Oxidized multiwalled carbon nanotubes modified with 2-(2-hydroxy-5-nitrophenyl)-4,5-diphenyl imidazole for solid phase extraction and preconcentration of some metal ions

In this work, a new procedure for the enrichment of the trace amount of Cu²⁺, Ni²⁺, Co²⁺, Pb²⁺, Fe²⁺, and Zn²⁺ ions based on the utilization of multiwalled carbon nanotubes (MWCNT) modified with 2-(2-hydroxy-5-nitrophenyl)-4,5-diphenyl imidazole as chelating agent prior to their determination by flame atomic absorption spectrometry has been described. The influence of effective parameters including pH, amount of ligand and MWCNT, composition of eluent, and coexisting ions on recoveries of understudy metal ions was examined. At the optimum pH of 5.0, all metal ions were quantitatively sorbed onto the proposed solid phase and completely desorbed with 8?mL of 5.0?mol?L^?1 HNO₃. The detection limit of Cu²⁺, Co²⁺, Ni²⁺, Pb²⁺, Fe²⁺, and Zn²⁺ ions was 1.7, 2.4, 2.3, 2.9, 2.8, and 1.4?µg?L^?1, while the preconcentration factor was 63 for Cu²⁺ and 94 for the other metal ions and relative standard deviations between 1.8 less than 3.0%. The proposed procedure was applied for the analysis of various samples.     

Evaluation of vehicular emissions reduction strategies using a novel hybrid method integrating BWM,Q methodology and ER approach

Environment, Development and Sustainability - Road transportation is the main source of greenhouse gas (GHG) emissions in Iran. Different road transport emissions reduction strategies (RTERS) can...     

Upper trapezius fatigue in carpet weaving: the impact of a repetitive task cycle

Introduction. Shoulder disorders are one of the most prevalent musculoskeletal disorders among carpet weavers. The most important cause of these disorders is muscle fatigue. The aim of the present study is to investigate the effect of carpet weaving characteristics on upper trapezius (UTr) muscle fatigue during a task cycle. Method. In this cross-sectional study, 9 women and 3 men participated. During an 80-min cycle of carpet weaving, a times-series model was applied to assess electromyography amplitude and frequency changes. Result. According to the joint analysis of electromyogram spectrum and amplitude method, the participants experienced 0% force decrease, 0.9% recovery, 18% force increase and 72% fatigue in the left UTr. Furthermore, the rates of force decrease, recovery, force increase and fatigue in the right UTr were 18%, 18%, 18% and 45%, respectively. Fatigue in the right and the left UTr was reported to be the dominant state during one carpet weaving task cycle. Conclusion. Task cycle appears to have a significant impact on UTr fatigue in participants, and UTr fatigue can be considered a serious risk factor in shoulder musculoskeletal disorders. Hence, further studies should focus on better workstations and work–rest periods during various subtasks.     

Evaluation of the potential of Sasobit® to reduce required heat energy and CO2 emission in the asphalt industry

Warm-mix asphalt (WMA) has been gaining popularity in the asphalt industry primarily because of its ability to lower the energy required to blend asphalt mixes, which in turn results in less fuel consumption, slower aging of the asphalt binder and reduced emission of greenhouse gases. This paper evaluates the effects of different quantities of a WMA additive known as Sasobit^® on the required heat energy and the amount of CO₂ produced to increase the temperature of two aggregates from three sources and one binder from 25 °C to the point of mixing. The results showed that incorporating 1% Sasobit^® can potentially reduce the required heat energy and amount of CO₂ produced by 2.8% and 3.0%, respectively, for all aggregate types and sources investigated. The paper also presented design charts that enable energy policy makers and engineers to select the appropriate Sasobit^® content to produce the most cost effective asphalt mixture with less environmental impact. The design charts show that 1.6% Sasobit^® content is the most suitable proportion to be blended into the asphalt binder without compromising pavement resistance against fatigue failure. Two similar aggregates from different sources may exhibit similar specific gravities, but their specific heat capacities can vary widely. These differences have a significant effect on the required heat energy, asphalt production cost and the amount of emissions released into the environment.     

Multiple pollutant discharge permit markets,a challenge for wastewater treatment plants

This study focuses on the challenge of using a multiple pollutant transferable discharge permit market for operating wastewater treatment plants. It uses an analytical case of Sefidrud River in Iran with two checkpoints. It shows that the operating limitations for simultaneous biochemical oxidation demand (BOD) and total nitrogen (TN) removal may convert the economically optimal waste load allocation (WLA) to a framework with lack of incentives. Therefore, water quality trading (WQT) may lose its economical advantages. In this case, a third parameter, such as dissolved oxygen is recommended as an index for assigning market interactions. In spite of economical and practical success, this approach made WLA become a more complicated and uncertain policy. It was totally concluded that using single parameter WQT is only recommended for areas with small agricultural activities or lakes. Otherwise, the integrated discharged permit and reclaimed water market is proposed instead for simultaneous BOD and TN management.     

Discharge permit market and farm management nexus: an approach for eutrophication control in small basins with low-income farmers

The economic concerns of low-income farmers are barriers to nutrient abatement policies for eutrophication control in surface waters. This study brings up a perspective that focuses on integrating multiple-pollutant discharge permit markets with farm management practices. This aims to identify a more economically motivated waste load allocation (WLA) for non-point sources (NPS). For this purpose, we chose the small basin of Zrebar Lake in western Iran and used the soil and water assessment tool (SWAT) for modeling. The export coefficients (ECs), effectiveness of best management practices (BMPs), and crop yields were calculated by using this software. These variables show that low-income farmers can hardly afford to invest in BMPs in a typical WLA. Conversely, a discharge permit market presents a more cost-effective solution. This method saves 64% in total abatement costs and motivates farmers by offering economic benefits. A market analysis revealed that nitrogen permits mostly cover the trades with the optimal price ranging from $6 to $30 per kilogram. However, phosphorous permits are limited for trading, and their price exceeds $60 per kilogram. This approach also emphasizes the establishment of a regional institution for market monitoring, dynamic pricing, fair fund reallocation, giving information to participants, and ensuring their income. By these sets of strategies, a WLA on the brink of failure can turn into a cost-effective and sustainable policy for eutrophication control in small basins.     

Developing a new fuzzy inference system for pipeline risk assessment

The problem of less and/or even lack of information and uncertainty in modeling and decision making plays a key role in many engineering problems; so that, it results in designers and engineers could not reach to sure solutions for the problems under consideration. In this paper, an application of the fuzzy logic for modeling the uncertainty involved in the problem of pipeline risk assessment is developed. For achieving the aim, relative risk score (RRS) methodology, one of the most popular techniques in pipeline risk assessment, is integrated with fuzzy logic. The proposed model is performed on fuzzy logic toolbox of MATLAB^® using Mamdani algorithm based on experts' knowledge. A typical case study is implemented and a comparison between the classical risk assessment approach and the proposed model is made. The results demonstrate that the proposed model provides more accurate, precise, sure results; so that, it can be taken into account as an intelligent risk assessment tool in different engineering problems.     

Assessment of the living and workplace health and safety conditions of site-resident construction workers in Tehran,Iran

Objectives. The purpose of this study was to assess living and workplace safety conditions of construction workers in Tehran, Iran. Methods. This cross-sectional study was conducted among 410 construction sites in a municipal area of Tehran whose municipal building permits were issued in 2011. Data on ventilation, workplace safety and hygiene were collected by direct observation and interviews with site foremen. Noise levels were estimated from 10 sound-level-meter stations in the municipality area. Results. Lack of ventilation in the workers’ rooms was abundant. Bathrooms were unhygienic and minimum requirements such as lighting and ventilation did not exist in 80% of the cases. In nearly 50% of large construction sites, sewage and garbage disposal were inappropriate. Elevator safety was poor at all sites and no measures for fall prevention were present in over 88% of active construction sites. This study showed that the mean 24-h equivalent continuous sound level L_eq was over 70?dB in 80% of the sites during weekdays. Conclusions. The results of this study revealed poor health and safety living and working conditions of construction workers in Tehran.