衡阳市区和衡山背景站臭氧浓度变化规律的对比分析

选取衡阳市区和衡山背景站臭氧自动监测数据,分析两地的臭氧污染特征。对空气质量的优良率情况、臭氧作为首要污染物的变化情况、臭氧浓度的日变化特征、典型时段的浓度变化特征、臭氧浓度的月际变化特征和臭氧与PM_(2.5)的关联情况等进行了分析。结果表明,多云及阴雨天气时,衡阳市区的臭氧浓度日变化幅度大于衡山背景站。夏季,衡阳市区和衡山背景站的臭氧浓度的日变化特征规律差异较大,臭氧浓度分布比较分散,前者为典型的单峰形,后者则波动平缓。冬季,日变化幅度不大,但衡阳市区的臭氧浓度明显低于衡山背景站。衡山背景站和衡阳市区的臭氧基本同步变化,但日均值高于衡阳市区。     

基于SHERPA的环境空气质量减排情景模拟评估

分析了SHERPA综合评价模型的基本原理和主要建模理念,重点介绍了其在环境空气质量减排情景模拟评估方面的作用,以及在排放源与受体关系(SRR)方面的处理方法,比较了其与欧盟常用的其他情景模拟模型的优缺点。SHERPA模型的特点是空间灵活性较好,对于任何给定地点,可以快速评估不同地区对该研究地点空气质量的影响。SHERPA模型的3个主要功能为污染物来源分析、决策支持和情景模拟。基于SHERPA模型对法国环境空气中PM_(2.5)、PM_(10)和NO_2年均浓度进行污染来源分析、决策支持分析和减排情景模拟评估,展示了模型在环境治理措施优先级筛选和政府间联合治理措施协调建议方面的功能和作用,以期为中国环境空气质量预测预报、环境质量管理措施的制定和成效评估等环境服务与管理工作提供借鉴。     

冷空气在北上台风“利奇马”致灾暴雨中的作用分析

利用NCEP逐6 h再分析资料、地面加密观测、探空、雷达资料,分析得出“利奇马”致灾暴雨是在长时间稳定维持的天气尺度环流背景下形成的。冷空气在降水所起的作用表现在:(1)长时间维持的弱冷空气与偏南暖湿气流交汇形成了边界层辐合线,辐射升温和暖湿气流的输送加大了辐合线两侧的温度和露点梯度,在高温高湿的有利环境下,对流在辐合线附近强烈发展。(2)高空槽后冷空气由“利奇马”环流西北侧渗入,先后形成3个冷平流中心,分别对应3个阶段的降水。(3)冷暖空气在降水区的持续辐合抬升作用增强了降水,最强降水时段发生在锋区垂直方向坡度最大的时段。(4)水平锋生有利于水汽输送和辐合抬升,垂直锋生有利于对流不稳定能量的累积和触发。冷空气形成的水平辐合和抬升造成大范围上升运动,使得锋生和垂直锋消同时存在,最强降水时段发生在水平锋生最强的时段。     

Physico-chemical characterization of Residual Household Waste for energy recovery in insular territories: Case study of Reunion Island

Waste-to-energy is a promising approach to face the current challenge of waste overproduction in Reunion Island, a French territory. In this particular context of an isolated and tropical territory, it is essential to study the properties of potential feedstocks to choose the most appropriate conversion process. This article reports on the composition of Residual Household Waste from Reunion Island and its physico-chemical parameters. Twelve representative samples of Residual Household Waste were subjected to thermal and elemental analysis. The results showed that their composition had a significant influence on the physico-chemical properties, including calorific value. Residual Household Waste from the selective sorting (rich in wood, plastic, and sanitary textiles) as well as dry mixed RHW are the most interesting for energy recovery. Due to their high volatile matter and high carbon content, and their low moisture content, these types of waste have a high calorific value exceeding 18 MJ/kg. Furthermore, the RHW sample comply with the environmental and health criteria applied by French regulations concerning halogen and heavy metal. Thus, it seems that Residual Household Waste can be an alternative to conventional fuels used in incineration or pyro-gasification processes. However, the study also points the need for a pre-treatment process for these wastes. Indeed, it is necessary to sort them correctly in order to avoid the risks of pollution and important maintenance. And more importantly, drying beforehand is unavoidable to improve combustibility and obtain optimal energy conversion.     

A new prediction method of industrial atmospheric pollutant emission intensity based on pollutant emission standard quantification

● Established a quantification method of pollutant emission standard. ● Predicted the SO₂ emission intensity of single coking enterprises in China. ● Evaluated the influence of pollutant discharge standard on prediction accuracy. ● Analyzed the SO₂ emissions of Chinese provincial and municipal coking enterprises. Industrial emissions are the main source of atmospheric pollutants in China. Accurate and reasonable prediction of the emission of atmospheric pollutants from single enterprise can determine the exact source of atmospheric pollutants and control atmospheric pollution precisely. Based on China’s coking enterprises in 2020, we proposed a quantitative method for pollutant emission standards and introduced the quantification results of pollutant emission standards (QRPES) into the construction of support vector regression (SVR) and random forest regression (RFR) prediction methods for SO₂ emission of coking enterprises in China. The results show that, affected by the types of coke ovens and regions, China’s current coking enterprises have implemented a total of 21 emission standards, with marked differences. After adding QRPES, it was found that the root mean squared error (RMSE) of SVR and RFR decreased from 0.055 kt/a and 0.059 kt/a to 0.045 kt/a and 0.039 kt/a, and theR² increased from 0.890 and 0.881 to 0.926 and 0.945, respectively. This shows that the QRPES can greatly improve the prediction accuracy, and the SO₂ emissions of each enterprise are highly correlated with the strictness of standards. The predicted result shows that 45% of SO₂ emissions from Chinese coking enterprises are concentrated in Shanxi, Shaanxi and Hebei provinces in central China. The method created in this paper fills in the blank of forecasting method of air pollutant emission intensity of single enterprise and is of great help to the accurate control of air pollutants.     

Zinc recovery from hazardous construction wastes via an integrated process of the air classification,alkaline leaching,and water washing

Zinc- and lead-containing wastes are often mixed with construction and demolition wastes in many factories, generating abundant of heavy metal-enriched hazardous waste. In the present study, a novel integrated process of air classification, alkaline leaching, and water washing dechlorination was proposed for the efficient recycling of Zinc (Zn) resources. The first air classification process was realized via venturi tube, wherein the content of Zn could increase by 20 wt.%. After that, the product underwent an alkaline leaching process. Results showed that Zn recovery rate increased with fine particle sizes, and a 65% recovery rate was obtained under the following conditions of 5 mol/L NaOH, liquid/solid 10:1, and leaching time 1 h. Finally, water washing associated with microwave and ultrasonic treatments could remove over 85% of Cl and other water-soluble salts. All the results indicated that the integrated method had an excellent recovery rate for Zn resources from construction and demolition wastes.     

一种新型铋基光催化剂的合成及其可见光催化性能

采用水热法合成铋基光催化剂Bi4VO8Br,通过X-射线粉末衍射、扫描电镜等手段对其进行表征.选择甲基橙为目标降解物来评价不同条件下合成的Bi4VO8Br在可见光下的光催化活性,发现pH 3、反应时间15 h、反应温度160℃为材料水热合成的最佳条件.考察了Bi4VO8Br在可见光及紫外光下对几种农药和增塑剂的光催化降解性能,显示了Bi4VO8Br对不易光解的含苯环有机物的可见光高活性.五氯酚的光催化过程影响因素优化结果表明,可见光和紫外光分别照射120 min和20 min,其降解率分别达到97％和99％,Bi4VO8Br表面上活性基团的捕获即空穴的氧化作用是主要反应原理.     

美国加州南岸地区空气质量监测系统运行管理与借鉴

借鉴加州南岸空气质量监测管理经验（特别是运行管理模式）对于现阶段我国城市环境空气质量监测管理具有极高的参考价值。简要介绍了加州南岸空气质量管理局（ SCAQMD）的空气质量监测现状、监测网络布局、颗粒物采样方法和相关质量管理体系。对现行的环境空气质量指数、管理架构和PM2?5考核方法进行了综合比较，建议从4个方面借鉴SCAQMD经验：试行“空气质量管理区”模式；开展专项研究网络建设；逐步开展手工监测采样和颗粒物化学组分分析；提升数据挖掘水平，服务管理决策。     

环境空气质量新标准对郑州和开封空气质量评价的影响

利用河南省环境空气质量新标准实施一期城市(郑州、开封)2013年的环境空气自动监测数据,分析了实施《环境空气质量标准》(GB 3095—2012)对这2个城市空气质量评价的影响。研究发现,若采用新标准,郑州、开封污染物年均浓度超标情况加重;城市空气质量达标率从51%、71%下降到35%和31%,下降了16和40个百分点;PM2.5的纳入是空气质量达标率下降的最主要原因,大于NO2标准的收严和CO、O3纳入评价指标的影响,其超标率分别为58%(郑州)和63%(开封);且PM2.5取代PM10成为郑州、开封的首要污染物,其作为首要污染物的比例均大于70%。     

城市大气中挥发性有机化合物监测技术进展

挥发性有机物(VOCs)是臭氧及二次有机颗粒物(SOA)的主要前体物。近年来,我国逐步将VOCs纳入大气污染物控制体系。准确可靠的监测技术是大气VOCs研究及控制的重要前提保障。按照采样方法、分析方法 2个方面介绍并讨论了城市大气中VOCs的现有监测方法,较为详细地介绍了几类广泛采用的离线及在线监测技术,简要讨论了目前VOCs监测中存在的一些问题,展望了今后的发展趋势。