on dust and gas explosions was investigated. The results of the study indicate that the probability of an explosion is influenced by the minimum ignition energy, spark duration time, feeding rate of ignition energy, circuit capacitance, ignition voltage, etc.     

静电除尘净化球团竖炉烟气技术研究

介绍了球团竖炉的烟尘排放特性,分析研究了影响静电除尘器工作性能的主要因素,总结了静电除尘改造工程中技术改进经验和运行管理所取得的经验。     

粉尘性质对电除尘器性能影响的试验研究

在半工业化的电除尘器实验系统装置上进行了烧结灰、飞灰、煤铁混合样的粒径分布及粉尘的真密度对电除尘器性能影响的实验研究。结果表明,电除尘器能有效捕集亚微米粉尘,对烧结灰净化最适合的粒径范围为1．37～2．03μm(η高达100％);对煤铁混合样的最适合粒径范围为3．30～7．25μm(η高达100％);电除尘器对煤铁混合样的粒径小于2．24μm的分级效率η高达92．36％。在同等试验条件下,电除尘器对烧结灰和煤铁混合样的总除尘效率为96．87％,高于飞灰的总除尘效率92．61％。     

电除尘器前端预荷电技术研究

电除尘器前端主要是指进口喇叭及进气烟道,在进口喇叭内设置预荷电电场,可以保证气流均匀进入电场的同时,对粉尘进行荷电、凝并,起到一级预收尘的作用,以增加收尘面积,提高除尘器的除尘效率。通过分析Indigo烟道凝聚器、进口喇叭内置电场技术、电除尘器中粉尘预荷电试验研究及国内专利技术成果基础上,提出电除尘器进口喇叭内预置电场技术,并取得比较好的应用效果。