微波高压络合消解石墨炉原子吸收分光光度法测定环境空气中锑

用有机滤膜采集空气中颗粒物样品,用微波高压络合消解后制成样品溶液。用石墨炉原子吸收分光光度法可确定样品溶液中锑的浓度。该方法具有对有机滤膜和样品消解完全,省时,无损失,灵敏度高,准确度、精密度好等特点。     

2-chlorophenol oxidation kinetic by photo-ssisted Fenton process

IntroductionTheo chlorophenolisaverytoxicandpoorlybiodegradablepollutant,whichisusedasanintermediateinthemanufactureofhigherchlorophenolandphenolresinsandforextractingsulphurandnitrogencompoundsfromcoals.Itisalsousedinorganicsynthesis(dyesandpesticide) .Oxidationofo chlorophenolwastewaterincatalyticwetairoxidationisofpracticalinterestsinceawastewatercontainingo chlorophenolover 2 0 0ppmmaynotbetreatedeffectivelybydirectbiologicalmethods.Advancedoxidationprocesses(AOPs)havebeensuccessfullyuse…     

活性艳红X-3B微波辅助光催化脱色的研究

研究了微波辅助光催化氧化(MW/UV/TiO2)处理活性艳红(X 3B)模拟废水。结果表明:400mg/LX 3B在反应150min时的脱色率由UV/TiO2体系的7.07%、MW体系的13.52%提高到了MW/UV/TiO2体系的56.35%。脱色反应速率随初始浓度(CX 3B)的增大而减慢;在强酸性介质中,脱色率更高;光照度(E)越强,越有利于X 3B脱色反应;改变催化剂投加量对X 3B脱色影响不大;H2O2浓度增加,X 3B脱色率升高;在以上条件下,X 3B的脱色反应均符合一级反应动力学方程,脱色反应中同时存在自由基反应与直接光解反应。     

MAE/GC-MS测定底泥中PCBs的研究

采用微波辅助萃取、气相色谱柱分离、质谱检测器检测底泥中PCBs的含量.通过实验对微波辅助参数优化,研究表明优化后的微波辅助萃取法不仅能够取得与索氏萃取法相当的效果,而且它还具有溶剂用量少、提取时间短等优点,是提取底泥中PCBs较好的方法.     

电助光催化处理高COD农药废水的研究

采用自制的电助光催化装置处理高浓度COD农药废水,处理后的出水水质符合《污水综合排放标准》(GB8978-1996)三级标准。     

Phenomenological compensation of thermally caused position and orientation errors of rotary axes

Thermal errors of machine tools are one of the major sources of inaccuracy. Therefore, the reduction of temperature induced deviations or the compensation of the resulting tool center point (TCP) errors have been of strong interest to the manufacturing industry for a couple of years. Up to now, the observation of the environment, the main spindle, the linear axes and the machine bed were in the focus of research, but with the rising demand for 5-axis machine tools and the increasing requirements regarding their accuracy, the analysis of the thermal behavior of rotary axes becomes more and more important. This paper gives an overview of corresponding thermal measurements of machine tools. The thermal behavior of rotary and swiveling axes is analyzed in detail. A simulation model and an approach for a phenomenological compensation of the TCP error are introduced and verified by measurements.     

Modulation-assisted high speed machining of compacted graphite iron (CGI)

The application of controlled, low-frequency modulation (～100 Hz) superimposed onto the cutting process in the feed-direction – modulation-assisted machining (MAM) – is shown to be quite effective in reducing the wear of cubic boron nitride (CBN) tools when machining compacted graphite iron (CGI) at high machining speeds (>500 m/min). The tool life is at least 20 times greater than in conventional machining. This significant reduction in wear is a consequence of the multiple effects realized by MAM, including periodic disruption of the tool–workpiece contact, formation of discrete chips, enhanced fluid action and lower cutting temperatures. The propensity for thermochemical wear of CBN, the principal wear mode at high speeds in CGI machining, is thus reduced. The tool wear in MAM is also found to be smaller at the higher cutting speeds (730 m/min) tested. The feed-direction MAM appears feasible for implementation in industrial machining applications involving high speeds.     

3D numerical investigation of thermally assisted high efficiency ductile machining of nanocrystalline hydroxyapatite

This study investigates the effects of four different variables (initial workpiece temperature, side rake angle, edge radius/feed rate, and nose radius/depth of cut) on ductile regime machining of a bioceramic material known as nanohydroxyapatite (nano-HAP) using 3D numerical simulation. AdvantEdge FEM Version 5.9 is used to conduct turning simulations of the nano-HAP workpiece. Tecplot 360 is used to analyze the results of the simulations. Because the workpiece is thin, the entire workpiece is set to a uniform initial temperature to simulate laser preheating of the material. Initial workpiece temperature, rake angle (side rake angle), edge radius, and nose radius are varied, and the effects of these operating conditions on critical feed are investigated. It is found that critical feed increases as initial workpiece temperature increases, and also as negativity of rake angle increases. For the edge radius, it is concluded that an initial increase causes an increase in critical feed – however, at some value of edge radius, critical feed shows no further increase; for the nose radius, critical feed appears to show no significant dependence.     

微波辅助空气氧化水溶液中的PCP

采用活性炭为催化剂,对微波辅助空气氧化水溶液中的五氯酚进行了处理研究.考察了活性炭投加量、微波功率、辐射时间和通气量对溶液中五氯酚的去除率的影响.结果表明,在通气量为0.2 L/min,微波功率800 W和微波辐射60 min时,五氯酚的去除率可达到90%以上;对微波辐射前后的滤液进行紫外扫描和pH分析,可证实五氯酚被降解.