Environmental Science and Pollution Research - Trace copper ion (Cu(II)) in water and wastewater can trigger peroxymonosulfate (PMS) activation to oxidize organic compounds, but it only works under... 相似文献
Over the past decades, the plastic production has been dramatically increased. Indeed, a category of small plastic particles mainly with the shapes of fragments, fibers, or spheres, called microplastics (particles smaller than 5 mm) and nanoplastics (particles smaller than 1 μm) have attracted particular attention. Because of its wide distribution in the environment and potential adverse effects to animal and human, microplastic pollution has been reported as a serious environment problem receiving increased attention in recent years. As one of the commonly detected emerging contaminants in the environment, recent evidence indicates that the concentration of microplastics show an increasing trend, for the reason that up to 12.7 million metric tons of plastic litter is released into aquatic environment from land-based sources each year. Furthermore, microplastic exposure levels of model organisms in laboratory studies are usually several orders of magnitude higher than those found in environment, and the microplastics exposure conditions are also different with those observed in the environment. Additionally, the detection of microplastics in feces indicates that they can be excreted out of the bodies of animal and human. Hence, great uncertainties might exist in microplastics exposure and health risk assessment based on current studies, which might be exaggerated. Policies reduce microplastic emission sources and hence minimize their environmental risks are determined. To promote the above policies, we must first overcome the technical obstacles of detecting microplastics in various samples. 相似文献
Plastic pollution is a major environmental issue worldwide, calling for advanced methods to recycle waste plastics in the context of the circular economy. Here we review methods and strategies to convert waste plastics into value-added carbon materials, with focus on sources, properties, pretreatment of waste plastics, and on preparation of carbon materials. Pretreatment techniques include mechanical crushing, plastic stabilization and electrospinning. Carbon materials such as carbon nanotubes, graphene, carbon nanosheets, carbon spheres and porous carbon are prepared by oxygen-limited carbonization, catalytic carbonization, the template-based method, and pressure carbonization. We emphasize the conversion of polyethene terephthalate, polyethylene, polypropylene, polystyrene, halogenated plastics, polyurethane and mixed plastics.
The rapid development and increase of antibiotic resistance are global phenomena resulting from the extensive use of antibiotics in human clinics and animal feeding operations. Antibiotics can promote the occurrence of antibiotic resistance genes (ARGs), which can be transferred horizontally to humans and animals through water and the food chain. In this study, the presence and abundance of ARGs in livestock waste was monitored by quantitative PCR. A diverse set of bacteria and tetracycline resistance genes encoding ribosomal protection proteins (RPPs) from three livestock farms and a river were analyzed through denaturing gradient gel electrophoresis (DGGE). The abundance of sul(I) was 103 to 105 orders of magnitude higher than that of sul(II). Among 11 tet-ARGs, the most abundant was tet(O). The results regarding bacterial diversity indicated that the presence of antibiotics might have an evident impact on bacterial diversity at every site, particularly at the investigated swine producer. The effect of livestock waste on the bacterial diversity of soil was stronger than that of water. Furthermore, a sequencing analysis showed that tet(M) exhibited two genotypes, while the other RPPs-encoding genes exhibited at least three genotypes. This study showed that various ARGs and RPPs-encoding genes are particularly widespread among livestock. 相似文献
Effective water quality management depends on enactment of appropriately designed monitoring programs to reveal current and forecasted conditions. Because water quality conditions are influenced by numerous factors, commonly measured attributes such as total phosphorus (TP) can be highly temporally varying. For highly varying processes, monitoring programs should be long-term and periodic quantitative analyses are needed so that temporal trends can be distinguished from stochastic variation, which can yield insights into potential modifications to the program. Using generalized additive mixed modeling, we assessed temporal (yearly and monthly) trends and quantified other sources of variation (daily and subsampling) in TP concentrations from a multidecadal depth-specific monitoring program on Big Platte Lake, Michigan. Yearly TP concentrations decreased from the late 1980s to late 1990s before rebounding through the early 2000s. At depths of 2.29 to 13.72 m, TP concentrations have cycled around stationary points since the early 2000s, while at the surface and depths ≥?18.29 concentrations have continued declining. Summer and fall peaks in TP concentrations were observed at most depths, with the fall peak at deeper depths occurring 1 month earlier than shallower depths. Daily sampling variation (i.e., variation within a given month and year) was greatest at shallowest and deepest depths. Variation in subsamples collected from depth-specific water samples constituted a small fraction of total variation. Based on model results, cost-saving measures to consider for the monitoring program include reducing subsampling of depth-specific concentrations and reducing the number of sampling depths given observed consistencies across the program period. 相似文献
Empirical studies investigating the natural resource curse theory mostly employ cross-country and panel regression techniques subject to endogeneity bias. Also, most of these studies employ GDP in its aggregate or per-capita terms as the outcome variable in their analyses. However, the use of GDP measures of income for resource curse investigations may not portray the true incomes of resource-intensive economies. Standard national accounts treat natural resource rents as a positive contribution to income without adjusting for the value of depleted natural resource stock. This treatment often leads to a positive bias in the national income computations of resource-rich economies. Unlike previous studies, we test the robustness of the curse in the predominantly used measures of national income, GDP, by investigating the theme in genuine income measures of economic output as well. Also, the paper deviates from most empirical studies in the literature by using the Arellano–Bond difference GMM method in investigating the oil curse in OECD and Non-OECD oil-exporting economies. Additionally, we employ two alternative measures of resource intensity in our explorations; the share of oil rents in GDP and per-capita oil reserves. Our results provide evidence of the curse in Non-OECD countries employing aggregate and per-capita measures of genuine income. 相似文献
Channa argus, a type of snakehead fish native to China, is a popular food fish in certain Asian countries but is a known destructive invasive species in the US. In this study, the two collagens, i.e. acid-soluble collagen (ASC) and pepsin-solubilized collagen (PSC), were obtained from C. argus skin. The yield of ASC was 28.0% and that of PSC was 16.8% on the dry bases. The collagens were identified as the collagen of type I by SDS–PAGE patterns. The Tds were approximately 27.0?°C. Similar ultraviolet spectra of both collagens were observed. Fourier Transform infrared spectra indicated PSC structure had a little change due to the loss of terminal domains by pepsin digestion. The results of XRD proved that the two collagens retained their helical structures. The results suggest that the collagens isolated from C. argus can potentially be alternative sources of vertebrate collagens for use in the food and other industries. 相似文献
• Highly efficient debromination of BDE-47 was achieved in the ZVZ/AA system.• BDE-47 debromination by the ZVZ/AA can be applied to a wide range of pH.• AA inhibits the formation of (hydr)oxide and accelerates the corrosion of ZVZ.• Reduction mechanism of BDE-47 debromination by the ZVZ/AA system was proposed. A new technique of zero-valent zinc coupled with ascorbic acid (ZVZ/AA) was developed and applied to debrominate the 2,2′,4,4′-Tetrabromodiphenyl ether (BDE-47), which achieved high conversion and rapid debromination of BDE-47 to less- or non-toxic forms. The reaction conditions were optimized by the addition of 100 mg/L ZVZ particles and 3 mmol/L AA at original solution pH= 4.00 using the solvent of methanol/H2O (v:v= 4:6), which could convert approximately 94% of 5 mg/L BDE-47 into lower-brominated diphenyl ethers within a 90 min at the ZVZ/AA system. The high debromination of BDE-47 was mainly attributed to the effect of AA that inhibits the formation of Zn(II)(hydr)oxide passivation layers and promotes the corrosion of ZVZ, which leads to increase the reactivity of ZVZ. Additionally, ion chromatography and gas chromatography mass spectrometry analyses revealed that bromine ion and lower-debromination diphenyl ethers formed during the reduction of BDE-47. Furthermore, based on the generation of the intermediates products, and its concentration changes over time, it was proposed that the dominant pathway for conversion of BDE-47 was sequential debromination and the final products were diphenyl ethers. These results suggested that the ZVZ/AA system has the potential for highly efficient debromination of BDE-47 from wastewater. 相似文献