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Neethu Kariyil Veettil Nandan Sivasankaran Bijoy Xavier Nelkunnassery Dominic Don Jayachandran Paravanparambil Rajakumar Anu Pashnath Raghu Midhun Alungal Manikandan Mohan Dhandapani Marigoudar Shambanagouda R. 《Environmental science and pollution research international》2021,28(2):1775-1788
Environmental Science and Pollution Research - The southwest coast of India along the Cochin region is seriously affected by metal contamination from increasing industrial activities. This... 相似文献
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K. Rajakumar V. Sarasvathy A. Thamarai Chelvan R. Chitra C. T. Vijayakumar 《Journal of Polymers and the Environment》2009,17(3):191-202
Polypropylene (PP) has achieved a dominating position and hence, their consumption increases thereby littering, which lead
to environmental pollution. Photodegradation seems to be a better choice because of naturally available sunlight as energy
source for degradation. The present work involves the study of the variation of degradation behavior of PP film during tropical
summer and winter seasons. The photodegradation is followed by Fourier transform infrared (FTIR) spectroscopic technique.
Various indices like hydroxyl, carbonyl, vinylidene, lactones, ester, carboxylic acid and crystallinity are calculated and
these values increased after a brief induction period. The variation in the mechanical properties like tensile strength and
elongation at break percentages are determined. The scanning electron microscopic (SEM) images of weathered PP showed surface
cracks when carbonyl index value increases sharply and the mechanical properties show a sudden decrease. Attempted life time
prediction using mathematical models showed that the carbonyl growth is more affected by ultraviolet (UV) and cumulative total
solar radiation for PP weathered during summer. The loss in tensile strength of PP weathered during summer is more dependent
on the average temperature and the UV portion of the total solar radiation whereas, intensity of UV radiation has profound
effect on the tensile strength of PP weathered during winter. 相似文献
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Howrelia JH Patnaik BB Selvanayagam M Rajakumar S 《Journal of environmental biology / Academy of Environmental Biology, India》2011,32(1):99-103
The present study investigated the effect of increasing temperature stress on the thermotolerance of B. mori cross-breed PM x CSR2 and tissue specific differential expression of heat shock proteins at IVth and Vth instars. The larvae reared at 25 +/-1 degrees C and 70 +/- 5% relative humidity were treated as control. Larvae were subjected to heat shock temperatures of 34, 38 and 42 degrees C for 3 hr followed by 3 hr recovery. Expression of Heat shock protein 72 were analyzed by SDS-PAGE and confirmed by western blotting analysis. The impact of heat shock on commercial traits of cocoons was analyzed by following different strategies in terms of acquired thermotolerance over control. Resistance to heat shock was increased as larval development proceeds and increased thermotolerance is achieved with the induction of Heat shock protein 72 in the Vth instar larval haemolymph. Relative influence of heat shock temperatures on commercial traits corresponding to the generation of heat shock protein 72 was significantly improved over control. In PM x CSR2, cocoon and shell weight significantly increased to 9.90 and 11.90% over control respectively. 相似文献
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Mondal Koushik Rajakumar Balla 《Environmental science and pollution research international》2023,30(9):22590-22605
Environmental Science and Pollution Research - Kinetics of the reaction of IO radicals with methanol (MeOH) and ethanol (EtOH) were experimentally studied in the gas phase using pulsed laser... 相似文献
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Venkidasamy Baskar Subramanian Umadevi Samynathan Ramkumar Rajakumar Govindasamy Shariati Mohammad Ali Chung Ill-Min Thiruvengadam Muthu 《Environmental science and pollution research international》2021,28(6):6289-6301
Environmental Science and Pollution Research - Organopesticides (OPs) are a group of various synthetic chemicals prevalently used in agriculture and homestead plantations. OPs were originally... 相似文献
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The mechanism by which Pseudomonas aeruginosa degraded Navitan Fast Blue S5R was studied using TLC, FTIR, HPLC and GC-MS analysis. Degradation started with the reduction of azo bonds producing metanilic acid and peri acid whose presence was confirmed by HPLC. Aniline, the desulfonated product from metanilic acid and salicylic acid could also be detected by HPLC. GC-MS analysis of the degradation products confirmed the presence of aniline and revealed the presence of beta-ketoadipic acid. Based on these products a probable pathway has been proposed for the degradation of Navitan Fast Blue S5R by Pseudomonas aeruginosa. 相似文献
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Manoj Patowary Rajakumar Ananthakrishnan Khanindra Pathak 《Environmental science and pollution research international》2017,24(22):18063-18072
Development of efficient techniques to combat the harmful effects of oil spill is an emerging field, where fabrication of new sorbents for selective removal of oil has become a hot topic for environmental scientists. The present study reports the preparation of superhydrophobic/oleophilic magnetic titania nanotubes via a facile hydrothermal method, followed by the treatment with octadecylamine, as potential magnetically driven sorbent for selective removal of oil from water surface. The magnetic nature (superparamagnetism at 300 K) of the nanotubes enabled magnetic removal of the oil-sorbed material from water surface. Wettability test of the material depicted a static water contact angle of 166 ± 1°, indicating its superhydrophobic character. Oil uptake experiments and contact angle measurements revealed its superoleophilicity with maximum oil sorption capacity >1.5 g/g for a variety of oils. In addition to the ease of magnetic removal, the nanotubes possess sufficient buoyancy, high selectivity, and quick rate of oil uptake and is more than five times reusable. 相似文献
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To evaluate the potential environmental effects of engineered nano metals, it is important to determine the adverse effects of various nanomaterials on aquatic species. Adult tilapia (Oreochromis mossambicus) were maintained in 10 L glass aquaria, and exposed to a graded series of synthesized silver nanoparticles (Ag-NPs) at 25, 50 and 75 mg/L for eight days. The LC50 value was 12.6 mg/L. Reduced activities of antioxidant enzymes and the contents of antioxidants were lowered in the gills and liver of fishes treated with Ag-NPs, which resulted in heavy accumulation of free radicals. Histopathological results imply that the balance between the oxidative and antioxidant system in the fish was broken down during Ag-NPs exposure. The principal concern related with the release of nanomaterials and their smaller particle may change the materials transport and potential toxicity to aquatic organisms compared to larger particles. 相似文献
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A simple, cost effective and rapid electrochemical method has been developed for the determination of micro level ortho nitrobenzaldehyde(ONB) based on outstanding properties of modified aluminum electrode tin nanorods/anodic aluminum oxide/aluminum(SnNR/AAO/Al) for the first time. The SnNR/AAO/Al electrode was fabricated by a second step anodization, followed by electrodeposition and its electrochemical behavior was investigated in detail. The cyclic voltammetry results indicated that the SnNR/AAO/Al electrode exhibited efficient electrocatalytic activity toward reduction of ONB in the acidic solution. It provides an appreciable improvement of reduction peak for ONB at-0.721 V.Furthermore, various kinetic parameters such as transfer electron number, transfer proton number and standard heterogeneous rate constant were calculated from the scan rates.The electrocatalytic behavior was further exploited as a sensitive detection scheme for the ONB determination by differential pulse voltammetry. Under the optimized conditions, the concentration range and detection limit are 0.1-100 μmol/L and 0.05 μmol/L, respectively,for ONB. The analytical performance of this modified sensor has been evaluated for detection of real sample such as river water and recovery of ONB was achieved all-out up to102.3% under standard addition method. 相似文献
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