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1.
电化学氧化法具有稳定高效、操作灵活、集成度高等特点,在处理难降解有机废水领域具有独特优势.电化学废水处理过程通常受限于传质速率,而膜电极有望解决这一瓶颈问题.亚氧化钛膜电极(TiSO-ME)的化学结构与电化学性质结果显示,经过高温还原法制备的TiSO-ME电极主要由Ti4O7和少量Ti5O9组成,大孔体积占总孔体积的92.7%,平均孔径为0.508 μm.电化学测试结果表明,TiSO-ME具有良好的导电性、高析氧电位和电化学稳定性.过滤试验结果表明,在0.82×10-3~3.14×10-3 mL·cm-2·s-1范围内膜通量与传质系数成正比.在电流密度为8 mA·cm-2,膜通量为2.31×10-3 mL·cm-2·s-1的条件下,电解1.5 h即可有效处理实际印染工业废水,sCOD去除率高达96.07%,电流效率可达24.22%,电能消耗较不存在膜通量时降低了32.99%.TiSO-ME能够实现废水在膜孔结构内部的穿流式操作,有效克服旁流式操作传质受限的问题,在小规模分散式工业废水处理中有着重要的研究价值和发展潜力. 相似文献
2.
自动电位滴定法测定水中氯离子 总被引:1,自引:0,他引:1
颜志明 《环境监测管理与技术》1997,9(2):29-31
以银电极为响应电极,用硝酸银溶液滴定水中氯离子,等当点时,产生电位突跃,以此确定终点电位,在仪器上锁定的此终点电位值,从而完成样品的自动分析。 相似文献
3.
建立了过氧化聚吡咯(OPPy)和聚乙烯吡咯烷酮(PVP)修饰碳糊电极测定废水中苯酚的方法.优化了试验条件,苯酚的氧化峰电流在1.0×10-5 mol/L~1.0×10-3 mol/L之间线性关系良好,检出限为1.0×10-6 mol/L.该电极制作简单,选择性好,测定灵敏度高,精密度与准确度均符合要求. 相似文献
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5.
《环境科学学报(英文版)》2023,35(3):553-567
Based on the online and membrane sampling data of Yuncheng from January 1st to February 12th, 2020, the formation mechanism of haze under the dual influence of Spring Festival and COVID-19 (Corona Virus Disease) was analyzed. Atmospheric capacity, chemical composition, secondary transformation, source apportionment, backward trajectory, pollution space and enterprise distribution were studied. Low wind speed, high humidity and small atmospheric capacity inhibited the diffusion of air pollutants. Four severe pollution processes occurred during the period, and the pollution degree was the highest around the Spring Festival. In light, medium and heavy pollution periods, the proportion of SNA (SO42−, NO3− and NH4+) was 59.6%, 56.0% and 54.9%, respectively, which was the largest components of PM2.5; the [NO3−]/[SO42−] ratio was 2.1, 1.5 and 1.7, respectively, indicating that coal source had a great influence; the changes of NOR (nitrogen oxidation ratio, 0.44, 0.45, 0.61) and SOR (sulphur oxidation ratio, 0.40, 0.49, 0.65) indicated the accumulation of secondary aerosols with increasing pollution. The coal combustion, motor vehicle, secondary inorganic sources and industrial sources contributed 36.8%, 26.59%, 11.84% and 8.02% to PM2.5 masses, respectively. Backward trajectory showed that the influence from the east was greater during the Spring Festival, and the pollutants from the eastern air mass were higher, which would aggravate the pollution. Meteorological and Spring Festival had a great impact on heavy pollution weather. Although some work could not operate due to the impact of the COVID-19 epidemic, the emission of pollutants did not reduce much. 相似文献
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7.
本法用Ag/S离子选择电极测定废水中的硫化物,测定浓度范围0.1~1000.0mg/l,方法精密度为4.3%,回收率为P2.5%,检出限为0.1mg/l。大多数离子不干扰测定,该法简便快速,适用于例行监测。 相似文献
8.
The feasibility of decomplexation removal of typical contaminants in electroplating wastewater, complexed Cu(II) with 1-hydroxyethylidene-1,1-diphosphonic acid (Cu-HEDP), was first performed by a three-dimensional electric
reactor with activated biochar as particle electrodes. For the case of 50 mg/L Cu-HEDP, Cu(II) removal (90.7%) and PO
initial pH 7, acid-treated almond shell biochar (AASB) addition 20 g/L, and reaction time 180 min, with second-order rate constants of 1.10 × 10−3 and 1.94 × 10−5 min−1respectively. The growing chelating effect between Cu(II) and HEDP and the comprehensive actions of adsorptive accumulation, direct and indirect oxidation given by particle electrodes accounted for the enhanced removal of Cu-HEDP, even though the mineralization of HEDP was mainly dependent on anode oxidation. The performance attenuation of AASB particle electrodes was ascribed to the excessive consumption of oxygen-containing functionalities during the reaction, especially acidic carboxylic groups and quinones on particle electrodes, which decreased from 446.74 to 291.48 µmol/g, and 377.55 to 247.71 µmol/g, respectively. Based on the determination of adsorption behavior and indirect electrochemical oxidation mediated by in situ electrogenerated H2O2 and reactive oxygen species (e.g., •OH), a possible removal mechanism of Cu-HEDP by three-dimensional electrolysis was further proposed. 相似文献
9.
光电化学法处理水体中腐殖酸的初步研究 总被引:10,自引:3,他引:10
结合90年代欧美学者提出了高级化学氧化过程(Advancedchemicaloxidationprocess,AOP)原理,提出了并建立了一套光电化学联用的新用于处理难以生物降解的腐殖酸废水,实验表明,在通电1h加光条件下(I=0.2A)总有碳(TOC)去除率达到90%,色度去除率达到95%。 相似文献
10.
采用固定电极测试状态的方法,将流动技术引入到离子电极直接电位分析法中,设计并试制了电极流动分析仪。配用市售硝酸根电极、钠电极、氟电极、氯电极和氨电极进行了环境样品的测定。结果表明,电极流动分析仪法的分析速度比直接电位法提高2-3倍,变异系数,2.9%-5.0%之间,回收率在90%-105%之间;直接电位法变异系数在2.3%-6.7%之间,加收率在90%-109%之间。 相似文献