全文获取类型
收费全文 | 3709篇 |
免费 | 438篇 |
国内免费 | 1816篇 |
专业分类
安全科学 | 214篇 |
废物处理 | 410篇 |
环保管理 | 267篇 |
综合类 | 3121篇 |
基础理论 | 808篇 |
污染及防治 | 796篇 |
评价与监测 | 255篇 |
社会与环境 | 67篇 |
灾害及防治 | 25篇 |
出版年
2024年 | 7篇 |
2023年 | 66篇 |
2022年 | 113篇 |
2021年 | 142篇 |
2020年 | 146篇 |
2019年 | 154篇 |
2018年 | 171篇 |
2017年 | 169篇 |
2016年 | 204篇 |
2015年 | 230篇 |
2014年 | 243篇 |
2013年 | 392篇 |
2012年 | 337篇 |
2011年 | 353篇 |
2010年 | 281篇 |
2009年 | 282篇 |
2008年 | 264篇 |
2007年 | 315篇 |
2006年 | 296篇 |
2005年 | 230篇 |
2004年 | 190篇 |
2003年 | 178篇 |
2002年 | 169篇 |
2001年 | 158篇 |
2000年 | 117篇 |
1999年 | 121篇 |
1998年 | 111篇 |
1997年 | 100篇 |
1996年 | 86篇 |
1995年 | 66篇 |
1994年 | 44篇 |
1993年 | 34篇 |
1992年 | 43篇 |
1991年 | 53篇 |
1990年 | 20篇 |
1989年 | 15篇 |
1988年 | 11篇 |
1987年 | 16篇 |
1986年 | 3篇 |
1985年 | 4篇 |
1984年 | 4篇 |
1983年 | 7篇 |
1982年 | 3篇 |
1981年 | 2篇 |
1980年 | 2篇 |
1978年 | 3篇 |
1977年 | 2篇 |
1976年 | 1篇 |
1975年 | 1篇 |
1973年 | 3篇 |
排序方式: 共有5963条查询结果,搜索用时 31 毫秒
1.
采用振荡淋洗和土柱动态淋洗实验研究了皂素和柠檬酸复合对土壤中钍的淋洗性能。实验结果表明:将质量浓度为20 g/L的皂素与浓度为20 mmol/L的柠檬酸以体积比1∶10配制复合淋洗液对污染土壤中钍的去除效果最佳,淋洗3.0 h,钍去除率为84.98%;准一级动力学方程能更好地描述复合淋洗液对钍的淋洗动力学特征;动态淋洗实验中当复合淋洗液用量为1 600 mL时,钍的累积去除量为73.66 mg/kg;淋洗后土壤中钍的酸可提取态、氧化结合态和有机结合态含量分别减少了79.63%、38.13%和20.34%,残渣态含量变化不大;淋洗后土壤中钍的稳定性增加。 相似文献
2.
Carbon coated monolith was prepared by sucrose solution 65 wt.% via dip-coating method. Sulfonation of incomplete carbonized carbon coated monolith was carried out in order to synthesize solid acid catalyst. The textural structure characteristics of the solid acid catalyst demonstrated a low surface area and pore volume. Palm fatty acid distillate (PFAD), a by-product of palm oil refineries, was utilized as oil source in biodiesel production. The esterification reaction subjected to different reaction conditions was performed by using the sulfonated carbon coated monolith as heterogeneous catalyst. The sulfonation process had been performed by using vapour of concentrated H2SO4 that was much easier and efficient than liquid phase sulfonation. Total acidity value of carbon coated monolith was measured for unsulfonated sample (0.5 mmol/g) and sulfonated sample (4.2 mmol/g). The effect of methanol/oil ratio, catalyst amount and reaction time were examined. The maximum methyl ester content was 89% at the optimum condition, i.e. methanol/oil molar ratio (15:1), catalyst amount (2.5 wt.% with respect to PFAD), reaction time (240 min) and temperature 80 °C. The sugar catalyst supported on the honeycomb monolith showed comparable reactivity compared with the sugar catalyst powder. However, the catalyst reusability studies showed decrease in FFA% conversion from 95.3% to 68.8% after four cycles as well as the total acidity of catalyst dropped from the value 4.2 to 3.1 mmol/g during these cycles. This might be likely due to the leaching out of SO3H group from the sulfonated carbon coated monolith surface. The leaching of active species reached a plateau state after fourth cycle. 相似文献
3.
A new approach to Assess Atmospheric Nitrogen Deposition by Way of Standardized Exposition of mosses
A standardized method of moss exposition for assessing variations in nitrogen deposition was tested in the western part of
Germany. Six pleurocarpous moss species were transplanted to two sites differing in their deposition rates but being comparable
as to their climatic conditions. The mosses were exposed in standardized containers over a period of 12 months; the focus
of interest was the effect of N deposition on nitrogen content and on 15N natural abundance (δ15N-values). Within the first nine months only trends could be observed. However, after one year all species tested showed significantly
higher N concentrations at the highly polluted site. Besides, more negative δ15N-values possibly reflecting the higher ammonium input were detected at this site. Surprisingly, most of the plants though
being kept in plastic containers without a favourable substratum did not show any conspicuous deficiency symptoms. The potential
advantages of a standardized moss exposition for N monitoring purposes are discussed. It is concluded that the method presented
here can yield significant results in particular if the number of testing sites is increased. 相似文献
4.
Alonso R Elvira S Sanz MJ Gerosa G Emberson LD Bermejo V Gimeno BS 《Environmental pollution (Barking, Essex : 1987)》2008,155(3):473-480
A sensitivity analysis of a proposed parameterization of the stomatal conductance (g(s)) module of the European ozone deposition model (DO(3)SE) for Quercus ilex was performed. The performance of the model was tested against measured g(s) in the field at three sites in Spain. The best fit of the model was found for those sites, or during those periods, facing no or mild stress conditions, but a worse performance was found under severe drought or temperature stress, mostly occurring at continental sites. The best performance was obtained when both f(phen) and f(SWP) were included. A local parameterization accounting for the lower temperatures recorded in winter and the higher water shortage at the continental sites resulted in a better performance of the model. The overall results indicate that two different parameterizations of the model are needed, one for marine-influenced sites and another one for continental sites. 相似文献
5.
Pre-concentration and separation of heavy metal ions by chemically modified waste paper gel 总被引:1,自引:0,他引:1
Iminodiacetic acid was immobilized on waste paper by chemical modification in order to develop a new type of adsorption gel for heavy metal ions. Adsorption behavior of the gel was investigated for a number of metal ions, specifically Cu(II), Pb(II), Fe(III), Ni(II), Cd(II), and Co(II) at acidic pH. From batch adsorption tests, the order of selectivity was found to be as follows: Cu(II) Fe(III) > Pb(II) > Ni(II) Co(II) > Cd(II). Column tests were carried out for pairs of metal ions to understand the separation and pre-concentration behavior of the gel. It was found that mutual separation of Ni(II) from Co(II) and that of Pb(II) from Cd(II) can be achieved at pH 3. Similarly, selective separation of Cu(II) from Cu(II)–Fe(III) and Cu(II)–Pb(II) mixtures at pH 1.5 and 2, respectively, was observed by using this new adsorption gel. In all cases, almost complete recovery of the adsorbed metal was confirmed by elution tests with HCl. 相似文献
6.
稳态条件下,采用厌氧折流板反应器(anaerobic baffled reactor,ABR)处理山梨酸废水并进行基质降解动力学研究.实验表明,在污泥负荷为0.54~1.63 kg COD/(kg VSS·d)的范围内,COD去除率随着负荷的增加从85%降到55%.各隔室出水COD沿程递减,前3个隔室承担了去除COD的重要作用,但随着污泥负荷的增加,后部承担的COD去除率比例增大.基于各串联隔室完全混合的假定,推导ABR中山梨酸废水的基质降解动力学方程,并通过实验确定相关动力学参数及相应的动力学方程.实测值与预测值基本吻合. 相似文献
7.
The effect of nitrogen on biomass production, shoot elongation and relative density of the mosses Pleurozium schreberi, Hylocomium splendens and Dicranum polysetum was studied in a chamber experiment. Monocultures were exposed to 10 N levels ranging from 0.02 to 7.35 g N m−2 during a 90-day period. All the growth responses were unimodal, but the species showed differences in the shape parameters of the curves. Hylocomium and Pleurozium achieved optimum biomass production at a lower N level than Dicranum. Pleurozium had the highest biomass production per tissue N concentration. Tolerance to N was the widest in Dicranum, whereas Hylocomium had the narrowest tolerance. Dicranum retained N less efficiently from precipitation than the other two species, which explained its deviating response. All species translocated some N from parent to new shoots. The results emphasize that the individual responses of bryophytes to N should be known when species are used as bioindicators. 相似文献
8.
Boxman AW Peters RC Roelofs JG 《Environmental pollution (Barking, Essex : 1987)》2008,156(3):1252-1259
In a Scots pine forest the throughfall deposition and the chemical composition of the soil solution was monitored since 1984. (Inter)national legislation measures led to a reduction of the deposition of nitrogen and sulphur. The deposition of sulphur has decreased by approximately 65%. The total mineral-nitrogen deposition has decreased by ca. 25%, which is mainly due to a reduction in ammonium-N deposition (−40%), since nitrate-N deposition has increased (+50%). The nitrogen concentration in the upper mineral soil solution at 10 cm depth has decreased, leading to an improved nutritional balance, which may result in improved tree vitality. In the drainage water at 90 cm depth the fluxes of NO3− and SO42− have decreased, resulting in a reduced leeching of accompanying base cations, thus preserving nutrients in the ecosystem. It may take still several years, however, before this will meet the prerequisite of a sustainable ecosystem. 相似文献
9.
The typical parameters of acid precipitation are evaluated in the forest of Vallombrosa (Tuscan Appennines) during the dry period 1988-89. Individual rain events (dry and wet deposition) were sampled in a clearing of the forest and below the canopy of an evergreen tree as well as a deciduous broadleaf tree.
In atmospheric precipitation the pH values usually vary around 4.4, with neutralization in the hot season due to calcareous material from distant sources. Relatively large concentrations of Pb and Cd are found in rain, but only in a small amount in canopy leachate. Aluminium, manganese and iron are more significantly washed off than Pb and Cd. 相似文献
In atmospheric precipitation the pH values usually vary around 4.4, with neutralization in the hot season due to calcareous material from distant sources. Relatively large concentrations of Pb and Cd are found in rain, but only in a small amount in canopy leachate. Aluminium, manganese and iron are more significantly washed off than Pb and Cd. 相似文献
10.
利用长江口枯季潮区界大通站近 4 0年来的水文化学观测资料 ,求得长江径流来源的硝酸盐通量 ,并以此作为长江河口硝酸盐的输入通量。结合历年长江流域的社会经济统计资料和降水量资料等分析 ,发现长江河口硝酸盐的输入通量与流域的人口密度、农业氮肥施用量、灌溉面积以及降水量等显著正相关。随着人口的增长 ,流域内的人类活动不断加剧 ,直接或间接地对长江河口硝酸盐的输入通量产生影响。而降水及灌溉等活动促进了土壤中氮素向河流流失的过程 ,并经长江径流向河口、海洋输送。 90年代后期 ,由人类因素造成的硝酸盐通量的增加占长江河口硝酸盐输入通量的95 %以上。降水引起的水土流失和大气氮氧化物的沉降是硝酸盐通量增加的直接原因 ,而农业活动、燃料燃烧和污水排放等人类活动是该通量变化的主要控制因素 相似文献