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951.
A statistical procedure is developed to adjust natural streamflows simulated by dynamical models in downstream reaches, to account for anthropogenic impairments to flow that are not considered in the model. The resulting normalized downstream flows are appropriate for use in assessments of future anthropogenically impaired flows in downstream reaches. The normalization is applied to assess the potential effects of climate change on future water availability on the Rio Grande at a gage just above the major storage reservoir on the river. Model‐simulated streamflow values were normalized using a statistical parameterization based on two constants that relate observed and simulated flows over a 50‐year historical baseline period (1964–2013). The first normalization constant is a ratio of the means, and the second constant is the ratio of interannual standard deviations between annual gaged and simulated flows. This procedure forces the gaged and simulated flows to have the same mean and variance over the baseline period. The normalization constants can be kept fixed for future flows, which effectively assumes that upstream water management does not change in the future, or projected management changes can be parameterized by adjusting the constants. At the gage considered in this study, the effect of the normalization is to reduce simulated historical flow values by an average of 72% over an ensemble of simulations, indicative of the large fraction of natural flow diverted from the river upstream from the gage. A weak tendency for declining flow emerges upon averaging over a large ensemble, with tremendous variability among the simulations. By the end of the 21st Century the higher‐emission scenarios show more pronounced declines in streamflow.  相似文献   
952.
Devils Lake is a terminal lake located in northeast North Dakota. Because of its glacial origin and accumulated salts from evaporation, the lake has a high concentration of sulfate compared to the surrounding water bodies. From 1993 to 2011, Devils Lake water levels rose by ~10 m, which flooded surrounding communities and increased the chance of an overspill to the Sheyenne River. To control the flooding, the State of North Dakota constructed two outlets to pump the lake water to the river. However, the pumped water has raised concerns about of water quality degradation and potential flooding risk of the Sheyenne River. To investigate these perceived impacts, a Soil and Water Assessment Tool (SWAT) model was developed for the Sheyenne River and it was linked to a coupled SWAT and CE‐QUAL‐W2 model that was developed for Devils Lake in a previous study. While the current outlet schedule has attempted to maintain the total river discharge within the confines of a two‐year flood (36 m3/s), our simulation from 2012 to 2018 revealed that the diversion increased the Sheyenne River sulfate concentration from an average of 125 to >750 mg/L. Furthermore, a conceptual optimization model was developed with a goal of better preserving the water quality of the Sheyenne River while effectively mitigating the flooding of Devils Lake. The optimal solution provides a “win–win” outlet management that maintains the efficiency of the outlets while reducing the Sheyenne River sulfate concentration to ≤600 mg/L.  相似文献   
953.
Weather variability has the potential to influence municipal water use, particularly in dry regions such as the western United States (U.S.). Outdoor water use can account for more than half of annual household water use and may be particularly responsive to weather, but little is known about how the expected magnitude of these responses varies across the U.S. This nationwide study identified the response of municipal water use to monthly weather (i.e., temperature, precipitation, evapotranspiration [ET]) using monthly water deliveries for 229 cities in the contiguous U.S. Using city‐specific multiple regression and region‐specific models with city fixed effects, we investigated what portion of the variability in municipal water use was explained by weather across cities, and also estimated responses to weather across seasons and climate regions. Our findings indicated municipal water use was generally well‐explained by weather, with median adjusted R2 ranging from 63% to 95% across climate regions. Weather was more predictive of water use in dry climates compared to wet, and temperature had more explanatory power than precipitation or ET. In response to a 1°C increase in monthly maximum temperature, municipal water use was shown to increase by 3.2% and 3.9% in dry cities in winter and summer, respectively, with smaller changes in wet cities. Quantifying these responses allows urban water managers to plan for weather‐driven variability in water use.  相似文献   
954.
Climate change poses water resource challenges for many already water stressed watersheds throughout the world. One such watershed is the Upper Neuse Watershed in North Carolina, which serves as a water source for the large and growing Research Triangle Park region. The aim of this study was to quantify possible changes in the watershed’s water balance due to climate change. To do this, we used the Soil and Water Assessment Tool (SWAT) model forced with different climate scenarios for baseline, mid‐century, and end‐century time periods using five different downscaled General Circulation Models. Before running these scenarios, the SWAT model was calibrated and validated using daily streamflow records within the watershed. The study results suggest that, even under a mitigation scenario, precipitation will increase by 7.7% from the baseline to mid‐century time period and by 9.8% between the baseline and end‐century time period. Over the same periods, evapotranspiration (ET) would decrease by 5.5 and 7.6%, water yield would increase by 25.1% and 33.2%, and soil water would increase by 1.4% and 1.9%. Perhaps most importantly, the model results show, under a high emission scenario, large seasonal differences with ET estimated to decrease by up to 42% and water yield to increase by up to 157% in late summer and fall. Planning for the wetter predicted future and corresponding seasonal changes will be critical for mitigating the impacts of climate change on water resources.  相似文献   
955.
Introduction: For many reasons, including a lack of adequate safety training and education, U.S. adolescents experience a higher rate of job-related injury compared to adult workers. Widely used social-psychological theories in public health research and practice, such as the theory of planned behavior, may provide guidance for developing and evaluating school-based interventions to prepare adolescents for workplace hazards and risks. Method: Using a structural equation modeling approach, the current study explores whether a modified theory of planned behavior model provides insight on 1,748 eighth graders’ occupational safety and health (OSH) attitude, subjective norm, self-efficacy and behavioral intention, before and after receiving instruction on a free, national young worker safety and health curriculum. Reliability estimates for the measures were produced and direct and indirect associations between knowledge and other model constructs assessed. Results: Overall, the findings align with the theory of planned behavior. The structural equation model adequately fit the data; most path coefficients are statistically significant and knowledge has indirect effects on behavioral intention. Confirmatory factor analyses suggest that the knowledge, attitude, self-efficacy, and behavioral intention measures each reflect a unique dimension (reliability estimates ≥0.86), while the subjective norm measure did not perform adequately. Conclusion: The findings presented provide support for using behavioral theory (specifically a modified theory of planned behavior) to investigate adolescents’ knowledge, perceptions, and behavioral intention to engage in safe and healthful activities at work, an understanding of which may contribute to reducing the downstream burden of injury on this vulnerable population—the future workforce. Practical application: Health behavior theories, commonly used in the social and behavioral sciences, have utility and provide guidance for developing and evaluating OSH interventions, including those aimed at preventing injuries and promoting the health and safety of adolescent workers in the U.S., who are injured at higher rates than are adults.  相似文献   
956.
Introduction: Symptoms of depression and anxiety are a common consequence of occupational injury regardless of its cause and type. Nevertheless, mental health care is rarely covered by workers’ compensation systems. The aim of this study was to assess the use of mental health care post-injury. Methods: We used a subsample of patient-care workers from the Boston Hospital Workers Health Study (BHWHS). We matched one injured worker with three uninjured workers during the period of 2012–2014 based on age and job title (nurse or patient-care associate) and looked at their mental health care use pre- and post-injury using medical claims data from the employer sponsored health plan. We used logistic regression analysis to assess the likelihood of mental health care use three and six months post-injury controlling for any pre-injury visits. Analyses were repeated separately by job title. Results: There were 556 injured workers between 2012 and 2014 that were matched with three uninjured workers at the time of injury (n = 1,649). Injured workers had a higher likelihood of seeking mental health care services than their uninjured counterparts during the six months after injury (OR = 1.646, 95% CI: 1.23–2.20), but not three months post-injury (OR = 0.825, 95% CI: 0.57–1.19). Patient-care associates had a higher likelihood to seek mental health care post-injury, than nurses (OR: 2.133 vs OR: 1.556) during the six months period. Conclusions: Injured workers have a higher likelihood to experience symptoms of depression and anxiety based on their use of mental health care post-injury and use is more predominant among patient-care associates; however, our sample has a small number of patient-care associates. Practical Applications: Treating depression and anxiety as part of the workers’ compensation system has the potential of preventing further physical ailment and improving the return to work process regardless of nature of injury.  相似文献   
957.
Thermal runaway hazard assessment provides the basis for comparing the hazard levels of different chemical processes. To make an overall evaluation, hazard of materials and reactions should be considered. However, most existing methods didn't take the both into account simultaneously, which may lead the assessment to a deviation from the actual hazard. Therefore, an integrated approach called Inherent Thermal-runaway Hazard Index (ITHI) was developed in this paper. Similar to Dow Fire and Explosion Index(F&EI) function, thermal runaway hazard of chemical process in ITHI was the product of material factor (MF) and risk index (RI) of reaction. MF was an indicator of material thermal hazards, which can be determined by initial reaction temperature and maximum power density. RI, which was the product of probability and severity, indicated the risk of thermal runaway during the reaction stage. Time to maximum rate under adiabatic conditions and criticality classes of scenario were used to indicate the runaway probability of the chemical process. Adiabatic temperature rise and heat of the desired reaction and secondary reaction were used to determine the severity of runaway reaction. Finally, predefined hazard classification criteria was used to classify and interpret the results obtained by this method. Moreover, the method was validated by case studies.  相似文献   
958.
The accomplishments of inherent safety in the field of loss prevention thus far are impressive due to its scientific philosophy: reducing risks at source rather than adding engineered and procedural protections. Generally, the implementation of inherent safety can be done through a cohesive set of fourteen principles elucidated by Kletz and Amyotte. This work, guided by the fourteen principles, presents a systematic review on the implementation methodologies of inherent safety. Firstly, PRISMA procedure was adopted to select eligible literatures according to inclusive and exclusive criteria. After obtaining the selected literatures, the preference, level of application, and gaps in using these principles were critically analyzed. Of the fourteen principles, intensification, substitution, attenuation, simplification, limitation of effects, and avoidance of knock-on effects are preferable to implementing inherent safety in chemical process. Although the remaining principles are also potentially useful, they are not commonly used due to their costs and complexities of implementation. Overall, this work presents a complete spectrum to look across the implementation methodologies of inherent safety and concludes with some holistic and inclusive approaches as future research recommendations.  相似文献   
959.
Most petrochemical units run under extreme conditions, such as high temperatures, pressures, and speeds. Consequently, the equipment operators may commit errors because the startup and shutdown processes usually involve complicated operation steps; moreover, the operators may lack experience in handling abnormal situations. Misoperation can lead to accidents, including fires and explosions. Thus, risk analysis for process operations and the development of preventive measures have become an effective means of avoiding misoperation-related accidents. However, it is challenging to ensure the comprehensiveness of risk-analysis results. In this paper, we present a method for misoperation monitoring and early warning in the startup and shutdown processes of petrochemical units. The mechanisms of misoperation occurrence are summarized based on investigations of serious accidents in the recent past. Knowledge regarding the mechanisms of misoperation is crucial for the risk analysis of petrochemical units. The potential risk information, such as causes, adverse consequences, key monitoring parameters, and prevention control solutions, should be acquired and be employed to construct an early-warning knowledge database. Furthermore, misoperation judgment rules need to be formulated to identify misoperations. The data obtained from the monitoring module, misoperation judgment rules, and analysis results can aid in developing schemes to avoid possible abnormal situations. This paper reports a misoperation monitoring and early-warning system for a hydrogenation unit. As demonstrated, conducting risk analysis to determine the potential operational risks and formulating misoperation judgment rules to analyze the process data are essential for enabling early warning. The application of this method will contribute to operational guidance, economic loss reduction, and accident avoidance.  相似文献   
960.
随着污水处理厂排到受纳水体标准的不断提高及区域污染物排放限值的要求,已建的污水处理厂需要提标改造提高排放标准。本文所提工程对现有的CASS池进行改造,通过投加悬浮填料形成CASS+MBBR工艺,其中TN污染物的去除率可提高到8%~15%间,其它污染物也能达到预期的设计标准。  相似文献   
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