Study on the denitrification performance of FexLayOz/activated coke for NH3-SCR and the effect of CO escaped from activated coke at mid-high temperature on catalytic activity

Currently, activated coke is widely used in the removal of multiple pollutants from industrial flue gas. In this paper, a series of novel Fe_xLa_yO_z/AC catalysts was prepared by the incipient wetness impregnation for NH₃-SCR denitrification reaction. The introduction of Fe-La bimetal oxides significantly improved the denitrification performance of activated coke at mid-high temperature, and 4% Fe_0.3La_0.7O_1.5/AC exhibited a superior NO_x conversion efficiency of 90.1% at 400 °C. The catalysts were further characterized by BET, SEM, XRD, Raman, EPR, XPS, FTIR, NH₃-TPD, H₂-TPR, et al., whose results showed that the perovskite-type oxide of LaFeO₃ and oxygen vacancies were produced on the catalysts’ surfaces during roasting. Fe-La doping enhanced the amount of acid sites (mainly Lewis and other stronger acid sites) and the content of multifarious oxygen species, which were beneficial for NO_x removal at mid-high temperature. Moreover, it was investigated that the effect of released CO from activated coke at mid-high temperature on the NO_x removal through the lifetime test, in which it was found that a large amount of CO produced by pyrolysis of activated coke could promote the NO_x removal, and long-term escaping of CO on the activated coke carrier did not have a significant negative impact on catalytic performance. The results of the TG-IR test showed that volatile matter is released from the activated coke while TG results showed that the weight loss rate of 4% Fe_0.3La_0.7O_1.5/AC only was 0.0015~0.007%/min at 300–400 °C. Hence, 4% Fe_0.3La_0.7O_1.5/AC had excellent thermal stability and denitrification performance to be continuously used at mid-high temperature. Finally, the mechanisms were proposed on the basis of experiments and characterization results.

     

压缩空气泡沫在长距离管路输送中压降的数值模拟

基于Fluent对压缩空气泡沫在长距离管道中的流动特性进行了数值模拟研究,将压缩空气泡沫近似为弥散流,采用Saplart-Allmaras模型模拟了不同管径下压缩空气泡沫以及不同泡沫原液浓度的AFFF泡沫在长距离管道内的流动及压降变化。模拟结果表明,随着距离变化,各管径管道内压降均呈现线性变化,且随着压缩空气泡沫的流动,压降线性增大。管道管径对管内压降变化具有显著影响,管道直径越小,管道内压降越大;泡沫原液浓度对压降的影响较小,且压缩空气泡沫在长距离输送中的压力随距离线性衰减。将模拟结果与长距离输送的试验结果进行了对比,误差在10%以内。     

运用LCA方法分析污水再生处理的成本效益

运用生命周期评价(LCA)方法,以西安市北石桥污水净化中心的污水处理与再生利用全过程为例进行环境影响评价,通过清单分析、当量计算和权重分析等一系列分析过程,计算出污水处理过程的投入成本及污水再生处理前后对环境的影响,得出污水在经过处理后,能够很大程度上减小其对环境的影响,从而产生环境正效益。该研究明确了污水处理在环境保护中的重要地位,同时对优化污水处理与再生利用工艺过程具有重要的参考价值和指导意义。     

加油站地下储油罐压力管理系统的相关研究

在当前普遍采用的加油站真空辅助式第二阶段油气回收系统中，为了避免回收到地下储油罐中的油气再次通过P/V阀排空，必须对其中气相空间的压力实施有效控制。从国外的发展情况来看，地下储油罐的压力管理系统主要分为基于膜分离技术、基于弹性气囊和基于活性炭吸附三大类，其中膜法油气回收装置在国内已经得到了较多关注。首次系统介绍了气囊式压力管理系统的工作原理及其主要结构设计，具体包括管线布局、钢制压力容器壳体、位于容器顶部封头上的接口组件和全部位于容器内的气囊等；同时对另外一种可行方案进行了分析。     

多元主体参与视角下的地方政府自然灾害应对:经验、问题与对策——以云南省为例

地方政府要做好自然灾害应对工作必须统筹兼顾两个方面的工作:一是在自然灾害应对的法规、组织等层面上切实发挥政府的主导作用;二是充分发挥多元主体参与的作用,集聚社会力量共同参与自然灾害应对。努力形成组织规范、运转协调的政府主导下的多元主体参与的自然灾害应对模式,切实提高地方政府自然灾害应急管理的能力和水平。     

3种内筒溢流型溶气罐结构改进设计方案的溶气性能对比分析

溶气罐是溶气释放式微气泡发生系统的关键设备,其中内筒溢流型溶气罐具有结构简单、成泡粒径小等优点.提出了3种内筒溢流型溶气罐的结构改进设计方案,并对其在不同操作参数下的溶气性能进行了对比分析.为克服通过测量释气量间接表征溶气量所带来的系统误差,建立了在线带压测量溶解氧的方法,并以空气在水中溶解量的变化率(即溶气效率)来直接表征溶气罐的溶气性能.结果表明:溶气效率随气液比和溶气压力的增大而增加,随液位比的升高而减小;在相同气液比、液位比及溶气压力下,气液切向进口加螺旋导叶片型溶气罐的溶气效率最高.采用响应曲面法对溶气性能相对最佳的内筒溢流型溶气罐的操作参数进行优化,预测最高溶气效率为72.43％时的最佳操作参数为:气液比为0.25,液位比为0.36,溶气压力为0.26 MPa.所得回归模型预测值与实测值的相对误差为0.87％,表明该模型可较好地分析和预测溶气罐的溶气性能.     

Are servant leaders appreciated? An investigation of how relational attributions influence employee feelings of gratitude and prosocial behaviors

Multisource data collected at three time phases were used in investigating when servant leadership elicits gratitude and then promotes prosocial behaviors. We tested a moderated mediation model, contending that relational attributions moderate the relationship between servant leadership and gratitude, and then gratitude sequentially predicts interpersonal citizenship behaviors and upward voice. As hypothesized, when employees do not highly rely on relational attributions for servant leadership, they feel more gratitude and subsequently engage in more interpersonal citizenship behaviors and upward voice than the employees who rely on relational attributions to explain their interactions with the leader. The sequential indirect effect from servant leadership to upward voice via gratitude and then interpersonal citizenship behaviors was significant when relational attributions are low rather than high.     

用MnSO4-Ce(SO4)2协同催化快速测定COD的研究

本文探讨了以MnSO4-Ce(SO4)2复合催化剂代替标准重铬酸钾法中的Ag2SO4，用密封消解法测定废水COD值的可行性，研究了复合催化剂总量、配比、消解时间、溶液酸度等因素对COD测定的影响。通过对各种废水COD值的测定表明，用MnSO4-Ce(SO4)2做催化剂，在165℃，较低酸度，密封消解15min是可行的。     

实施污水总量控制的经验和做法

为实现２０００年达标排放和总量控制目标,胜利油田的经验和做法是：制定了污水排放总量控制计划、总量控制监测及监督考核办法;认真搞好工业污水治理和综合利用,重点抓好采油污水的回注,使回注率大于９０％,并对各行业污水治理制定了措施     

乡村绿色住区示范区污水就地处置回用--黄土高原干旱半干旱乡村绿色住区水资源开发利用研究

探讨了乡村绿色住区污水就地处置技术的可行性,结合西北黄土高原乡村绿色住区示范区建设,设计了黄土高原干旱半干旱乡村聚居区污水就地处置回用的工艺型式.