A performance evaluation of the National Air Quality Forecast Capability for the summer of 2007

This paper provides a performance evaluation of the real-time, CONUS-scale National Air Quality Forecast Capability (NAQFC) that supported, in part, its transition into operational status. This evaluation focuses primarily on discrete forecasts for the maximum 8-h O₃ concentrations covering the 4-month period, June through September, 2007, using measurements obtained from EPA's AIRNow network. Results indicate that the 2007 NAQFC performed as well or better than previous configurations, despite the expansion of the forecast domain into the western half of the nation that is dominated by complex terrain. The mean, domain-wide, season-long correlation was 0.70. When examined over time, the domain-wide correlations exhibit a fairly consistent nature, with values exceeding 0.60 (0.70) over 90% (55%) of the days. The NAQFC systematically over-predicted the 8-h O₃ concentrations, continuing a trend established by earlier NAQFC configurations, though to a lesser degree. The summer-long mean forecast value of 53.2 ppb was 4.2 ppb higher than the observed value, resulting in a domain-wide Normalized Mean Bias (NMB) of 8.7%. Most of the over-prediction is associated with observed concentrations less than 50 ppb. In fact the model tends to under-predict when concentrations exceed 70 ppb. As with the bias, the error associated with the latest configuration was also lower. The summer-long Root Mean Square Error of 13.0 ppb (Normalized Mean Error (NME) = 20.4%) represented marked improvements over earlier forecasts. Examination of the spatial distribution of both the NMB and NME reveals that the NAQFC was generally within 25% for the NME and 25% for the NMB over a majority of the domain. Several areas of poorer performance, where the NMB and NME often exceed 25% and in some cases 50%, were noted. These areas include southern California, where the NAQFC tended to under-predict concentrations (especially on weekends) and the southeast Atlantic and Gulf coasts regions, where the model over-predicted. Subsequent analysis revealed that the incorrect temporal allocation of precursor emissions was likely the source of the under-prediction in southern California, while inaccurate simulation of PBL heights likely contributed to the over-prediction in the coastal regions.     

226Ra, 232Th and 40K analysis in soil samples from some areas of Malwa region, Punjab, India using gamma ray spectrometry

The activity concentrations of soil samples collected from thirty different locations of Malwa region of Punjab were determined by using HPGe detector based on high-resolution gamma spectrometry system. The range of activity concentrations of ²²⁶Ra, ²³²Th and ⁴⁰K in the soil from the studied areas varies from 18.37 Bq kg⁻¹ (Sangrur) to 53.11 Bq kg⁻¹ (Sitoguno), 57.28 Bq kg⁻¹ (Dhanola) to 148.28 Bq kg⁻¹ (Sitoguno) and 211.13 Bq kg⁻¹ (Sunam) to 413.27 Bq kg⁻¹ (Virk Khera) with overall mean values of 35 Bq kg⁻¹, 80 Bq kg⁻¹and 317 Bq kg⁻¹ respectively. The absorbed dose rate calculated from activity concentration of ²²⁶Ra, ²³²Th and ⁴⁰K ranges between 8.47 and 24.48, 35.68 and 92.38, and 8.74 and 17.11 nGy h⁻¹, respectively. The total absorbed dose in the study area ranges from 58.08 nGy h⁻¹ to 130.85 nGy h⁻¹ with an average value of 79.11 nGy h⁻¹. The calculated values of external hazard index (H_ex) for the soil samples of the study area range from 0.35 to 0.79. Since these values are lower than unity, therefore, according to the Radiation Protection 112 (European Commission. Radiation Protection 112 1999) report, soil from these regions is safe and can be used as a construction material without posing any significant radiological threat to population.     

Translocation of metals and its effects in the tomato plants grown on various amendments of tannery waste: evidence for involvement of antioxidants

A field experiment was conducted to study the effect of different amendments of tannery sludge on physiological and biochemical parameters of tomato plant (Lycopersicon esculentum L. Mill). The accumulation of metals (Cr, Fe) in different parts of tomato plants grown on tannery sludge amended soil increased in a concentration and duration-dependent manner. The accumulation of both the metals was found lowest in the fruits of the plant. The statistical analysis of the results showed an increase in chlorophyll and protein contents in lower sludge amendment ratio at all exposures followed by a decrease at highest (100%) sludge amendment ratio. Lipid peroxidation enhanced in both root and leaves of sludge grown plants of tomato at all the sludge amendments and exposure periods, which is evidenced by increased malondialdehyde content, however the maximum increase was found in the roots (43.63%) and leaves (56.66%) of the plant grown on 100% tannery sludge at 60 d, over respective controls. The level of antioxidants, cysteine, non-protein thiol and ascorbic acid increased in the sludge grown plants of tomato to cope up with stress induced by the excess amount of the heavy metals present in the tannery sludge. The maximum increase was found in cysteine content (75.53% in the leaves), non-protein thiol content (92.68% in the roots) and ascorbic acid content (29.66% in the roots) of the plant at 75% tannery sludge after 30 d. The tomato plants were found well adopted for minimizing damage induced by reactive oxygen species, when grown on tannery sludge amendments in the present study.     

Glutathione as a matrix for the synthesis of CdS nanocrystallites

GSH-capped CdS nanocrystallites were synthesized by reacting Cd(II)-GSH with aqueous sodium sulfide using specific initial sulfide/Cd(II) ratios. Spectroscopic analyses of fractions obtained from a size exclusion column showed varying absorption spectra indicating a significant dispersion in size-distribution of nanocrystallites at lower sulfide/Cd(II) ratios. However, size distribution of the nanocrystallites was narrower at initial sulfide/Cd(II) ratios that exceeded 1.0. An ethanol precipitation procedure was used to remove free Cd(II)-GSH complexes and selectively isolate GSH-capped nanocrystallites in a very narrow size range. Size exclusion chromatography indicated similar chemical compositions and overlapping spectral profiles of ethanol-precipitated samples suggesting apparent uniformity in both the size and the cap content. All of the GSH-capped CdS nanocrystallites with varying cap contents degraded p-nitrophenol upon irradiation at 366 nm. However, photocatalytic degradation of p-nitrophenol was significantly higher in samples with higher sulfide/Cd ratio and less capping material. The addition of H2O2 enhanced levels of photo-oxidation of p-nitrophenol.     

Recent advancements in the challenges and strategies of globally used traffic noise prediction models

Environmental Science and Pollution Research - It is the need of an era to develop efficient traffic noise prediction models with optimum accuracy. In this context, the present work tries to...     

Nanomaterials photocatalytic activities for waste water treatment: a review

Water is necessary for the survival of life on Earth. A wide range of pollutants has contaminated water resources in the last few decades. The presence of contaminants incredibly different dyes in waste, potable, and surface water is hazardous to environmental and human health. Different types of dyes are the principal contaminants in water that need sudden attention because of their widespread domestic and industrial use. The toxic effects of these dyes and their ability to resist traditional water treatment procedures have inspired the researcher to develop an eco-friendly method that could effectively and efficiently degrade these toxic contaminants. Here, in this review, we explored the effective and economical methods of metal-based nanomaterials photocatalytic degradation for successfully removing dyes from wastewater. This study provides a tool for protecting the environment and human health. In addition, the insights into the transformation of solar energy for photocatalytic reduction of toxic metal ions and photocatalytic degradation of dyes contaminated wastewater will open a gate for water treatment research. The mechanism of photocatalytic degradation and the parameters that affect the photocatalytic activities of various photocatalysts have also been reported.

     

Impact of Fly Ash from Coal-Fired Power Stations in Delhi, with Particular Reference to Metal Contamination

Indraprastha Power Station (IPP Stn) and Rajghat Power House (RPH), owned by Delhi Electric Supply Undertaking, are both coal-fired power stations located on Ring Road in New Delhi. Ash content of the coal used ranges between 38–47%. The ash is collected in electrostatic precipitators which have an efficiency of 99.3% (IPP station), and 99.7% (RPH). There are instances of major dust pollution around the power stations from fly ash dispersal. The main method of disposal of fly ash from the power stations is by mixing with water, the resultant slurry is pumped through pipes to ash disposal ponds. The supernatant from these ponds is discharged into River Yamuna. Field studies have revealed large quantities of fly ash being deposited into the river. Local populations of Eichhornia crassipes have reduced dramatically between 1987–1995, with a marked reduction in the year 1994–1995. Field studies, conducted in January, 1995 have investigated the impact of fly ash dispersal in the Delhi region with particular reference to metal contamination. Elemental concentrations for a range of elements are determined by ICP-AES in fly ash and top soils along four transects from the power stations up to a distance of 8 km. The effects of fly ash leachates from the ash settling ponds on the river are determined by analyzing river overbank soils and vegetation for their elemental contents. It is concluded that fly ash dispersal from the stacks are a source of alkali, alkaline-earth and to some extent heavy metals in soils in the vicinity of the power stations, and enrichment of elements in river overbank soils are a result of discharge of fly ash leachates from ash disposal ponds. However, the impact from both these sources of metal contamination is not large enough to give cause for concern. Marked reduction in populations of Eichhornia crassipes downstream of the river where it receives leachates from the ash disposal ponds are attributed to turbidity of the ash pond leachates and metal toxicity. Elemental enrichment in the floodplain soils, as a result of fly ash particle deposition during monsoons, may enhance the horticultural value of these soils as is shown by a healthy cultivated crop of Brassica juncea.     

Experimental investigation of groundwater contamination by surface sources: Determination of adsorption capacity,diffusion, and sorption potential of selected anions in different soils

The present study investigated the fate and transport of two significant anions through soil to explore their potential as groundwater contaminants. The retention properties of chloride and sulfate in soils having several significantly different characteristics (soil‐1 and soil‐2) were determined using adsorption test and adsorption‐diffusion column experiments. The maximum adsorption capacity of chloride was 3.7 and 1.16 mg/g, respectively, in soil‐1 and soil‐2, with organic matter (OM) content of 3.92% and 4.69%, respectively. The sulfate adsorption obtained was 24.09% and 13.83%, respectively, in the two soils. The anions exhibited monolayer adsorption in the soils with replacement of hydroxyl ions from soils as the major mechanism of adsorption. On the other hand, the adsorption capacities obtained from the adsorption‐diffusion column experiment were about 100 times lower compared to that of the column tests of both of the soils. The maximum adsorption capacity of chloride was 0.03 mg/g and 0.01 mg/g, respectively, in soil‐1 and soil‐2, whereas that of sulfate was 0.04 mg/g and 0.03 mg/g. The empirical relation for depth of penetration (d) from a known spillage onto the soil surface was determined as a function of sorption capacity (S) and initial anion concentration (C) as d = 0.0073e^(?57S)C and d = 0.0038e^(?35S)C for chloride and sulfate, respectively.     

Spatial analysis of soil resources in the Mewat district in the semiarid regions of Haryana,India

The soil characteristics are critical for crop health and its yield and therefore for agriculture. The soil properties are spatially variable and therefore soil resources should be managed as per location-specific requirements. An integrated spatial analysis of the soil resources of Mewat district was conducted to identify the soil resource management zones to develop site-specific soil management plan which might lead to sustained and enhanced crop yield. Spatial analysis of soil resources was conducted by modeling soil fertility and erosion which determines the crop productivity in the region. Soil fertility of the region was modeled using weighted overlay approach using 10 soil parameters, namely nitrogen, phosphorus, potassium, sulfur, iron, zinc, manganese, organic carbon, electrical conductivity, and pH. Each parameter was assigned weights based on their relative importance to agricultural productivity. The modeled soil fertility was classified into three fertility zones, low, medium, and high. Soil fertility was found to be low to moderate in 65% of the area, largely because of the low nitrogen, soil organic carbon, phosphorus concentration, and excessive salinity. Soil erosion was modeled using the universal soil loss equation (USLE) model by estimating rainfall erosivity factor (R), the soil erodibility factor (K), the topographic factors (L and S), cropping factor (C), and the conservation practice factor (P). Soil erosion problems were limited to areas having high elevation with barren land and areas with minimal management practices. The severity of soil erosion was found high in 15% of the region, while the remaining 85% showed low to moderate erosion. Soil fertility and erosion were integrated using the multivariate clustering method to identify soil management zones. The region was delineated into three soil management zones. Zone I (29%) which covers majorly Tarou block, was characterized by high soil fertility and low soil erosion. Zone II (18%) with medium soil fertility and high erosion covers villages of Taoru, Nuh, Nagina, FP Jhirka, and Punhana, which are located in the foothills of Aravalli ranges. Zone III represents the major part of the region, covering Nuh, Nagina, and FP Jhirka blocks (54%) with low soil fertility and erosion conditions. Thus, within the study area, the soil management domains are spatially variable in terms of fertility and soil erosion, and thus zone-specific soil management measures are required to improve the soil condition in order to sustain and improve agriculture production. The study would help the policy makers to design site-specific planning for identified soil resource management zones.     

A review on ex situ mineral carbonation

The increased CO₂ quantities in the environment have led to many harmful effects. Therefore, it is very important to decrease the CO₂ levels in the environment. CO₂ capture along with safe and permanent storage using mineral CO₂ sequestration method can play an important role to reduce carbon emissions into the environment. Mineral sequestration is a stable storage method that provides long-term storage and an appropriate substitute for the more popular geological storage method. The process is most suited for places where there is a lack of underground cavities for underground geological storage. Minerals rich in Ca and Mg are used predominantly in carbonation reactions. In addition, those alkaline wastes that are rich in Mg and Ca such as cement waste, steel slag and many process ashes can also be employed in CO₂ sequestration. Mineral carbonation could be used for the sequestration of billions of tonnes of CO₂ every year. However, various drawbacks related to mineral carbonation still need to be addressed, such as resolving the slow rate of reactions, necessity of large amounts of feedstock, decreasing the high overall cost of CO₂ sequestration and reducing the huge energy requirements to accelerate the carbonation reaction. This study explores a number of carbonation methods, parameters that control the process and future potential applications of carbonated products.