运用生态有偿服务制度保护流域生态系统

中国现有的依赖公共财政支付的生态补偿机制,给生态补偿机制的长期维持带来了不确定性.本文着重探讨一种"创新方法"--生态有偿服务制度在中国的前景,以及如何促进其进一步广泛使用:在回顾中国生态补偿机制的政策和实践之后,探讨生态有偿服务制度的概念和方法,并以长江上游区域的一个小自然保护区为例,评估了在中国采用生态有偿服务制度的潜力,最后提出了一些政策建议.     

中国生态补偿政策评估与框架初探

按照法律法规、政府手段、市场机制的体系对中国现行的生态补偿机制与政策进行了系统的评估,总结了中国生态补偿机制和政策在法律法规体系、财政制度、重大生态建设工程、生态税费制度和市场交易模式等方面存在的问题和改进方向.在此基础上,基于不同尺度上的生态建设外部性问题,提出中国生态补偿机制和政策的初步框架,包括西部生态补偿、生态功能区补偿、流域生态补偿和生态要素补偿等.并针对当前生态补偿面临的紧迫问题和可能的应对措施,提出近阶段中国生态补偿应该重点突破的若干政策领域.      

中国农业生态补偿法律制度建设研究

2014年通过的《环境保护法》第31条规定:国家建立、健全生态保护补偿制度.紧随其后,2014年5月苏州市人大常委会正式批准了《苏州市生态补偿条例》,彰显了国家和地方政府对于生态补偿这一法律制度的重视.农业生态补偿作为生态补偿的一个具体分支,法律制度的建设,将对当前中国日趋严重的农业面源污染问题,提供一个现实的解决路径.文中找出农业生态补偿法律制度存在的问题,并提出具体的建设意见,为中国农业生态补偿法律制度的建设提供理论上的支撑.     

生态利益的法律补偿制度与机制分析

生态利益法律补偿制度指的是运用经济手段实现生态资源环境保护及恢复的一项重要的资源保护制度,我国目前的生态利益法律补偿机制呈现出多元化、多层次的特点,生态利益法律补偿制度是人们通过反思工业给生态环境带来的深重灾难之后所制定的一套环境资源管理制度,因此,在社会主义发展的新时期,对于我国现存的生态利益法律补偿制度进行研究,有助于对我国的生态利益法律补偿制度建设指明发展方向,从而推动我国生态利益法律补偿制度的建设.     

西部民族地区生态补偿法律问题研究

生态问题是西部民族地区社会转型中出现"类发展困境"的典型表现,以对西部民族地区生态境遇的检视为切入,从制度层面论证了生态补偿的可能贡献,并以批判的思维对中国当前生态补偿相关法律制度进行了深入的解构与反观,进而对中国西部民族地区生态补偿法治化做出了制度的现代性重构.     

环境经济学

X196X-01200600108中国生态补偿政策评估与框架初探/万军…(中国环境规划院)∥环境科学研究/中国环科院.-2005,18(2).-1～8环图X-6按照法律法规、政府手段、市场机制的体系对中国现行的生态补偿机制与政策进行了系统的评估,总结了中国生态补偿机制和政策在法律法规体系、财政制度、重大生态建设工程、生态税费制度和市场交易模式等方面存在的问题和改进方向。在此基础上,基于不同尺度上的生态建设外部性问题,提出中国生态补偿机制和政策的初步框架,包括西部生态补偿、生态功能区补偿、流域生态补偿和生态要素补偿等。并针对当前生态补偿面…     

生态功能区补偿法律制度初探

生态功能区补偿法律制度是落实我国主体功能区布局战略的重要措施.目前我国生态补偿法律制度内容虽已比较系统丰富,但在补偿主体制度、补偿标准制度和监督管理制度等方面还明显不足.因此,有必要进一步扩大生态补偿的主体,优化生态补偿的标准,健全生态补偿监督管理制度.     

水源地生态补偿制度研究——以青岛市崂山水库为例

水源地生态补偿机制,就是用立法、计划、市场等手段解决下游地区对上游地区、开发地区对保护地区、受益地区对受损地区的利益补偿。水源地生态补偿制度是解决生态问题的有效途径,在国内外已有许多成功的实践。而在中国,水源地生态补偿制度处于刚刚起步阶段,分析生态补偿制度的立法现状,吸取国内外在实践中的经验和教训,通过明确生态补偿的权利义务主体、补偿方式和制度实施等内容,探讨水源地生态补偿制度在中国的构建,为解决水源地生态污染问题提供途径。     

国内外生态补偿机制的对比分析与研究

建立和完善生态补偿机制,是新时期中国生态环境保护政策创新的重要内容,也是新时期中国推进生态文明建设的必然选择.文章首先介绍了生态补偿的概念和内涵,重点阐述了国外的欧盟、美国、德国-捷克以及国内的浙江省、深圳市和苏州市在生态补偿机制方面的做法和经验,在此基础上提出对常州市的借鉴和启示,主要包括:依靠政府的大力推动、完善生态补偿政策和法律法规的制度,为常州市生态补偿相关管理制度和办法的制定提供理论基础.     

昆明市生态补偿机制及对策研究

生态补偿是中国生态文明建设的重要制度保障.党的十九大报告明确指出要"加大生态系统保护力度""建立市场化、多元化生态补偿机制".党的十九届四中全会要求"落实生态补偿和生态环境损害赔偿制度".     

Effects of two sludge application on fractionation and phytotoxicity of zinc and copper in the soil

The potential harm of heavy metals is a primary concern in application of sludge to the agricultural land. A pot experiment was conducted to evaluate the effect of two sludges on fractionation of Zn and Cu in soil and their phytotoxicity to pakchoi. The loamy soil was mixed with 0%, 20%, 40%, 60% and 80% (by weight) of digested sewage sludge (SS) and composted sludge (SC). The additions of both sludges caused a significant raise in all fractions, resulting in that exchangeable (EXCH) and organic bound (OM) became predominance of Zn and organic bound Cu occupied the largest portion. There was more available amount of Zn and Cu in SS treatments than SC treatments. During the pot experiment, the concentration of Zn in EXCH, carbonate (CAR) and OM and Cu in EXCH and OM fractions decreased in all treatments, so their bioavailability reduced. Germination rate and plant biomass decreased when the addition rate was high and the best yield appeared in 20% mixtures at the harvest of pakchoi. The two sludges increased tissue contents of Zn and Cu especially in the SS treatments. Zn in pakchoi was not only in relationship to ΔEXCH and ΔCAR forms but also in ΔOM forms in the sludge-soil mixtures. Tissue content of Cu in pakchoi grown on SC-soils could not be predicted by ΔEXCH. These correlation rates between Zn and Cu accumulation in pakchoi and variation of different fractions increased with time, which might indicate that sludges represented stronger impacts on the plant in long-term land application.     

Intraspecific differences in effects of co-contamination of cadmium and

A hydroponic experiment was carried out to study intraspecific differences in the effects of different concentrations of cadmium (Cd)(0-10 mg/L) and arsenate (As(V)) (0-8 mg/L) on the growth parameters and accumulation of Cd and As in six wheat varieties Jing-9428, Duokang-1, Jingdong-11, Jing-411, Jingdong-8 and Zhongmai-8. The endpoints of wheat seedlings, including seed germination,biomass, root length and shoot height, decreased with increasing the Cd and As concentrations. Significant differences in seed germination, biomass, root length, shoot height and the accumulation of Cd and As were observed between the treatments and among the varieties (p ＜ 0.05). The lethal dosage 50% were about 20, 80, 60, 60, 80 and 20 mg As/L for Jing-9428, Duokang-1, Jingdong-11,Jing-411, Jingdong-8 and Zhongmai-8, respectively, and the corresponding values for Cd were about 30, 80, 20, 40, 60 and 10 mg Cd/L, respectively. Among the six varieties, Duokang-1 was found to be the most resistant to Cd and As toxicity, and Zhongmai-8 was the most sensitive to Cd and As co-contamination. The resistance of the six varieties was found dependant on the seedling uptake of Cd and As. Duokang-1 was the most suitable for cultivation in Cd and As co-contaminated soils.     

Toxic effects of acetochlor, methamidophos and their combination on nifH gene in soil

Toxic effects of two agrochemicals on nifH gene in agricultural black soil were investigated using denaturing gradient gel electrophoresis （DGGE） and sequencing approaches in a microcosm experiment. Changes of soil nifH gene diversity and composition were examined following the application of acetochlor, methamidophos and their combination. Acetochlor reduced the nifH gene diversity （both in gene richness and diversity index values） and caused changes in the nifH gene composition. The effects of acetochlor on nifH gene were strengthened as the concentration of acetochlor increased. Cluster analysis of DGGE banding patterns showed that nifH gene composition which had been affected by low concentration of acetochlor （50 mg/kg） recovered firstly. Methamidophos reduced nifH gene richness that except at 4 weeks. The medium concentration of methamidophos （150 mg/kg） caused the most apparent changes in nifH gene diversity at the first week while the high concentration of methamidophos （250 mg/kg） produced prominent effects on nifH gene diversity in the following weeks. Cluster analysis showed that minimal changes of nifH gene composition were found at 1 week and maximal changes at 4 weeks. Toxic effects of acetochlor and methamidophos combination on nifH gene were also apparent. Different nifH genes （bands） responded differently to the impact of agrochemicals： four individual bands were eliminated by the application of the agrochemicals, five bands became predominant by the stimulation of the agrochemicals, and four bands showed strong resistance to the influence of the agrochemicals. Fifteen prominent bands were partially sequenced, yielding 15 different nifH sequences, which were used for phylogenetic reconstructions. All sequences were affiliated with the alpha- and beta-proteobacteria, showing higher similarity to eight different diazotrophic genera.     

Arsenic uptake by arbuscular mycorrhizal maize （Zea mays L.） grown in an arsenic-contaminated soil with added phosphorus

The effects of arbuscular mycorrhizal (AM) fungus (Glomus mosseae) and phosphorus (P) addition (100 mg/kg soil) on arsenic (As) uptake by maize plants (Zea mays L.) from an As-contaminated soil were examined in a glasshouse experiment.Non-mycorrhizal and zero-P addition controls were included.Plant biomass and concentrations and uptake of As,P,and other nutrients,AM colonization,root lengths,and hyphal length densities were determined.The results indicated that addition of P significantly inhibited root colonization and development of extraradical mycelium.Root length and dry weight both increased markedly with mycorrhizal colonization under the zero-P treatments,but shoot and root biomass of AM plants was depressed by P application.AM fungal inoculation decreased shoot As concentrations when no P was added,and shoot and root As concentrations of AM plants increased 2.6 and 1.4 times with P addition,respectively.Shoot and root uptake of P,Mn,Cu,and Zn increased,but shoot Fe uptake decreased by 44.6%,with inoculation, when P was added.P addition reduced shoot P,Fe,Mn,Cu,and Zn uptake of AM plants,but increased root Fe and Mn uptake of the nonmycorrhizal ones.AM colonization therefore appeared to enhance plant tolerance to As in low P soil,and have some potential for the phytostabilization of As-contaminated soil,however,P application may introduce additional environmental risk by increasing soil As mobility.     

Distribution and ecological effect of mercury in Laogang landfill, Shanghai, China

Laogang landfill near Shanghai is the largest landfill in China, and receives about 10000 t of daily garbage per day, Samples of topsoil and plants were analyzed to evaluate mercury pollution from the landfill. For topsoil samples, there were significant correlations among total mercury （HgT）, combinative mercury （Hgc） and gaseous mercury （HgG）, and content of total organic carbon （TOC）, but, no significantly relationship was found between Hg content and filling time. Hg content changes in vertical profiles with time showed that the average Hgv of profiles 1992, 1996, and 2000 was similar, but their average HgG was quite different. HgT was significantly correlated with Hgc in profile 1992 and 2000, and Hgv was significantly correlated with Hg6 in profile 1996. HgG/Hgv ratio in profile samples decreased in the order of （HgG,/HgT）1992〉（HgG/HgT）1996〉〉（HgG/HgT）2000. A simple outline of Hg release in landfill could be drawn： with increasing of filling time, degradation undergoes different biodegradation, accordingly, gaseous mercury goes through small, more, and small proportion to total mercury. Distribution of Hg in plants was inhomogeneous, following the order of leaf〉root〉stem. The highest value of leaf may be associated with higher atmospheric Hg from landfill. Ligneous plants （e.g. Phyllostachys glanca, Prunus salicina and Ligustrum lucidum） are capable of enriching more Hg than herbaceous plants.     

EDTA-enhanced phytoremediation of lead contaminated soil by Bidens maximowicziana

Phytoremediation is a potential cleanup technology for the removal of heavy metals from contaminated soils.Bidens maximowicziana is a new Pb hyperaccumulator,which not only has remarkable tolerance to Pb but also extraordinary accumulation capacity for Pb.The maximum Pb concentration was 1509.3 mg/kg in roots and 2164.7 mg/kg in overground tissues.The Pb distribution order in the B. maximowicziana was:leaf>stem>root.The effect of amendments on phytoremediation was also studied.The mobility of soil Pb and the Pb concentrations in plants were both increased by EDTA application.Compared with CK(control check),EDTA application promoted translocation of Pb to overground parts of the plant.The Pb concentrations in overground parts of plants was increased from 24.23-680.56 mg/kg to 29.07-1905.57 mg/kg.This research demonstrated that B.maximowicziana appeared to be suitable for phytoremediation of Pb contaminated soil,especially,combination with EDTA.     

Potential of plant polyphenol oxidases in the decolorization and removal of textile and non-textile dyes

In this study an effort has been made to use plant polyphenol oxidases; potato （Solanum tuberosum） and brinjal （Solanum melongena）, for the treatment of various important dyes used in textile and other industries. The ammonium sulphate fractionated enzyme preparations were used to treat a number of dyes under various experimental conditions. Majority of the treated dyes were maximally decolorized at pH 3.0. Some of the dyes were quickly decolorized whereas others were marginally decolorized. The initial first hour was sufficient for the maximum decolorization of dyes. The rate of decolorization was quite slow on long treatment of dyes. Enhancement in the dye decolorization was noticed on increasing the concentration of enzymes. The complex mixtures of dyes were treated with both preparations of polyphenol oxidases in the buffers of varying pH values. Potato polyphenol oxidase was significantly more effective in decolorizing the dyes to higher extent as compared to the enzyme obtained from brinjal polyphenol oxidase. Decolorization of dyes and their mixtures, followed by the formation of an insoluble precipitate, which could be easily removed simply by centrifugation.     

Decomposition of alachlor by ozonation and its mechanism

Decomposition and corresponding mechanism of alachlor, an endocrine disruptor in water by ozonation were investigated. Results showed that alachlor could not be completely mineralized by ozone alone. Many intermediates and final products were formed during the process, including aromatic compounds, aliphatic carboxylic acids, and inorganic ions. In evoluting these products, some of them with weak polarity were qualitatively identified by GC-MS. The information of inorganic ions suggested that the dechlorination was the first and the fastest step in the ozonation of alachlor.     

Enzymatic oxidation of aqueous pentachlorophenol

The influence of the nonionic surfactant Tween 80 on pentachlorophenol （PCP） oxidation catalyzed by horseradish peroxidase was studied. The surfactant was tested at concentrations below and above its critical micelle concentration （CMC）. Enhancement of PCP removal was observed at sub-CMCs. The presence of Tween 80 in the reaction mixture reduced enzyme inactivation which occurred through a combination of free radical attack and sorption by precipitated products. A simple first-order model was able to simulate time profiles for enzyme inactivation in the presence or absence of Tween 80. At supra-CMCs, the surfactant caused noticeable reductions in PCP removal, presumably through micelle partitioning of PCP which precluded the hydrophobic PCP molecule from interacting with the enzyme.     

Effect of sorbed and desorbed Zn(Ⅱ) on the growth of a green alga (Chlorella pyrenoidosa)

Toxic effect of Zn(Ⅱ) on a green alga (Chlorella pyrenoidasa) in the presence of sepiolite and kaolinite was investigated.The Zn-free clays were found to have a negative impact on the growth of C.pyrenoidosa in comparison with control samples (without adding any clay or Zn(Ⅱ)).When Zn(Ⅱ) was added,the algae in the presence of clays could be better survived than the control samples,which was actually caused by a decrease in Zn(Ⅱ) concentration in the solution owing to the adsorption of Zn(Ⅱ) on the clays.When the solution system was diluted,the growth of algae could be further inhibited as compared to that in a system which had the same initial Zn(Ⅱ) concentration as in the diluted system.This in fact resulted from desorption of Zn(Ⅱ) from the zinc-contaminated clays,although the effect varied according to the different desorption capabilities of sepiolite and kaolinite.Therefore the adsorption and desorption processes of Zn(Ⅱ) played an important part in its toxicity,and adsorption and desorption of pollutants on soils/sediments should be well considered in natural eco-environmental systems before their risk of toxicity to aquatic organisms was assessed objectively.