Three-dimensional data interpolation for environmental purpose: lead in contaminated soils in southern Brazil

Monitoring of heavy metal contamination plume in soils can be helpful in establishing strategies to minimize its hazardous impacts to the environment. The objective of this study was to apply a new approach of visualization, based on tridimensional (3D) images, of pseudo-total (extracted with concentrated acids) and exchangeable (extracted with 0.5 mol L^?1 Ca(NO₃)₂) lead (Pb) concentrations in soils of a mining and metallurgy area to determine the spatial distribution of this pollutant and to estimate the most contaminated soil volumes. Tridimensional images were obtained after interpolation of Pb concentrations of 171 soil samples (57 points × 3 depths) with regularized spline with tension in a 3D function version. The tridimensional visualization showed great potential of use in environmental studies and allowed to determine the spatial 3D distribution of Pb contamination plume in the area and to establish relationships with soil characteristics, landscape, and pollution sources. The most contaminated soil volumes (10,001 to 52,000 mg Pb kg^?1) occurred near the metallurgy factory. The main contamination sources were attributed to atmospheric emissions of particulate Pb through chimneys. The large soil volume estimated to be removed to industrial landfills or co-processing evidenced the difficulties related to this practice as a remediation strategy.     

Herbicide application timing in preharvest desiccation of soybean cultivars with different growth habits

In order to evaluate the ideal time of herbicide applications to desiccate soybean cultivars with determinate and indeterminate growth habits in preharvest, an experiment was carried out at the University of Ponta Grossa (PR), during 2002--2003. The experimental design used was a randomized blocks arranged in a factorial scheme 4 x 5 (herbicides and time of application), with three replications, using four soybean cultivars: Spring, V-Max, BR-16, and BRS-133. The herbicides glufosinate, diquat, and paraquat were used at the rate of 400 g ha(-1), when soybean was at stage of R6.0, R6.5, R7.0, R7.5, and R8.0. The assessments included yield, as well as yield components, considering each cultivar separately. The results show that desiccation should be done on cultivars with determinate growth habit at stages between R7.0 and R7.5, independent of herbicide used. For indeterminate growth habit cultivars, desiccation should be done later, because those pods formed after R6.5 stage are important to define yield; although herbicides have different mode of action, yield results were similar. In cultivars, desiccation should start when all pods in the middle of plants become yellow and grains are not held by fibers.     

Energy efficiency and reduction of Co2 emissions through 2015: The Brazilian cement industry

The cement industry is characterisedby intensive energy consumption throughout itsproduction stages which, together with the calcinationof its raw materials, accounts for significant amountsof greenhouse gases (GHG) emissions. In 1996, theBrazilian cement industry consumed 4.3% of the energyrequired by the industrial sector, contributing over22 Tg (Teragrams) of CO₂. The prospects forgrowth in this sector in Brazil indicate risingdemands for fossil fuels, with a consequent upsurge inemissions. This article aims to present the prospectsfor energy conservation in the Brazilian cementindustry through to 2015, taking into account: theintroduction of new production technologies in thissector, the use of waste and low-grade fuels,cogeneration, the use of cementitious materials, andother measures, based on a technical and economicenergy demand simulation model. In all scenarios, wefound that is possible to significantly reduce energyconsumption and CO₂ emissions for BrazilianCement Industry. Under the market potential scenarios,energy savings vary between 1562.0 to 1900.6 PJ(PetaJoules), with use of cementitious materialsaccounting for around 31% of this total. Fortechnical potential scenarios, use of cementitiousmaterials could represent 51% to 52% of totalachieved energy savings, between 2374.6 to 2803.4 PJ.     

A review of the main methods for composite adsorbents characterization

Environmental Science and Pollution Research - Adsorption is a promising technology for removing several contaminants from aqueous matrices. In the last years, researchers worldwide have been...