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81.
Tran B. Nguyen Adam P. Bateman David L. Bones Sergey A. Nizkorodov Julia Laskin Alexander Laskin 《Atmospheric environment (Oxford, England : 1994)》2010,44(8):1032-1042
The chemical composition of secondary organic aerosol (SOA) generated from the ozonolysis of isoprene (C5H8) in the presence of an OH scavenger was examined using high-resolution electrospray ionization mass spectrometry (ESI-MS) in the mass range m/z = 50–1000. The chemical composition of SOA is complex, with more than 1000 assigned peaks observed in the positive and negative ion mode spectra. Only a small fraction of peaks correspond to known products of isoprene oxidation, such as pyruvic acid, glycolic acid, methylglyoxal, etc. The absolute majority of the detected peaks correspond to highly oxidized oligomeric constituents of SOA, with an average O:C molar ratio of 0.6. The corresponding organic mass (OM) to organic oxygen (OO) ratio is 2.4. Approximately 8% of oxygen atoms in SOA are in the form of peroxides, as quantified with an iodide test. Double bond equivalency (DBE) factors, representing the sum of all double bonds and rings, increase by 1 for every 1–2 additional carbon atoms in the molecule. The number of unoxidized CC double bonds is estimated to be less than 10%; the remaining DBE is due to CO carbonyl groups. Kendrick analysis suggests that the prevalent oligomer building blocks are small carbonyls with a C1–C2 skeleton. Formaldehyde (CH2O) is identified as the most common repetitive building block in the observed oligomeric compounds. 相似文献
82.
Paul Scott Paul Brown Julia Verne Jody James Alistair Gordon Joyshri Sarangi Jonathan A. C. Sterne 《Environmental geochemistry and health》2009,31(2):297-308
This ecological study aimed, through the analysis of 1,146 wards in the South West of England (1998–2002), firstly, to examine
whether chemical incidents and public casualties are more likely near complex industry (emissions to land, air or water: Integrated
Pollution Control industry, IPC) or industry with emissions to air only (Local Air Pollution Control industry, LAPC). Secondly,
the study examined whether industry, incidents and casualties are found close to deprivation. Social inequalities were examined
across quintiles of wards. Fifty-two wards (4.5%) contained an IPC industry and 712 (62.1%) an LAPC. Incidents occurred in
132 wards (11.5%), with casualties in 59 (5.1%). Chemical incidents occurred more frequently in wards with LAPC (152, IPC
20); the same was true of casualties (211, 12). With each additional LAPC site in a ward, the risk of an incident rose by
22% (95% confidence interval [CI] 8–38%), suggesting a dose–response relationship. No clear social inequalities were found.
In the South West of England, the public are more likely to be affected by an incident occurring at a simple LAPC site rather
than a complex IPC site. This has implications for emergency planning which, at present, focusses most attention on the larger,
more complex IPC sites. 相似文献
83.
Energy efficiency and conservation for individual Americans 总被引:1,自引:0,他引:1
D. Pimentel Jennifer Gardner Adam Bonnifield Ximena Garcia Julie Grufferman Claire Horan Julia Schlenker Emily Walling Emily Rochon 《Environment, Development and Sustainability》2009,11(3):523-546
Americans make up only 4% of the world population, yet currently consume 25% of the world’s fossil fuels. The U.S. imports
63% of its oil and it is predicted that by 2020 the U.S. will be importing 95% of its oil resources. Over the past century,
ample and affordable supplies of fossil fuels have powered the growth and prosperity of the economies of the US and other
countries. Within this century, world oil supplies will decline while demand is projected to continue to increase, suggesting
that we will have to transition to different fuels or become much more energy efficient or both. Looking ahead to the near
decades, estimates are that consumers will have to reduce their energy use by at least 50%. This reduction will be necessary
in large part due the decline in the availability of conventional oil and gas, but also because the U.S. population will continue
to grow in number. Although government action is important, individuals too often discount their ability to make significant
contributions to solving such major problems. This investigation identifies how informed and concerned individuals can collectively
conserve fossil energy.
Readers should send their comments on this paper to: BhaskarNath@aol.com within 3 months of publication of this issue.
An erratum to this article can be found at 相似文献
84.
Verkerk Pieter J. Lindner Marcus Pérez-Soba Marta Paterson James S. Helming John Verburg Peter H. Kuemmerle Tobias Lotze-Campen Hermann Moiseyev Alexander Müller Daniel Popp Alexander Schulp Catharina J. E. Stürck Julia Tabeau Andrzej Wolfslehner Bernhard van der Zanden Emma H. 《Regional Environmental Change》2018,18(3):817-830
Regional Environmental Change - Plausible scenarios of future land use derived from model projections may differ substantially from what is actually desired by society, and identifying such... 相似文献
85.
Erin K. Cameron Inês S. Martins Patrick Lavelle Jérôme Mathieu Leho Tedersoo Mohammad Bahram Felix Gottschall Carlos A. Guerra Jes Hines Guillaume Patoine Julia Siebert Marten Winter Simone Cesarz Olga Ferlian Holger Kreft Thomas E. Lovejoy Luca Montanarella Alberto Orgiazzi Henrique M. Pereira Helen R. P. Phillips Josef Settele Diana H. Wall Nico Eisenhauer 《Conservation biology》2019,33(5):1187-1192
Human activities are accelerating global biodiversity change and have resulted in severely threatened ecosystem services. A large proportion of terrestrial biodiversity is harbored by soil, but soil biodiversity has been omitted from many global biodiversity assessments and conservation actions, and understanding of global patterns of soil biodiversity remains limited. In particular, the extent to which hotspots and coldspots of aboveground and soil biodiversity overlap is not clear. We examined global patterns of these overlaps by mapping indices of aboveground (mammals, birds, amphibians, vascular plants) and soil (bacteria, fungi, macrofauna) biodiversity that we created using previously published data on species richness. Areas of mismatch between aboveground and soil biodiversity covered 27% of Earth's terrestrial surface. The temperate broadleaf and mixed forests biome had the highest proportion of grid cells with high aboveground biodiversity but low soil biodiversity, whereas the boreal and tundra biomes had intermediate soil biodiversity but low aboveground biodiversity. While more data on soil biodiversity are needed, both to cover geographic gaps and to include additional taxa, our results suggest that protecting aboveground biodiversity may not sufficiently reduce threats to soil biodiversity. Given the functional importance of soil biodiversity and the role of soils in human well-being, soil biodiversity should be considered further in policy agendas and conservation actions by adapting management practices to sustain soil biodiversity and considering soil biodiversity when designing protected areas. 相似文献
86.
Stephen G. Perz Jeffrey Hoelle Karla Rocha Veronica Passos Flavia Leite Julia Cortes 《Journal of Land Use Science》2017,12(4):231-251
In the complex causation behind land change, dependent causation can play a central role. A case in point concerns land tenure diversity, where contrasting use rules for different lands may affect the impacts of other drivers on land use outcomes. We therefore evaluate the evolutionary theory of land rights (ETLR), which assumes homogeneous private property rights, in order to test for dependent causation due to distinct use rules among various types of private lands. In the present analysis, we focus on whether land tenure type modifies the effects of highway infrastructure on key outcomes highlighted in the ETLR framework. We take up the case of rural settlements along the Inter-Oceanic Highway in the eastern part of the Brazilian state of Acre, where there is considerable land tenure diversity. Findings from multivariate models for land titling, the castanha nut harvest, and cattle pasture all indicate that the effects of infrastructure depend on land tenure type. These results confirm the importance of dependent causation behind land use and bear implications for theory on land change, infrastructure impacts, and land system science. 相似文献
87.
Pyrolysis and combustion runs at 850°C in a horizontal laboratory furnace were carried out on different parts of a mobile phone (printed circuit board, mobile case and a mixture of both materials). The analyses of the carbon oxides, light hydrocarbons, polycyclic aromatic hydrocarbons (PAHs), polychlorodibenzo-p-dioxin, polychlorodibenzofurans (PCDD/Fs), and dioxin-like PCBs are shown. Regarding semivolatile compounds, phenol, styrene, and its derivatives had the highest yields. In nearly all the runs the same PAHs were identified, naphthalene being the most common component obtained. Combustion of the printed circuit board produced the highest emission factor of PCDD/Fs, possibly due to the high copper content. 相似文献
88.
Ana Julia Fernandes Cardoso de Oliveira Paula Thais Ranzani de França Aline Bartelochi Pinto 《Environmental monitoring and assessment》2010,169(1-4):375-384
Antimicrobial resistance of marine heterotrophic bacteria to different antimicrobials agents were evaluated in seawater, dry and wet sands from three marine recreational beaches with different pollution levels. In all studied beaches, the greatest frequencies of resistance were found in relation to penicillin. On Gonzaguinha, the most polluted beach, 72.3% of all isolated strains showed simple resistance, whilst 8.33% had multiple resistance. The values found on Ilha Porchat beach, were 70.8% and 6.9% for simple and multiple resistances, respectively. On Guaraú, the less polluted beach, only 35.3% of isolated strains had simple resistance. Multiple resistance was not observed. While samples from Gonzaguinha and Ilha Porchat beach showed isolated strains resistant to seven and six different antimicrobial agents, respectively, samples from Guaraú beach were resistant only to penicillin and erytromicin. The positive correlations obtained between the degree of seawater contamination and frequency and variability of bacterial resistance indicate that polluted marine recreational waters and sands are sources of resistant bacteria contributing thus, to the dissemination of bacterial resistance. 相似文献
89.
Joan G. Staniswalis Norris J. Parks Julia O. Bader Yolanda Muñoz Maldonado 《Journal of the Air & Waste Management Association (1995)》2013,63(7):893-902
Abstract One of two topics explored is the limitations of the daily average in summarizing pollutant hourly profiles. The daily average of hourly measurements of air pollutant constituents provides continuity with previous studies using monitoring technology that only provided the daily average. However, other summary statistics are needed that make better use of all available information in 24-hr profiles. The daily average reflects the total daily dose, obscuring hourly resolution of the dose rate. Air pollutant exposures with comparable total daily doses may have very different effects when occurring at high levels over a few hours as opposed to low levels over a longer time. Alternative data-based choices for summary statistics are provided using principal component analysis to capture the exposure dose rate, while preserving ease of interpretation. This is demonstrated using the earliest hourly particle concentration data available for El Paso from archived records of particulate matter (PM)10. In this way, a significant association between evening PM10 exposures and nonaccidental daily mortality is found in El Paso from 1992 to 1995, otherwise missed using the daily average. Secondly, the nature and, hence, effects of particles in the ambient aerosol during El Paso sandstorms is believed different from that of particles present during stillair conditions resulting from atmospheric temperature inversions. To investigate this, wind speed (ws) is used as a surrogate variable to label PM10 exposures as Low-ws (primarily fine particles), High-ws (primarily coarse particles), or Mid-ws (a mixture of fine and coarse particles). A High-ws evening is significantly associated with a 10% lower risk of mortality on the succeeding third day, as compared with comparable exposures at Low- or Mid-ws. Although this analysis cannot be used to form firm conclusions because it uses a very small data set, it demonstrates the limitations of the daily average and suggests differential toxicity for different particle compositions. 相似文献
90.
Bong Mann Kim Julia Lester Laki Tisopulos Melvin D. Zeldin 《Journal of the Air & Waste Management Association (1995)》2013,63(9):142-153
ABSTRACT In February 1993, the South Coast Air Basin (SCAB) was redesignated as a “serious” nonattainment area for PM10. To improve the understanding and characterization of fine particulate matter in the SCAB, the South Coast Air Quality Management District (SCAQMD) initiated a comprehensive PM10 Technical Enhancement Program (PTEP). Using enhanced PTEP monitors (specially designed multichannel/multifilter samplers), a one-year fine particulate matter (PM) monitoring program was initiated in January 1995. As part of the special monitoring program, nitric acid, ammonia, and speciated PM10 and PM2.5 concentrations were measured at five locations in the SCAB (downtown Los Angeles, Anaheim, Diamond Bar, Fontana, and Rubidoux) and at one background station (San Nicolas Island). The PM2.5 data are the first spatially resolved speciated data collected in the SCAB on an annual basis. Within the SCAB, where nitrate is a major component of PM2.5, nitrate losses have been documented. The spatial and temporal variations of the nitrate losses during PM2.5 sampling and the uncertainties of the nitrate losses are discussed. Significant losses occur at a low mass range, between 10 and 50 ìg/m3. Significant gains occur at an even lower mass range of less than 30 ìg/m3. On an annual average basis, nitrate losses vary between 1.25 and 2.32 ìg/m3 and the SCAB-wide average value of nitrate loss is 1.8 ìg/m3 based on five PTEP stations in the SCAB. The maximum nitrate losses for each station vary from 6.4 ìg/m3 to 22.5 ìg/m 3. Theoretical prediction of the sampling efficiency of the nitrate during PM2.5 sam - pling was compared with the PTEP data. In general, theoretical prediction was in good agreement with measured values. 相似文献