Collaborative study to improve the quality control of rare earth element determinations in environmental matrices

In order to control the quality of rare earth determinations in environmental matrices, the Standards, Measurements and Testing Programme (formerly Community Bureau of Reference, BCR) of the European Commission has started a project, the final aim of which is to certify four types of matrices (tuna muscle, mussel tissue, aquatic plant and estuarine sediment) for their contents of a range of rare earth elements (Sc, Y and the lanthanides: La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb and Lu). The elements U and Th were added to the study. The first part of this project consisted of an interlaboratory study which aimed to test the feasibility of preparation of environmental reference materials and to detect and remove most of the pitfalls observed in rare earth determinations. This paper presents the preparation of the four matrices for the intercomparison study and for the candidate reference material. The main results are presented of the interlaboratory study that was carried out prior to the certification campaign. This collaborative trial is the first attempt ever carried out at this scale to evaluate the state-of-the-art of rare earth determinations in the environment. Its impact on the improvement of chemical measurements will have positive effects on the comparability of data necessary for environmental monitoring.     

Oxides of nitrogen in the greater Manchester conurbation,UK

Summary This paper reviews the emission sources of oxides of nitrogen and provides an estimate of the contribution from the Greater Manchester conurbation. The uncertainty attached to the estimate is large. Atmospheric and rainwater concentrations of oxides of nitrogen are reported from the Greater Manchester Acid Deposition Survey network. The health and ecological implications of these concentrations are commented upon and the measured values compared to a number of environmental guidelines, including recently formulated critical load and critical level estimates. Control technologies applicable to both mobile and large combustion sources are briefly reviewed.Dr James Longhurst is Director of the Acid Rain Information Centre which is based at Manchester Polytechnic.