用BaCl2滴定法快速测定硫酸盐的研究

用铬酸钡光度法、EDTA滴定法、间接原予吸收法、离子色谱法等方法测定SO4^2-检测上限都很低（12—200mg／L），且只适用于清洁水，若水样混浊则会引起较大的误差。有的地下水，SO4^2-浓度高迭44000mg／L，用BaCl2滴定法测定SO4^2-：测试水样，以溴酚蓝做酸碱指示剂，加1：50盐酸，调为pH=3．5，加入30ml异丙醇，以钍试荆做终点指示荆，滴加0．01mol／L BaCl2，砖红色为终点，根据BaCl2用量计算SO4^2-浓度。本方法快捷、准确、测定范围大，上限可迭2000mg／L，克服了光度法测定浑浊水样引起误差大的缺点。     

用BaCl2滴定法快速测定硫酸盐的研究

用铬酸钡光度法、EDTA滴定法、间接原子吸收法、离子色谱法等方法测定SO42-检测上限都很低(12-200mg/L),且只适用于清洁水,若水样混浊则全引起较大的误差.有的地下水,SO42-浓度高达44000mg/L,用BaCl2滴定法测定SO42-:测试水样,以溴酚蓝做酸碱指示剂,加1∶50盐酸,调为pH=3.5,加入30ml异丙醇,以钍试剂做终点指示剂,滴加0.01mol/L BaCl2,砖红色为终点,根据BaCl2用量计算SO42-浓度.本方法快捷、准确、测定范围大,上限可达2000mg/L,克服了光度法测定浑浊水样引起误差大的缺点.     

Evaluation of best management practice products in preventing discharge of metals: a laboratory evaluation

Heavy metal accumulation in soil poses serious environmental and health risks, as metals are carried with eroded soils. In this study, 17 different soil erosion and sediment control products were investigated for their effectiveness in controlling transport of particulate heavy metals (Cu, Zn, Pb, Cd). Among the treatments investigated, wood mulch and tackifiers were found to be the most effective in reducing total suspended solids (TSS) and total heavy metal losses. They reduced TSS to an undetectable level during short-term simulation tests. Paper mulch was the only treatment that had no significant reduction in both total metal loss and TSS. Fiber rolls, silt fences, and gravel bags were effective in reducing sediment loss. Although the netting/blanket treatments were not effective in reducing total metal discharge, they significantly reduced sediment loss compared with the control.     

Designing Systematic Conservation Assessments that Promote Effective Implementation: Best Practice from South Africa

Abstract:  Systematic conservation assessment and conservation planning are two distinct fields of conservation science often confused as one and the same. Systematic conservation assessment is the technical, often computer-based, identification of priority areas for conservation. Conservation planning is composed of a systematic conservation assessment coupled with processes for development of an implementation strategy and stakeholder collaboration. The peer-reviewed conservation biology literature abounds with studies analyzing the performance of assessments (e.g., area-selection techniques). This information alone, however, can never deliver effective conservation action; it informs conservation planning. Examples of how to translate systematic assessment outputs into knowledge and then use them for "doing" conservation are rare. South Africa has received generous international and domestic funding for regional conservation planning since the mid-1990s. We reviewed eight South African conservation planning processes and identified key ingredients of best practice for undertaking systematic conservation assessments in a way that facilitates implementing conservation action. These key ingredients include the design of conservation planning processes, skills for conservation assessment teams, collaboration with stakeholders, and interpretation and mainstreaming of products (e.g., maps) for stakeholders. Social learning institutions are critical to the successful operationalization of assessments within broader conservation planning processes and should include not only conservation planners but also diverse interest groups, including rural landowners, politicians, and government employees.     

Impacts of Climate Variability and Land Use Alterations on Frequency Distributions of Terrestrial Runoff Loading to Coastal Waters in Southern California1

Abstract: The transport of water, sediment, dissolved and particulate chemicals, and bacteria from coastal watersheds affects the nearshore marine and estuarine waters. In southern California, coastal watersheds deliver water and associated constituents to the nearshore system in discrete pulses. To better understand the pulsed nature of these watersheds, frequency distributions of simulated runoff events are presented for: (1) three land use conditions (1929, 1998, 2050); (2) three time periods (all water years 1989‐2002), only El Nino years (1992, 1993, 1995, 1998); and only non‐El Nino years; and (3) three regions (watershed, uplands, and lowlands). At the watershed scale, there was a significant increase (>200%) in mean event runoff from 1929 to 2050 (0.4‐1.3 cm) due to localized urbanization, which shifted the dominant sources of runoff from the mountains in 1929 (78% of watershed runoff) to the coastal plane for 2050 conditions (51% of watershed runoff). Inter‐annual climate variability was strong in the rainfall and runoff frequency distributions, with mean event rainfall and runoff 66 and 60% larger in El Nino relative to non‐El Nino years. Combining urbanization and climate variability, 2050 land conditions resulted in El Nino years being five times more likely to produce large (>3.0 cm) runoff events relative to non‐El Nino years. Combining frequency distributions of event runoff with regional nutrient export relationships, we show that in El Nino years, one in five events produced runoff ≥2.5 cm and temporary nearshore nitrate and phosphate concentrations of 12 and 1.4 μM, respectively, or approximately 5‐10 times above ambient conditions.     

PRINCIPLES FOR INTERNATIONAL GROUND-WATER LAW (I)

International ground-water resources have not received their full share of legal investigation. This paper outlines some principles applicable to the development of international co-operation concerning this important resource, bearing in mind that ground and surface waters are the same resource. In the absence of positive international law covering ground-water resources, national laws are investigated to examine their suitability for adaptation to the international level. In a second paper, to be published in the next issue of the Forum , the interjurisdictional experience among federated states and among independent states will be reviewed.     

SPATIALLY EXPLICIT HYDROLOGIC MODELING OF LAND USE CHANGE1

ABSTRACT: Using a Geographic Information System (GIS), a method is presented to develop a spatially explicit time series of land use in an urbanizing watershed. The method is prefaced on the existence of independent observations of land use at different times and data that describes the spatial‐temporal land use transition characteristics of the watershed between these two points in time. A method is then presented to generalize the TR‐55 graphical method, a common lumped hydrologic model for estimating peak discharge, for use in a spatially explicit scheme. This scheme predicts peak discharge throughout a watershed, rather than at a single selected watershed outlet. Coupling these two methods allows the engineer to model both the temporal and spatial evolution of peak discharge for the watershed. An illustrative watershed in a suburban area of Washington, DC is selected to demonstrate the methods. The model results from these analyses are presented graphically to highlight the complex features in peak discharge behavior that exist both spatially, as a function of position within the watershed drainage network, and temporally, as the watershed undergoes urbanization. These features are not commonly noted in most hydrologic analyses but are captured in these analyses because of the high spatial and temporal resolution of the methods presented. The physical implications of the modeled results are discussed in the context of the information content of a stream gauge located at the overall outlet of the illustrative watershed. This work shows that the common practice of transposition of gauge information to locations internal to the watershed would neglect internal variability in peak discharge behavior, and could potentially lead to the determination of inappropriate design discharges.     

Spatial and Temporal Variations in Eastern U.S. Hydrology: Responses to Global Climate Variability

Coastal ecosystems are dependent on terrestrial freshwater export which is affected by both climate trends and natural climate variability. However, the relative role of these factors is not clear. Here, both climate trends and internal climate variabilities at different time scales are related to variations in terrestrial freshwater export into the eastern United States (U.S.) coastal region. For the recent 35‐year period, the intensified hydro‐meteorological processes (annual precipitation or evapotranspiration) may explain the observed streamflow variability in the northeast. However, in the southeast, streamflow is positively correlated with climate variability induced by the Pacific Ocean conditions (El Nino‐Southern Oscillation [ENSO] and Pacific Decadal Oscillation) rather than Atlantic Ocean conditions (Atlantic Multi‐decadal Oscillation and North Atlantic Oscillation). The centroid location for volume of terrestrial freshwater export integrated along the eastern U.S. has a positive temporal trend and is negatively correlated with ENSO conditions, suggesting the northward trend in freshwater export to U.S. eastern coast may be disturbed by the natural climate variability, especially ENSO conditions, i.e., the center of freshwater mass moves southward (northward) during El Nino (La Nina) years. The results indicate the spatial and temporal variations in freshwater export from the eastern U.S. are affected by both climate change and inter‐annual climate variability during the recent 35‐year period (1980‐2014).     

PRINCIPLES FOR INTERNATIONAL GROUND-WATER LAW (II)

This is the second part of a paper outlining some principles applicable to the development of international law in the sub-sector of ground-water resources. In the first part of the paper, in the previous issue of the Forum , national ground-water laws were investigated to examine their suitability for adaptation at the international level. This part of the paper is devoted to reviewing the interjurisdictional experience among federated states and among independent states. It also draws the general conclusion of the entire paper.     

IMPACTS OF CALIFORNIA'S CLIMATIC REGIMES AND COASTAL LAND USE CHANGE ON STREAMFLOW CHARACTERISTICS1

ABSTRACT: To investigate the impacts of urbanization and climatic fluctuations on stream flow magnitude and variability in a Mediterranean climate, the HEC‐HMS rainfall/runoff model is used to simulate stream flow for a 14‐year period (October 1, 1988, to September 30, 2002) in the Atascadero Creek watershed located along the southern coast of California for 1929, 1998, and 2050 (estimated) land use conditions (8, 38 and 52 percent urban, respectively). The 14‐year period experienced a range of climatic conditions caused mainly by El Nino‐Southern Oscillation variations. A geographic information system is used to delineate the watershed and parameterize the model, which is calibrated using data from two stream flow and eight rainfall gauges. Urbanization is shown to increase peak discharges and runoff volume while decreasing stream flow variability. In all cases, the annual and 14‐year distributions of stream flow are shown to be highly skewed, with the annual maximum 24 hours of discharge accounting for 22 to 52 percent of the annual runoff and the maximum ten days of discharge from an average El Nino year producing 10 to 15 percent of the total 14‐year discharge. For the entire period of urbanization (1929 to 2050), the average increase in annual maximum discharges and runoff was 45 m³/s (300 percent) and 15 cm (350 percent), respectively. Additionally, the projected increase in urbanization from 1998 to 2050 is half the increase from 1929 to 1998; however, increases in runoff (22 m³/s and 7 cm) are similar for both scenarios because of the region's spatial development pattern.