Gas permeability and tortuosity for packed layers of processed municipal solid wastes and incinerator residue.

To make a proper evaluation of gas component movement inside a landfill site, it is important to investigate the different parameters related to gas flow. In this work gas-filled porosity, intrinsic permeability, tortuosity and equivalent pore radius were determined for various packed wastes, such as incineration ash, shredded bulky waste and shredded incombustible waste. These parameters were measured/inferred for samples packed in a column and exposed to a controlled gas flow. The effect of waste conditions, especially the moisture content, on these parameters was also investigated. The intrinsic permeability of such packed wastes was generally in the order of 10(-10) to 10(-9) m2, except for some ash that was one to two orders lower. The tortuosity of waste layer was greater than that of a particulate material and ranged between 2 and 10. The equivalent pore radius was generally in the order of 10(-4) m, which means that gas diffusion is still ordinary in such packed waste layer. The obtained results will be utilized when simulating gas flow inside a landfill site for biogas extraction or site aeration.     

Projections of industrial water withdrawal under shared socioeconomic pathways and climate mitigation scenarios

We estimated global future industrial water withdrawal (IWW) by considering socioeconomic driving forces, climate mitigation, and technological improvements, and by using the output of the Asia–Pacific Integrated Model/Computable General Equilibrium (AIM/CGE) model. We carried out this estimation in three steps. First, we developed a sector- and region-specific regression model for IWW. The model utilized and analyzed cross-country panel data using historical statistics of IWW for 10 sectors and 42 countries. Second, we estimated historical IWW by applying a regression model. Third, we projected future IWW from the output of AIM/CGE. For future projections, we considered and included multiple socioeconomic assumptions, namely different shared socioeconomic pathways (SSPs) with and without climate mitigation policy. In all of the baseline scenarios, IWW was projected to increase throughout the twenty-first century, but growth through the latter half of the century is likely to be modest mainly due to the effects of decreased water use intensity. The projections for global total IWW ranged from 461 to 1,560 km³/year in 2050 and from 196 to 1,463 km³/year in 2100. The effects of climate mitigation on IWW were both negative and positive, depending on the SSPs. We attributed differences among scenarios to the balance between the choices of carbon capture and storage (CCS) and renewable energy. A smaller share of CCS was accompanied by a larger share of non-thermal renewable energy, which requires a smaller amount of water withdrawal per unit of energy production. Renewable energy is, therefore, less water intensive than thermal power with CCS with regard to decarbonizing the power system.     

Compartment model of aerobic and anaerobic biodegradation in a municipal solid waste landfill

The mathematical formulations in a one-dimensional compartment model of the biodegradation of organic landfill components are described. The model is designed to switch between anaerobic and aerobic conditions, depending on the local oxygen concentration. The model also includes the effect of environmental factors, such as moisture content, pH, and temperature, on reaction rates. The model includes not only biodegradation processes for carbon compounds (acetate, CO2, CH4), but also for nitrogen compounds involved in nitrification and denitrification due to their significance in landfills. Two example runs to simulate anaerobic and aerobic waste were conducted for a single landfill unit cell by changing the organic content and diffusion coefficient.     

Recovery of solid fuel from municipal solid waste by hydrothermal treatment using subcritical water

Hydrothermal treatments using subcritical water (HTSW) such as that at 234 °C and 3 MPa (LT condition) and 295 °C and 8 MPa (HT condition) were investigated to recover solid fuel from municipal solid waste (MSW). Printing paper, dog food (DF), wooden chopsticks, and mixed plastic film and sheets of polyethylene, polypropylene, and polystyrene were prepared as model MSW components, in which polyvinylchloride (PVC) powder and sodium chloride were used to simulate Cl sources.While more than 75% of carbon in paper, DF, and wood was recovered as char under both LT and HT conditions, plastics did not degrade under either LT or HT conditions. The heating value (HV) of obtained char was 13,886-27,544 kJ/kg and was comparable to that of brown coal and lignite. Higher formation of fixed carbon and greater oxygen dissociation during HTSW were thought to improve the HV of char.Cl atoms added as PVC powder and sodium chloride to raw material remained in char after HTSW. However, most Cl originating from PVC was found to converse into soluble Cl compounds during HTSW under the HT condition and could be removed by washing.From these results, the merit of HTSW as a method of recovering solid fuel from MSW is considered to produce char with minimal carbon loss without a drying process prior to HTSW. In addition, Cl originating from PVC decomposes into soluble Cl compound under the HT condition. The combination of HTSW under the HT condition and char washing might improve the quality of char as alternative fuel.     

Global-scale quantitative assessment for biodiversity on forest land use: applying the Global No Net Loss approach

Here we propose a method to quantitatively assess and examine Global No Net Loss (GNNL) of forest biodiversity on a global scale. The method produces a GNNL index of existing forest and enables future predictions of forest loss under different assumptions. The method tests the feasibility of the GNNL index and enables discussion of policy for future global scale sustainable forest management up to 2050. The GNNL index was estimated from an equation including forest areas per country per forest type (primary forest, secondary forest and plantation forest), diversity of forest ecosystem, and species density. Estimates derived from historical data revealed an approximate 7% reduction in GNNL index between 1990 and 2005. Predictions of the GNNL index until 2050 emphasize the importance of regenerating large portions of forests felled for agricultural land (or other uses) with secondary forests.     

Experimental study of behavior of endocrine-disrupting chemicals in leachate treatment process and evaluation of removal efficiency

An experimental study of the behavior of endocrine-disrupting chemicals (EDCs) in leachate treatment processes (aeration, coagulation and sedimentation, activated carbon adsorption, and advanced oxidation) was conducted and removal efficiencies were evaluated. Among target EDCs, concentrations of BPA (1800 times), DBP (10 times), BBP (40 times), and DEHP (30 times) in leachate are more than ten times higher than those in surface water. BPA, DBP, and BBP can be treated by aeration and DEHP, by advanced oxidation processes. BPA could not be effectively removed by coagulation and sedimentation because most of BPA partitioned in the supernatant. DEHP could hardly be treated by aeration. The removal ratios of DEHP were approximately 50–70% if the generated sediment was removed completely. The removal ratios of DEHP in leachate of 100 m³/d with 100 kg of activated carbon were 50–70%, assuming a complete mixing model. The concentration of DEHP was decreased to below one-tenth in 120 min by advanced oxidation processes.     

Temporal pessimism and spatial optimism in environmental assessments: An 18-nation study

The personal assessments of the current and expected future state of the environment by 3232 community respondents in 18 nations were investigated at the local, national, and global spatial levels. These assessments were compared to a ranking of each country's environmental quality by an expert panel. Temporal pessimism (“things will get worse”) was found in the assessments at all three spatial levels. Spatial optimism bias (“things are better here than there”) was found in the assessments of current environmental conditions in 15 of 18 countries, but not in the assessments of the future. All countries except one exhibited temporal pessimism, but significant differences between them were common. Evaluations of current environmental conditions also differed by country. Citizens' assessments of current conditions, and the degree of comparative optimism, were strongly correlated with the expert panel's assessments of national environmental quality. Aside from the value of understanding global trends in environmental assessments, the results have important implications for environmental policy and risk management strategies.     

Extraction of heavy metal ions from waste colored glass through phase separation

A new method utilizing phase separation phenomena for the extraction of heavy metal ions used as colorants in colored glass is proposed. Colored soda-lime-silica glass containing Co or Cr as a colorant was remelted with B2O3 to yield soda-lime-borosilicate glass. The soda-lime-borosilicate glass thus obtained was leached in 1M nitric acid at 90 degrees C to dissolve the borate phase. All cations (Na, Ca, Cr and Co) concentrated in the borate phase are successfully leached out with the dissolution of the borate phase, when the amount of the B2O3 added to the glass and heat treatment conditions are properly chosen. Porous silicate glass powders with high SiO2 purity are obtained as the result of the leaching. Porous glass can also be formed as bulk material by controlling the composition of additives during the remelting.     

Foliage profiles of individual trees determine competition,self-thinning,biomass and NPP of a Cryptomeria japonica forest stand: A simulation study based on a stand-scale process-based forest model

A simulation study was carried out to investigate simultaneously the effects of eco-physiological parameters on competitive asymmetry, self-thinning, stand biomass and NPP in a temperate forest using an atmosphere–vegetation dynamics interactive model (MINoSGI). In this study, we selected three eco-physiological relevant parameters as foliage profiles (i.e. vertical distribution of leaf area density) of individual trees (distribution pattern is described by the parameter η), biomass allocation pattern in individual tree growth (χ) and the maximum carboxylation velocity (V_max). The position of the maximal leaf area density shifts upward in the canopy with increasing η. For scenarios with η < 4 (foliage concentrated in the lowest canopy layer) or η > 12 (foliage concentrated in the uppermost canopy layer), a low degree of competitive asymmetry was produced. These scenarios resulted in the survival of subordinate trees due to a brighter lower canopy environment when η < 4 or the generation of spatially separated foliage profiles between dominant and subordinate trees when η > 12. In contrast, competition between trees was most asymmetric when 4 ≤ η ≤ 12 (vertically widespread foliage profile in the canopy), especially when η = 8. In such cases, vertically widespread foliage of dominant trees lowered the opportunity of light acquisition for subordinate trees and reduced their carbon gain. The resulting reduction in carbon gain of subordinate trees yielded a higher degree of competitive asymmetry and ultimately higher mortality of subordinate trees. It was also shown that 4 ≤ η ≤ 12 generated higher self-thinning speed, smaller accumulated NPP, litter-fall and potential stand biomass as compared with the scenarios with η < 4 or η > 12. In contrast, our simulation revealed small effects of χ or V_max on the above-mentioned variables as compared with those of η. In particular, it is notable that greater V_max would not produce greater potential stand biomass and accumulated NPP although it has been thought that physiological parameters relevant to photosynthesis such as V_max influence dynamic changes in forest stand biomass and NPP (e.g. the greater the V_max, the greater the NPP). Overall, it is suggested that foliage profiles rather than biomass allocation or maximum carboxylation velocity greatly govern forest dynamics, stand biomass, NPP and litter-fall.     

Decomposition of organochlorine compounds in flue gas from municipal solid waste incinerators using natural and activated acid clays

High-temperature particle control (HTPC) using a ceramic filter is a dust collection method without inefficient cooling and reheating of flue gas treatment; thus, its use is expected to improve the energy recovery efficiency of municipal solid waste incinerators (MSWIs). However, there are concerns regarding de novo synthesis and a decrease in the adsorptive removal efficiency of dioxins (DXNs) at approximately 300°C. In this study, the effect of natural and activated acid clays on the decomposition of monochlorobenzene (MCB), one of the organochlorine compounds in MSW flue gas, was investigated. From the results of MCB removal tests at 30–300°C, the clays were classified as adsorption, decomposition, and low removal types. More than half of the clays (four kinds of natural acid clays and two kinds of activated acid clays) were of the decomposition type. In addition, the presence of Cl atoms detached from MCB was confirmed by washing the clay used in the MCB removal test at 300°C. Activated acid clay was expected to have high dechlorination performance because of its proton-rich-composition, but only two clays were classed as decomposition type. Conversely, all the natural acid clays used in this work were of the decomposition type, which contained relatively higher di- and trivalent metal oxides such as Al₂O₃, Fe₂O₃, MgO, and CaO. These metal oxides might contribute to the catalytic dechlorination of MCB at 300°C. Therefore, natural and activated acid clays can be used as alternatives for activated carbon at 300°C to remove organochloride compounds such as DXNs. Their utilization is expected to mitigate the latent risks related to the adoption of HTPC, and also to contribute to the improvement of energy recovery efficiency of MSWI.

ImplicationsThe effect of natural and activated acid clays on MCB decomposition was investigated to evaluate their suitability as materials for the removal of organochlorine compounds, such as DXNs, from MSWI flue gas at approximately 300°C. More than half of the clays used in this study showed the decomposition characteristics of MCB. The presence of Cl atoms in the clay used in the MCB removal test at 300°C proved the occurrence of MCB decomposition. The results of this study suggest a novel flue gas treatment method to establish high-energy efficient MSWI systems.