全文获取类型
收费全文 | 225篇 |
免费 | 7篇 |
国内免费 | 19篇 |
专业分类
安全科学 | 16篇 |
废物处理 | 2篇 |
环保管理 | 14篇 |
综合类 | 92篇 |
基础理论 | 29篇 |
污染及防治 | 41篇 |
评价与监测 | 42篇 |
社会与环境 | 12篇 |
灾害及防治 | 3篇 |
出版年
2023年 | 6篇 |
2022年 | 5篇 |
2021年 | 1篇 |
2020年 | 5篇 |
2019年 | 4篇 |
2018年 | 4篇 |
2017年 | 3篇 |
2016年 | 6篇 |
2015年 | 8篇 |
2014年 | 9篇 |
2013年 | 21篇 |
2012年 | 13篇 |
2011年 | 22篇 |
2010年 | 8篇 |
2009年 | 17篇 |
2008年 | 20篇 |
2007年 | 16篇 |
2006年 | 10篇 |
2005年 | 2篇 |
2004年 | 9篇 |
2003年 | 8篇 |
2002年 | 5篇 |
2001年 | 4篇 |
2000年 | 6篇 |
1999年 | 3篇 |
1998年 | 7篇 |
1997年 | 6篇 |
1996年 | 4篇 |
1995年 | 6篇 |
1994年 | 2篇 |
1993年 | 1篇 |
1992年 | 5篇 |
1991年 | 2篇 |
1989年 | 1篇 |
1981年 | 1篇 |
1974年 | 1篇 |
排序方式: 共有251条查询结果,搜索用时 46 毫秒
71.
72.
Sediment-water distribution of perfluorooctane sulfonate (PFOS) in Yangtze River Estuary 总被引:2,自引:0,他引:2
Analysis of Perfluorooctane sulfonate (PFOS) distribution in water and sediment in Yangtze River Estuary showed that the estuary was a sink for PFOS. Salinity was an important parameter in controlling the sediment-water interactions and the fate or transport of PFOS in the aquatic environment. As the salinity (S‰) increased from 0.18 to 3.31, the distribution coefficient (Kd) between sediment and water linearly increased from 0.76 to 4.70 L g−1. The study suggests that PFOS may be carried with the river water and transported for long distances before it reaches to the sea and largely scavenged to the sediment in the estuaries due to the dramatic change in salinity. 相似文献
73.
The objective of this study was to provide operational probability density functions (PDFs) for distribution coefficients (Kds) in freshwater, representing the partition of radionuclides between the particulate and the dissolved phases respectively. Accordingly, the Kd variability should be considered in uncertainty analysis of transport and risk assessment models. The construction of PDFs for 8 elements (Ag, Am, Co, Cs, I, Mn, Pu and Sr) was established according to the procedure already tested in Durrieu et al. [2006. A weighted bootstrap method for the determination of probability density functions of freshwater distribution coefficients (Kds) of Co, Cs, Sr and I radioisotopes. Chemosphere 65 (8), 1308–1320]: (i) construction of a comprehensive database where Kds values obtained under various environments and parametric conditions were collected; (ii) scoring procedure to account for the ‘quality’ of each datapoint (according to several criteria such as the presentation of data (e.g. raw data vs mean with or without replicates), contact time, pH, solid-to-liquid ratio, expert judgement) in the construction of the PDF; (iii) weighted bootstrapping procedure to build the PDFs, in order to give more importance to the most relevant datapoints. Two types of PDFs were constructed: (i) non-conditional, usable when no knowledge about the site of concern is available; (ii) conditional PDFs corresponding to a limited range of parameters such as pH or contact time; conditional PDFs can thus be used when some parametric information is known on the site under study. For 7 other radionuclides (Ba, Be, Ce, Ra, Ru, Sb and Th), a simplified procedure was adopted because of the scarcity of data: only non-conditional PDFs were built, without incorporating a scoring procedure. 相似文献
74.
Sbastien Denys Guillaume Echevarria Louis Florentin Elisabeth Leclerc Jean-Louis Morel 《Journal of environmental radioactivity》2009,100(10):884-889
Parameters regarding fate of 63Ni in the soil–plant system (soil: solution distribution coefficient, Kd and soil plant concentration ratio, CR) are mostly determined in controlled pot experiments or from simple models involving a limited set of soil parameters. However, as migration of pollutants in soil is strongly linked to the water migration, variation of soil structure in the field and seasonal variation of evapotranspiration will affect these two parameters. The aim of this work was to explore to what extent the downward transfer of 63Ni and its uptake by plants from surface-contaminated undisturbed soil cores under cultivation can be explained by isotopic dilution of this radionuclide in the pool of stable Ni of soils. Undisturbed soil cores (50 cm × 50 cm) were sampled from a brown rendzina (Rendzic Leptosol), a colluvial brown soil (Fluvic Cambisol) and an acidic brown soil (Dystric Cambisol) using PVC lysimeter tubes (three lysimeters sampled per soil type). Each core was equipped with a leachate collector. Cores were placed in a greenhouse and maize (DEA, Pioneer®) was sown. After 44 days, an irrigation was simulated at the core surfaces to supply 10 000 Bq 63NiCl2. Maize was harvested 135 days after 63Ni input and radioactivity determined in both vegetal and water samples. Effective uptake of 63Ni by maize was calculated for leaves and kernels. Water drainage and leaching of 63Ni were monitored over the course of the experiment. Values of Kd in surface soil samples were calculated from measured parameters of isotopic exchange kinetics. Results confirmed that 63Ni was strongly retained at the soil surface. Prediction of the 63Ni downward transfer could not be reliably assessed using the Kd values, since the soil structure, which controls local water fluxes, also affected both water and Ni transport. In terms of 63Ni plant uptake, the effective uptake in undisturbed soil cores is controlled by isotope dilution as previously shown at the pot experiment scale. 相似文献
75.
Jerome J. Schleier III Collin Preftakes Robert K. D. Peterson 《Journal of environmental science and health. Part. B》2013,48(7):621-625
The most important factor affecting efficacy and drift of pesticide applications is the droplet spectrum. To measure pesticide drift, researchers utilize fluorescent tracers to rapidly quantify spray deposition. Although fluorescent tracers have been used for more than 50 years, no experiments have been performed on the effect they have on the properties of pesticide formulations (density and viscosity) or droplet spectrum, which affect the drift of pesticides. Therefore, we examined the effect of an oil- and water-based tracer on the volume median diameter (VMD), viscosity, and density of oil- and water-based pesticide formulations. In addition, we experimentally fit and demonstrate the utility of using distributions to characterize pesticide droplet spectra. The addition of tracers to both water- and oil-based formulations did not significantly alter the VMD, viscosity, and density. Lognormal distributions provided the best fit for the water- and oil-based formulations with and without tracer. Our results demonstrated that the addition of oil- and water-based tracers do not significantly alter pesticide formulations properties and droplet spectrum, and most likely do not alter the movement of pesticide droplets in the environment. 相似文献
76.
Anne Straczek Dariusz Wegrzynek Ernesto Chinea-Cano Jacques Navez 《Journal of environmental radioactivity》2010,101(3):258-266
Accumulation and distribution of uranium in roots and shoots of four plants species differing in their cation exchange capacity of roots (CECR) was investigated. After exposure in hydroponics for seven days to 100 μmol U L−1, distribution of uranium in roots was investigated through chemical extraction of roots. Higher U concentrations were measured in roots of dicots which showed a higher CECR than monocot species. Chemical extractions indicated that uranium is mostly located in the apoplasm of roots of monocots but that it is predominantly located in the symplasm of roots of dicots. Translocation of U to shoot was not significantly affected by the CECR or distribution of U between symplasm and apoplasm. Distribution of uranium in roots was investigated through chemical extraction of roots for all species. Additionally, longitudinal and radial distribution of U in roots of maize and Indian mustard, respectively showing the lowest and the highest translocation, was studied following X-ray fluorescence (XRF) analysis of specific root sections. Chemical analysis and XRF analysis of roots of maize and Indian mustard clearly indicated a higher longitudinal and radial transport of uranium in roots of Indian mustard than in roots of maize, where uranium mostly accumulated in root tips. These results showed that even if CECR could partly explain U accumulation in roots, other mechanisms like radial and longitudinal transport are implied in the translocation of U to the shoot. 相似文献
77.
Natural resources are limited, so we need to handle them carefully. Wastewater also belongs as a significant natural resource. The re-usage of wastewater is to save fresh water and for the preparation of raw materials or/and utilities. The wastewater re-usage distribution can be optimised using mixed-integer nonlinear programming (MINLP), as a tool in combinations using the coordinates technique. The main goal of this MINLP coordinates technique was: i) wastewater and condensate, as produced during different industrial processes, could be collected for: utilities for steam-generation, and the preparations of raw materials; ii) wastewater and condensate could be collected within the main reservoir; iii) distributions from the main reservoir could be used with including different alternatives, which can reduce pollution, based on the re-usage of wastewater. Alternatives included in the optimization model represent potential solutions, which need to be evaluated on appropriate way.The MINLP coordinates technique for wastewater re-usage distribution was tested on existing formalin and methanol industrial processes, thus allowing the saving of water and generated by 280 kEUR/a profit. 相似文献
78.
79.
The Evolution of the Environmental Quality Concept: From the US EPA Red Book to the European Water Framework Directive 总被引:1,自引:0,他引:1
Vighi M Finizio A Villa S 《Environmental science and pollution research international》2006,13(1):9-14
- DOI: http://dx.doi.org/10.1065/espr2006.01.003
Background Water Quality Criteria were firstly defined in the 1970s by the EPA in the USA and the EIFAC in Europe, recognizing the need
for protecting water quality in order to allow the use of water resources by man. In the 1990s, the European Commission emphasized
the importance of safeguarding structure and function of biologic communities. These approaches were chemically-based. The
European Water Framework Directive (WFD) substantially changes the concept of Water Quality, by assuming that a water body
needs to be protected as an environmental good and not as a resource to be exploited. In this frame, the biological-ecological
quality assumes a prevailing role.
Main Features The Water Quality concept introduced by the WFD is a challenge for environmental sciences. Reference conditions should be
defined for different typologies of water bodies and for different European ecoregions. Suitable indicators should be developed
in order to quantify ecological status and to define what a 'good' ecological status is. Procedures should be developed for
correlating the deviation from a good ecological to the effects of multiple stressors on function and structure of the ecosystem.
The protection of biodiversity becomes a key objective. In this frame, the traditional procedures for ecotoxicological risk
assessment, mainly based on laboratory testing, should be overcome by more site-specific approaches, taking into account the
characteristics and the homeostatic capabilities of natural communities. In the paper an overview of the present knowledge
and of the new trends in ecotoxicology to get these objectives will be given. A procedure is suggested based on the concept
of Species Sensitivity Distribution (SSD).
Recommendations and Perspective . The need for more site-specific and ecologically-oriented approaches in ecotoxicology is strongly recommended. The development
of new tools for implementing the concept of 'Stress Ecology' has been recently proposed by van Straalen (2003). In the same
time, more 'cological realism'is needed in practically applicable procedures for regulatory purposes. 相似文献
80.