Kinetics of continuous biodegradation of pesticide organic wastewater by activated carbon-activated sludge

１ＩｎｔｒｏｄｕｃｔｉｏｎＮｏｖｅｌｂｉｏｌｏｇｉｃａｌａｃｔｉｖａｔｅｄｃａｒｂｏｎａｎｄａｃｔｉｖａｔｅｄｓｌｕｄｇｅｓｙｓｔｅｍｈａｓｓｈｏｗｎｉｔｓｅｆｅｃｔｉｖｅａｂｉｌｉｔｙｔｏｒｅｄｕｃｅＣＯＤｉｎｔｏｘｉｃｏｒｇａｎｉｃｗａｓｔｅｗａ...     

Effect of platinum on the photocatalytic degradation of chlorinated organic compound

TiO2 nanoparticles, doped with di erent Pt contents, were prepared by a modified photodeposition method using Degussa P-25 TiO2, H2PtCl6 6H2O and methanol as the solvents. The physicochemical properties of Pt/TiO2 were investigated by the nitrogen adsorption and desorption isotherm measurement technique, X-ray di raction analysis and photoluminescence spectra, respectively. Reaction rates from photocatalytic removal of dichloromethane over Degussa P-25 TiO2 and Pt/TiO2 were evaluated. The average diameter and BET surface area of the TiO2 catalyst particles were 300 nm and 50 m2/g, respectively. The degradation e ciency was 99.0%, 82.7%, 55.2%, and 57.9% with TiO2 at inlet concentrations of 50, 100, 200, and 300 ppm, respectively. And the degradation e ciency was 99.3%, 79.7%, 76.5%, and 73.4% with a 0.005 wt.% Pt/TiO2 at inlet concentrations of 50, 100, 200, and 300 ppm, respectively. In addition, we found that the photoluminescence emission peak intensities decreased with increases in the doping amount of Pt, which indicates that the irradiative recombination was weakened. Furthermore, the results showed that the UV/0.005 wt.% Pt/TiO2 process was capable of e ciently decomposing gaseous DCM in air.     

Formation pathways of brominated products from benzophenone-4 chlorination in the presence of bromide ions

The brominated products, formed in chlorination treatment of benzophenone-4 in the presence of bromide ions, were identified, and the formation pathways were proposed.Under disinfection conditions, benzophenone-4 would undertake electrophilic substitution generating mono- or di-halogenated products, which would be oxidized to esters and further hydrolyzed to phenol derivatives. The generated catechol intermediate would be transformed into furan-like heterocyclic product. The product species were p H-dependent,while benzophenone-4 elimination was chlorine dose-dependent. When the chlorination treatment was performed on ambient water spiked with benzophenone-4 and bromide ions, most of brominated byproducts could be detected, and the acute toxicity significantly increased as well.     

Effect of methylmercury on LPO levels, SH groups and activities of GSH-Px, SOD, XOD in liver of rats

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Investigation of carbonyl compound sources at a rural site in the Yangtze River Delta region of China

Carbonyl compounds are important intermediates in atmospheric photochemistry, but their primary sources are still not understood well. In this work, carbonyls, hydrocarbons, and alkyl nitrates were continuously measured during November 2011 at a rural site in the Yangtze River Delta region of China. Mixing ratios of carbonyls and hydrocarbons showed large fluctuations during the entire measurement. The average level for total measured volatile organic compounds during the pollution episode from 25th to 27th November, 2011 was 91.6 ppb, about 7 times the value for the clean period of 7th-8th, November, 2011. To preliminarily identify toluene sources at this site, the emission ratio of toluene to benzene (T/B) during the pollution episode was determined based on photochemical ages derived from the relationship of alkyl nitrates to their parent alkanes. The calculated T/B was 5.8 ppb/ppb, significantly higher than the values of 0.2-1.7 ppb/ppb for vehicular exhaust and other combustion sources, indicating the dominant influence of industrial emissions on ambient toluene. The contributions of industrial sources to ambient carbonyls were then calculated using a multiple linear regression fit model that used toluene and alkyl nitrates as respective tracers for industrial emission and secondary production. During the pollution episode, 18.5%, 69.0%, and 52.9% of measured formaldehyde, acetaldehyde, and acetone were considered to be attributable to industrial emissions. The emission ratios relative to toluene for formaldehyde, acetaldehyde, and acetone were determined to be 0.10, 0.20 and 0.40 ppb/ppb, respectively. More research on industrial carbonyl emission characteristics is needed to understand carbonyl sources better.     

猛进水库水环境问题研究

猛进水库是五家渠地区的主要水源地,也是乌鲁木齐市重要的淡水鱼供应基地.近年来,猛进水库水质呈不断恶化的趋势,水质为劣V类,为此,猛进水库水质恶化问题已经成为各级政府及公众十分关注的问题.本文选用新疆水环境监测中心多年对猛进水库水质监测及调查的资料,对猛进水库水质现状进行分析评价,运用季节性肯达尔(Kendall)检验等方法,分析了猛进水库水质变化趋势及影响猛进水库水质的主要污染源,提出了进一步保护猛进水库水质的建议,为改善其水环境质量提供依据.     

Local Area Quotas for Industrial Emissions along Reaches of the Pearl River in Guangdong

There is an obvious departure from the regional equilibrium of developments between the upper and lower reaches of the Pearl River in Guangdong, which resulted in ＂the effects of contra-geography-grads development＂. It is mainly because the upriver mountainous areas have been deeply stuck in industrialization delay and marginalization plights, so that nearly 40 million local people have conceived a dream to get rid of ＂the vicious circle of poverty＂ by speeding up industrial development. But the problem is that such industrialization efforts on a large scale in mountainous areas are encountering the bottleneck of environmental capacity that strictly limits industrial emissions along the upper reaches of any water system. As a solution, an institutional arrangement called ＂the Local Area Quotas for Industrial Emissions along the Pearl River＂ is put forward supposed to give corresponding compensation to the rights of industrial development yielded by some areas with lower environmental capacity through the distribution and trading of IDQs.     

Characterizing the optimal operation of photocatalytic degradation of BDE-209 by nano-sized TiO2

Brominated flame retardants have been widely used in industry. There is a rapid growing public concern for their availabilities in the environment. Advanced oxidation process (AOP) is a promising and efficient technology which may be used to remove emerging chemicals such as brominated flame retardants. This project aims at investigating optimal operational conditions for the removal of BDE-209 using nano-scaled titanium(IV) oxide. The residual PBDE congeners after photocatalytical degradation of BDE-209 by TiO₂ were analysed by gas chromatography-mass spectrometry (GC-MS). It was found that the degradability of BDE-209 by TiO₂ was attributed to its photocatalytic activity but not the small size of the particles. The half-life of removing BDE-209 by TiO₂ was 3.05 days under visible light. Tetra- and penta-BDEs were the major degraded products of BDE-209. Optimum conditions for photocatalytical degradation of BDE-209 was found to be at pH 12 (93% ± 1%), 5, 10, 20 mg/L (93.0% ± 1.70%, 91.6% ± 3.21%, 91.9% ± 0.952%, respectively), respectively of humic acid and in the form of anatase/rutile TiO₂ (82% ± 3%). Hence, the efficiency of removing BDE-209 can be maximized while being cost effective at the said operating conditions.     

Repairing of rutin to the toxicity of combined F-53B and chromium pollution on the biofilm formed by Pseudomonas aeruginosa

The wastewater discharge from the process of chrome plating, which contains 6:2 chlorinated polyfluorinated ether sulfonate(F-53B) and chromium (Cr), may be toxic to biofilm.In this study we found that the biofilm formed by Pseudomonas aeruginosa PAO1 was inhibited by exposure to a combination of F-53B and Cr(VI). The combined pollution damaged the cell membranes and the structure of the biofilm, and inhibited the production of the Pseudomonas quinolone-based signal, which affected biofilm forma...     

Comparative study of microbial community structure in di erent filter media of constructed wetland

Comparisons of microbial community structure, in eight filter media of zeolites, anthracite, shale, vermiculite, ceramic filter media, gravel, steel slag and bio-ceramic, were undertaken by analyzing the phospholipid fatty acid (PLFA) composition. A total of 20 fatty acids in the range of C11 to C20 were determined but only 13 PLFAs were detected in steel slag. They consist of saturated fatty acids, branched fatty acids, monounsaturated fatty acids, and polyunsaturated fatty acids. The variation of fatty acids was revealed in the relative proportions of these fatty acids in di erent media. The aerobic prokaryotes were the predominant group in all media. The PLFA composition showed significant di erences among the eight di erent media by Tukey’s honestly test. It was found that steel slag was significantly di erent in the microbial community as compared to other filter media, probably due to its alkaline e uent. Steel slag alone is probably not a good choice of substratum in constructed wetlands. The principle components analysis (PCA) showed that zeolites, bio-ceramic, shale and vermiculite had a similar microbial community structure while steel slag and ceramic filter media were distinct from other media.