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Tesfaye Fitsum Liu Xiaoyu Zheng Jufeng Cheng Kun Bian Rongjun Zhang Xuhui Li Lianqing Drosos Marios Joseph Stephen Pan Genxing 《Environmental science and pollution research international》2021,28(26):34108-34120
Environmental Science and Pollution Research - As one of the most important nutrients for plant growth, phosphorus was often poorly available in soil. While biochar addition induced improvement of... 相似文献
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Barbara Fontaine Marios Drosos Pierluigi Mazzei 《Environmental science and pollution research international》2014,21(13):8016-8024
We evaluated the catalytic activity of a water-soluble iron-porphyrin in an oxidative coupling reaction to form covalent bonds between 2,4-dichlorophenol (2,4-DCP) and humic molecules. The biomimetic catalysis in the presence of H2O2 was tested in the dark and in daylight, and changes in reaction products were revealed by high-performance liquid chromatography (HPLC) and nuclear magnetic resonance (NMR) spectroscopy. In all conditions, iron-porphyrin was effective in promoting complete disappearance of 2,4-DCP, although catalyst activity was enhanced in daylight (with a maximum turnover number of 85.13). Further evidence of the occurred covalent coupling between 2,4-DCP and humic molecules was revealed by diffusion-ordered nuclear magnetic resonance (DOSY-NMR) spectroscopy that showed a reduced diffusivity of 2,4-DCP after the catalytic reaction. These findings indicate that iron-porphyrin is an efficient catalyst for the covalent binding of polyhalogenated phenols to humic molecules, thereby suggesting that the copolymerization reactions may become a useful technology to remediate soils and waters contaminated by halogenated phenols and their analogues. 相似文献
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通过荧光猝灭滴定法探究玉米秸秆炭(MSB)、水稻秸秆炭(RSB)和花生秸秆炭(PSB)中DOM的光谱特征及其与Cu2+的络合机理.结果表明:三种生物质炭的DOM均具有较高的亲水性和较低的芳香性,其中RSB-DOM的芳香性相对较强、分子量较大,但DOM含量低,PSB-DOM含量最高,芳香结构中含氧官能团较多.MSB和RSB-DOM中均含类富里酸组分C1和类腐殖酸组分C3、C4,RSB-DOM中还有类色氨酸组分C5,PSB-DOM则由两种类富里酸组分C1、C2和较长波长类腐殖酸组分C4组成,3种DOM均以类富里酸组分为主,占比达54.93%~86.29%.Cu2+与类腐殖酸组分的稳定常数(logKM)高于类富里酸组分,且类腐殖酸组分C4的络合能力(f)最强,类腐殖酸组分的logKM和f值总体上表现为:PSB-DOM> MSB-DOM>RSB-DOM.二维相关光谱分析发现,类富里酸组分对Cu2+最敏感,而Cu2+优先与类腐殖酸组分结合.研究结果有助于进一步揭示生物质炭的DOM对Cu2+环境行为的影响机制. 相似文献
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不同原料的生物质炭DOM含量和组分存在差异,选取水稻秸秆(RS)、小麦秸秆(WS)、大豆秸秆(SS)、油菜秸秆(YS)、花生壳(PH)、松木屑(PW)和竹粉(BS)7种生物质原料在450 ℃下制备的生物质炭,采用紫外-可见光光谱(UV-vis)、荧光光谱(EEM)结合平行因子分析(PARAFAC)技术对生物质炭中DOM的光谱特征和荧光组分进行表征.结果表明:木本类生物质炭的DOM含量较秸秆类生物质炭低,分子量较高.从生物质炭DOM中鉴定分离可见区类富里酸组分(C1)、较短波长类腐殖酸组分(C2)、较长波长类腐殖酸组分(C3)和类蛋白质组分(C4)等4种组分.不同原料生物质炭DOM各组分的最大荧光强度(Fmax)值表现为C1 > C2 > C3 、C4,秸秆类炭DOM各组分的Fmax值显著高于木本类.生物质炭DOM中以C1组分占主导地位,占比达48.87% ~ 79.97%.C2、C3组分在YSB、SSB-DOM中占比最高,分别达32.71%和23.25% ,仅在YSB和PHB-DOM中发现少量C4组分.木本类原料的有机和无机矿物含量远低于秸秆类,原料中纤维素含量与生物质炭DOM总量及其C3组分呈显著的正相关关系, Ca含量与生物质炭的DOM含量及其Fmax值和C3组分呈显著正相关,说明不同生物质原料的组成对生物质炭DOM组成特性具有显著的影响,研究结果为全面评估不同原料生物质炭DOM的环境效应提供重要的科学理论依据. 相似文献
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