KALMAN FILTER CALCULATION OF SAMPLING FREQUENCY WHEN DETERMINING ANNUAL MEAN SOLUTE CONCENTRATIONS

ABSTRACT: A linear filter (Kalman filter) technique was used with a Streamflow-concentration model the minimize surface water quality sampling frequencies when determining annual mean solute concentrations with a predetermined allowable error. The Kalman filter technique used the stream discharge interval as a replacement for the more commonly used time interval. Using filter computations, the measurement error variance was minimized within the sample size constraints. The Kalman filter application proposed here is applicable only under several conditions including: monitoring is solely to estimate annual mean concentration; discharge measurement errors are negligible; the Streamflow-concentration model is valid; and monthly samples reflect the total variance of the solute in question.     

VARIABILITY IN MEASURES OF MACROINVERTEBRATE COMMUNITY STRUCTURE BY STREAM REACH AND STREAM CLASS1

ABSTRACT: Macroinvertebrate community data collected from streams in Wyoming were assessed at various scales: within one stream reach, between stream reaches within one stream, between streams, and between stream classes. Fourteen indices including number of individuals/m², biomass/m², number of taxa, Shannon's diversity index, and functional feeding group ratios were used to compare macroinvertebrates by stream reach and stream class. Statistical analysis indicated that for five of the 14 indices, significant variability occurred between macroinvertebrate communities within one reach. For two of the remaining nine indices there was significant variability between communities from several reaches within the same stream. For seven of the nine indices, there was significant variability among macroinvertebrate communities from streams of the same class. Variability among the macroinvertebrate communities from the three stream classes was significantly different for seven of the nine indices. ANOVA results suggest that macroinvertebrate communities from different samples within one reach and between reaches within one stream were more comparable than those from different streams and different stream classes.     

Hydrochemical Changes Over Time in the Zahedan Aquifer, Iran

Groundwater in the Zahedan Aquifer located in the arid southeast of Iran was chemically characterized to understand both the nature of the alluvium aquifer and the effect of human activities, specifically sewage disposal on groundwater quality. Concentrations of major cations and anions in the Zahedan Aquifer are much higher than concentrations observed in groundwater of similar settings. Although the nature of the aquifer and climatic parameters have affected the chemistry of groundwater, human impacts on the groundwater quality are more significant. The electrical conductivity in some areas of the Zahedan aquifer increased up to 7,500μS/cm in 25 years. Human influences in some areas are so prevalent, that the groundwater type changed from a Na⁺-HCO₃ ^- in 1976 to a Na⁺-Cl^- type in 2000. The impact of human influences on the groundwater quality is also indicated through observed nitrate concentration up to 4.81 meq/L in the urban area.     

Risk assessment for salmon from water quality changes following timber harvesting

Land use activities may affect surface water quantity and quality. Water quality changes (concentration increases) from land use activities that are above background but below the water quality standard or criteria have always been considered benign. Increased public interest and recent legislation and management regarding threatened, or endangered, salmon populations suggest that environmental influences on these populations need to be reevaluated.As one approach, we developed a risk assessment (toxicity and exposure) for salmon from water quality changes following timber harvesting. Toxicity relationships for nitrate-nitrogen (as an LC₅₀) using chloride, suspended sediment, and exposure were developed from the literature and data from the Alsea Watershed Study in the Oregon Coast Range. These relationships were used to predict the probable risk to coho salmon (Oncorhynchus kisutch) to nitrate-nitrogen exposure.The control or reference catchment, Flynn Creek, had higher nitrate-nitrogen concentrations, but showed little likelihood of risk to salmon because of lower suspended sediment concentrations. The treated catchment, Needle Branch (harvested 27 years ago), had lower nitrate-nitrogen concentrations and was expected to have less risk to salmon. However, the risk assessment relationship exhibited sensitivity to suspended sediment concentrations. This smaller catchment had higher suspended sediment transport and thus a higher risk of nitrate-nitrogen exposure to salmon. The suspended sediment transport functions were based on post-treatment monitoring (1966–1973) and are not considered to represent the current situation. These findings are not meant to be categorical, but merely illustrative of this risk assessment application.