气相色谱-串联质谱法测定沉积物中多环芳烃

采用ASE法提取沉积物中16种多环芳烃,以固相萃取法净化提取液,用气相色谱-串联质谱法测定。通过优化测定条件,使方法在5.00μg/L~1 600μg/L范围内线性良好,方法检出限为0.15μg/kg~0.66μg/kg。空白石英砂的加标回收率为61.9%~121%,7次测定结果的RSD为2.6%~11.1%。     

基于响应曲面法的遗煤自燃分析与研究*

为研究高瓦斯易自燃煤层不同供风量、高抽巷抽采流量、低抽巷抽采流量3因素对采空区自燃“三带”分布影响规律，选取阳煤五矿8406工作面为研究对象，在数值模拟研究基础上，采用Design Expert软件进行Box Behnken试验设计，构建采空区氧化升温带宽度在3因素、3水平条件下的二次回归响应曲面模型，并对不同条件下采空区氧化升温带宽度进行预测与分析。结果表明:二次回归方程P值为0.001 6，预测模型显著，模型的失拟项为0.606 3，不显著，回归方程具有统计学意义；当供风量为1 500~2 000 m3/min，低抽流量为450~650 m3/min，高抽流量为100~200 m3/min时，对氧化升温带宽度一次项重要度排序为C（高抽巷抽采流量）>A（供风量）>B（低抽巷抽采流量），二次项重要度排序为AC（供风量和高抽巷抽采流量）>AB（供风量和低抽巷抽采流量）>BC（低抽巷抽采流量和高抽巷抽采流量），且AB,AC,BC之间均无交互作用。     

The passion bug: How and when do leaders inspire work passion?

Drawing from signaling theory, we propose a work passion transfer model where leaders' passion is transmitted to employees through the former's leadership style and is contingent on employees' perceived importance of performance to self-esteem (IPSE). Data from 201 supervisor–employee dyads from the health-care industry show that leaders' harmonious passion led to employees' harmonious passion through charismatic leadership, whereas contingent reward leadership accounted for the transfer of obsessive passion; IPSE did not play a moderating role for either form of passion. Results from a supplementary study further reveal that the link between leadership and employee passion operated through employees' perception of leader passion and that employees' IPSE accentuated for the relationship between perceived leader obsessive passion and employees' obsessive passion. This study advances research in work passion, leadership, and signaling theory and provides important implications for managerial practice.     

高含盐废水脱盐处理技术研究进展

综述了几种常见的高含盐废水脱盐处理技术的发展历程、工艺原理、优缺点及目前的研究进展，分析了热分离、膜分离、电渗析、离子交换、电吸附、微生物脱盐等方法的优缺点，展望了未来废水脱盐工艺的发展方向。指出：脱盐方法将根据各类水体的水质特点更加精细化；多种脱盐技术联合应用也是今后废水脱盐的发展方向。     

On the search for mimetic patterns in environmental disclosure: an international perspective

In this paper, we assert and test the proposition that environmental disclosure (ED) is structured by institutionalised myths and that is why ED is decoupled from environmental performance and media pressures. Focusing on firms from Canada, France and Germany, findings show that ED mimetic isomorphism for different topics varies among countries and by industry sensitiveness to the environment. The results corroborate the institutional presumption that institutionalised myths vary among different contexts. Our findings also suggest that institutionalised ED structures may not reflect environmental performance, mimetic patterns being affected by environmental performance. However, the decoupling between ED mimetic isomorphism and environmental performance decrease when firms’ ED credibility is questioned by the media.     

Structural equation model analysis for the evaluation of overall driving performance: A driving simulator study focusing on driver distraction

Objective: The present research relies on 2 main objectives. The first is to investigate whether latent model analysis through a structural equation model can be implemented on driving simulator data in order to define an unobserved driving performance variable. Subsequently, the second objective is to investigate and quantify the effect of several risk factors including distraction sources, driver characteristics, and road and traffic environment on the overall driving performance and not in independent driving performance measures.

Methods: For the scope of the present research, 95 participants from all age groups were asked to drive under different types of distraction (conversation with passenger, cell phone use) in urban and rural road environments with low and high traffic volume in a driving simulator experiment. Then, in the framework of the statistical analysis, a correlation table is presented investigating any of a broad class of statistical relationships between driving simulator measures and a structural equation model is developed in which overall driving performance is estimated as a latent variable based on several individual driving simulator measures.

Results: Results confirm the suitability of the structural equation model and indicate that the selection of the specific performance measures that define overall performance should be guided by a rule of representativeness between the selected variables. Moreover, results indicate that conversation with the passenger was not found to have a statistically significant effect, indicating that drivers do not change their performance while conversing with a passenger compared to undistracted driving. On the other hand, results support the hypothesis that cell phone use has a negative effect on driving performance. Furthermore, regarding driver characteristics, age, gender, and experience all have a significant effect on driving performance, indicating that driver-related characteristics play the most crucial role in overall driving performance.

Conclusions: The findings of this study allow a new approach to the investigation of driving behavior in driving simulator experiments and in general. By the successful implementation of the structural equation model, driving behavior can be assessed in terms of overall performance and not through individual performance measures, which allows an important scientific step forward from piecemeal analyses to a sound combined analysis of the interrelationship between several risk factors and overall driving performance.     

Pressurized liquid extraction of six tetracyclines from agricultural soils

Veterinary antibiotics used in agriculture can be introduced into the environment through land application of animal manure, accumulating in soils and groundwaters and posing a significant risk to human health and animal well-being. As the analysis of tetracyclines in soil is challenging due to their strong interaction with soil minerals and organic carbon, the objective of this study was to develop a reliable and reproducible method for quantitative analysis of chlortetracycline and oxytetracycline, and their respective metabolites in soils. A method based on pressurized liquid extraction (PLE) with in-cell clean-up was developed for the extraction of chlortetracycline and oxytetracycline and four likely metabolites from a set of four soils. Optimized conditions included a cell size of 22?mL, soil loading of 5?g, pH of 8.0, methanol:water ratio of 3:1, 50?°C, and two cycles. Soil extracts were analysed by high-performance liquid chromatography (HPLC) coupled with ion trap mass spectrometry (MS). Recoveries of seven tetracyclines from soil ranged from 41% to 110%. The limits of detection for tetracyclines were 0.08–0.3 µg g^?1 soil, and intra- and inter-day variation ranged from 0.12–0.34%. The proposed PLE method is suitable for quantification of tetracyclines in agricultural soils at typical concentrations expected in contaminated environments.     

The potential of vehicle and road infrastructure interventions in fatal bicyclist accidents on Swedish roads—What can in-depth studies tell us?

Abstract

Objective: The objective of this article is to describe the characteristics of fatal crashes with bicyclists on Swedish roads in rural and urban areas and to investigate the potential of bicycle helmets and different vehicle and road infrastructure interventions to prevent them. The study has a comprehensive approach to provide road authorities and vehicle manufacturers with recommendations for future priorities.

Methods: The Swedish Transport Administration’s (STA) in-depth database of fatal crashes was used for case-by-case analysis of fatal cycling accidents (2006–2016) on rural (n?=?82) and urban (n?=?102) roads. The database consists of information from the police, medical journals, autopsy reports, accident analyses performed by STA, and witness statements. The potential of helmet use and various vehicle and road infrastructure safety interventions was determined retrospectively for each case by analyzing the chain of events leading to the fatality. The potential of vehicle safety countermeasures was analyzed based on prognoses on their implementation rates in the Swedish vehicle fleet.

Results: The most common accident scenario on rural roads was that the bicyclist was struck while cycling along the side of the road. On urban roads, the majority of accidents occurred in intersections. Most accidents involved a passenger car, but heavy trucks were also common, especially in urban areas. Most accidents occurred in daylight conditions (73%). Almost half (46%) of nonhelmeted bicyclists would have survived with a helmet. It was assessed that nearly 60% of the fatal accidents could be addressed by advanced vehicle safety technologies, especially autonomous emergency braking with the ability to detect bicyclists. With regard to interventions in the road infrastructure, separated paths for bicyclists and bicycle crossings with speed calming measures were found to have the greatest safety potential. Results indicated that 91% of fatally injured bicyclists could potentially be saved with known techniques. However, it will take a long time for such technologies to be widespread.

Conclusions: The majority of fatally injured bicyclists studied could potentially be saved with known techniques. A speedy implementation of important vehicle safety systems is recommended. A fast introduction of effective interventions in the road infrastructure is also necessary, preferably with a plan for prioritization.     

HUD状态下飞行员视觉注意资源分配机制研究

为了解决平视显示器（Head Up Display,HUD）飞行中的注意资源分配问题，基于飞行模拟器，设计双作业飞行任务开展相关研究。基于事件相关电位（Event Related Potential，ERP）技术，选取行为绩效和P300成分为评价指标，采用oddball模式，在双作业飞行任务条件下开展实验研究。结果表明:随主任务难度的增加，主、辅任务的作业绩效均显著下降，被试者对HUD上异常信息的正确操作率降低，且反应时间延长；随主任务难度的增加，由辅任务所诱发的P300的波幅显著降低。在实验结果的基础上，最终提出了HUD状态下飞行员视觉注意资源分配机制。     

大数据环境下企业安全绩效管理的基础性问题*

为明晰大数据对安全绩效管理的影响，把握信息时代下企业安全绩效管理的研究方向，基于大数据时代下安全绩效管理内容，阐述数据驱动下安全绩效管理的应用优势，探讨数据驱动下安全绩效管理的研究变革，剖析大数据环境下企业安全绩效管理的数据流向，构建数据驱动下安全绩效管理的框架模型，并提出数据驱动下企业安全绩效管理应用对策。结果表明:基于大数据的安全绩效管理有助于提升企业安全管理水平，也为安全生产系统优化提供理论依据。