Simultaneous removal of metronidazole and Pb(II) from aqueous solution onto bifunctional activated carbons

Environmental Science and Pollution Research - In this work, it was analyzed the behavior of three commercial activated carbons with different textural and chemical properties to adsorb...     

2,4-Dichlorophenoxyacetic acid (2,4-D) photodegradation on WO3-TiO2-SBA-15 nanostructured composite

Environmental Science and Pollution Research - A current environmental problem is the uncontrolled use of various pesticides that are harmful to the environment and public health. The herbicide...     

A climate-change vulnerability and adaptation assessment for Brazil's protected areas

Brazil hosts the largest expanse of tropical ecosystems within protected areas (PAs), which shelter biodiversity and support traditional human populations. We assessed the vulnerability to climate change of 993 terrestrial and coastal-marine Brazilian PAs by combining indicators of climatic-change hazard with indicators of PA resilience (size, native vegetation cover, and probability of climate-driven vegetation transition). This combination of indicators allows the identification of broad climate-change adaptation pathways. Seventeen PAs (20,611 km²) were highly vulnerable and located mainly in the Atlantic Forest (7 PAs), Cerrado (6), and the Amazon (4). Two hundred fifty-eight PAs (756,569 km²), located primarily in Amazonia, had a medium vulnerability. In the Amazon and western Cerrado, the projected severe climatic change and probability of climate-driven vegetation transition drove vulnerability up, despite the generally good conservation status of PAs. Over 80% of PAs of high or moderate vulnerability are managed by indigenous populations. Hence, besides the potential risks to biodiversity, the traditional knowledge and livelihoods of the people inhabiting these PAs may be threatened. In at least 870 PAs, primarily in the Atlantic Forest and Amazon, adaptation could happen with little or no intervention due to low climate-change hazard, high resilience status, or both. At least 20 PAs in the Atlantic Forest, Cerrado, and Amazonia should be targeted for stronger interventions (e.g., improvement of ecological connectivity), given their low resilience status. Despite being a first attempt to link vulnerability and adaptation in Brazilian PAs, we suggest that some of the PAs identified as highly or moderately vulnerable should be prioritized for testing potential adaptation strategies in the near future.     

Interinstrument comparison of remote-sensing devices and a new method for calculating on-road nitrogen oxides emissions and validation of vehicle-specific power

Emissions of nitrogen oxides (NOx) by vehicles in real driving environments are only partially understood. This has been brought to the attention of the world with recent revelations of the cheating of the type of approval tests exposed in the dieselgate scandal. Remote-sensing devices offer investigators an opportunity to directly measure in situ real driving emissions of tens of thousands of vehicles. Remote-sensing NO₂ measurements are not as widely available as would be desirable. The aim of this study is to improve the ability of investigators to estimate the NO₂ emissions and to improve the confidence of the total NOx results calculated from standard remote-sensing device (RSD) measurements. The accuracy of the RSD speed and acceleration module was also validated using state-of-the-art onboard global positioning system (GPS) tracking. Two RSDs used in roadside vehicle emissions surveys were tested side by side under off-carriageway conditions away from transient pollution sources to ascertain the consistency of their measurements. The speed correlation was consistent across the range of measurements at 95% confidence and the acceleration correlation was consistent at 95% confidence intervals for all but the most extreme acceleration cases. VSP was consistent at 95% confidence across all measurements except for those at VSP ≥ 15 kW t^?1, which show a small underestimate. The controlled distribution gas nitric oxide measurements follow a normal distribution with 2σ equal to 18.9% of the mean, compared to 15% observed during factory calibration indicative of additional error introduced into the system. Systematic errors of +84 ppm were observed but within the tolerance of the control gas. Interinstrument correlation was performed, with the relationship between the FEAT and the RSD4600 being linear with a gradient of 0.93 and an R² of 0.85, indicating good correlation. A new method to calculate NOx emissions using fractional NO₂ combined with NO measurements made by the RSD4600 was constructed, validated, and shown to be more accurate than previous methods.

Implications: Synchronized remote-sensing measurements of NO were taken using two different remote-sensing devices in an off-road study. It was found that the measurements taken by both instruments were well correlated. Fractional NO₂ measurements from a prior study, measurable on only one device, were used to create new NO_x emission factors for the device that could not be measured by the second device. These estimates were validated against direct measurement of total NO_x emission factors and shown to be an improvement on previous methodologies. Validation of vehicle-specific power was performed with good correlation observed.     

Larvicidal and pupicidal activities of eco-friendly phenolic lipid products from Anacardium occidentale nutshell against arbovirus vectors

Environmental Science and Pollution Research - Aedes aegypti and Culex quinquefasciatus are vectors of diseases that constitute public health problems. The discovery of products capable of...     

An integrated approach for assessing the migration behavior of chlorpyrifos and carbaryl in the unsaturated soil zone

Chlorpyrifos (O, O-diethyl O-3,5,6-trichloropyridin-2-yl phosphorothioate) and carbaryl (1-naphthyl methylcarbamate) are often applied concurrently as insecticides in food production. The aim of this study was to research their migration behavior in a real environment. We researched the leaching of both pesticides by setting up field lysimeters on a farm with the typical soil used in fruit production today. In order to analyze the variables involved in this process, we performed complementary adsorption studies, we performed complementary adsorption studies using batches and undisturbed soil laboratory columns for both compounds. The results for pesticide transport through the lysimeters showed that less than 1% of chlorpyrifos was recovered in the leachates, while almost 17% was recovered for carbaryl. Having completed the experiment in undisturbed laboratory columns, soil analysis showed that chlorpyrifos mainly remained in the first 5 cm, while carbaryl moved down to the lower sections. These results can be explained in view of the sorption coefficient values (K_D) obtained in horizons A and B for chlorpyrifos (393 and 184 L kg^?1) and carbaryl (3.1 and 4.2 L kg^?1), respectively. By integrating the results obtained in the different approaches, we were able to characterize the percolation modes of these pesticides in the soil matrix, thus contributing to the sustainable use of resources.     

Review: recent advances in biogas purifying technologies

Biomethane production through biogas upgrading is a promising renewable energy for some industries which could be part of the equilibrium needed with fossil fuels consumption to achieve a sustainable society. This paper presents a comprehensive list of biogas upgrading technologies focused on carbon dioxide removal as well as recent advances reported by researcher with wide expertise in this topic. Additionally, an extensive costs–performance comparison among the technologies studied is discussed. Among the different alternatives, chemical scrubbing stood out to achieve high biomethane purities while cryogenic technologies proved to be effective against methane losses. Regarding the different costs, water scrubbing and membrane separation seem to be the most affordable techniques.     

Ovariectomy predisposes female rats to fine particulate matter exposure’s effects by altering metabolic,oxidative, pro-inflammatory,and heat-shock protein levels

Environmental Science and Pollution Research - The reduction of estrogen levels, as a result of menopause, is associated with the development of metabolic diseases caused by alterations in...     

The personal,social and environmental sustainability of Jainism in light of Maharishi Vedic Science

The Jain tradition of ecological awareness and sustainability has been well documented over the last 25 years, although its roots lie deep in Indian history, specifically in texts such as the Tattvārtha Sūtra and ācārā?ga Sūtra. This traditional body of knowledge includes a long-standing theory and practice of personal, social and environmental sustainability, addressing such views as the interconnectedness of humans and the laws of nature, the interdependence of everything in the universe, the responsibility of humans to conserve and preserve natural resources, the avoidance of wanton and unnecessary waste generation, and a general aversion to mistreating or abusing the environment. These views encapsulate the lifestyles of some ten million people, including both mendicants and laity. Similarly, Maharishi Vedic Science, the systematic exploration and practical application of the Veda and Vedic Literature as taught by Maharishi Mahesh Yogi, makes a compelling case for establishing the unity of human life with nature and for promoting actions which guarantee both the protection of nature and protection by it. The purpose of this paper is to examine the relationship between the principles of sustainability in Jainism and the corresponding viewpoint of Maharishi Vedic Science, including supporting scientific evidence of its application, and to posit their contribution to a sustainable world future.