新疆农用地变化的环境效应

土地生态环境问题一直都是专家、学者研究的热点话题,土地利用的生态环境效应更是人们日益关注的问题,以新疆1996-2004年农用地详查数据为依据,在分析研究土地利用的变化特点的基础上,阐述了农用地变化产生的环境效应.尽管农用地数量在整体上是增加的,但是土地沙化、退化,水土流失、生物多样性减少等一系列生态环境恶化现象仍在继续.因此,新疆农用地要在水资源的承载范围内适度增加.目前,新疆农用地变化给整体环境带来负面的效应,仅使局部生态环境改善,整体环境变坏.因此,新疆在土地利用中,要以此为鉴,加强生态环境建设,注重各种功能用地的结合.     

半城市化地区土地利用变化及驱动力分析——以厦门市集美区为例

半城市化地区是在快速城市化进程中产生的一种过渡类型地域,伴随着剧烈的土地利用竞争和矛盾,土地利用变化迅速的特征。以厦门市集美区为例分析了半城市化地区土地利用演变规律,发现1987-2007年间研究区土地利用强度持续提高,城市建设用地和农村建设用地增加,农用地和淡水水域面积减少。矩阵转移分析结果表明,城市建设用地的增加主要来自未利用地、农用地和农村建设用地,农村建设用地的增加主要由农用地和未利用地转化而来,农用地是城市化过程中最容易受到侵占的土地利用类型。建设用地变化与非农业人口、总GDP,第二产业产值、固定资产投资、农民人均纯收入、实际利用外资、房地产投资呈现显著的正相关关系,是建设用地变化的主要驱动力。农用地面积变化与非农人口、总GDP、第一产业产值、第二产业产值、农民人均纯收入以及实际利用外资呈现显著的负相关关系。集美半城市化地区土地利用变化的主要驱动力包括城市人口增长、土地利用政策、经济结构调整、公共基础设施的发展以及国家政策。     

黄河三角洲土地利用/土地覆盖变化研究现状与展望

土地利用/土地覆盖变化是全球环境变化研究的3个核心主题之一。黄河三角洲是我国乃至世界造陆速度最快的河口三角洲之一。伴随着人口的不断增加,黄河流域经济的发展,河口地带油气的开发,黄河三角洲土地利用/土地覆盖发生了迅速的变化,从而引发了土壤盐渍化、水污染严重、湿地资源保护受到威胁等一系列生态环境问题。论文以黄河三角洲为典型样区,把其土地利用/土地覆盖变化的研究作为全球环境变化研究的一个缩影,为全球性土地利用/土地覆盖变化模型的建立提供依据。论文首先介绍了黄河三角洲概况,其次对该地区土地利用/土地覆盖变化探测方法、结果进行了对比、归纳,接着回顾了该地区对土地利用/土地覆盖变化的驱动力分析以及模型预测,然后介绍了土地利用/土地覆盖与环境变化交互作用等的研究状况,最后总结了目前黄河三角洲土地利用/土地覆盖研究所取得的成绩和存在的不足,同时为进一步开展该地区的研究工作提出了若干建议。     

土地利用动态变化与生态环境效应研究——以多伦县蔡木山乡为例

采用遥感技术,对位于农牧交错带的内蒙古自治区锡林郭勒盟多伦县蔡木山乡土地利用动态变化及生态环境效应进行定性、定量相结合的研究.运用Arcview3.3地信息系统软件对研究区2000年、2010年的遥感影像进行解译,获取土地利用现状及动态变化数据,运用土地利用动态变化模型对该乡十年间的土地利用变化进行了定量研究,得出蔡木山乡土地利用变化的幅度、速度和程度等信息,就该乡的实际情况进行生态环境效应分析,以便针对实际,提出具体建议.     

区域土地利用变化对生态环境影响定量评估——以铜川市城郊区为例

区域土地利用变化对生态环境的影响,是地理学全球变化研究的重要内容,而生态服务价值则是目前生态学、生态经济学研究的热点问题。研究利用研究区地形、土壤、植被数据和近10年来每年的气候、土地利用数据,运用生态服务价值测算模型,计算了1994~2003年铜川市城郊区历年的生态服务价值,并模拟了无土地利用变化情景下的生态服务价值,提出了土地利用变化环境效应指数,并尝试性地运用该指数定量评价了城郊区土地利用变化对生态环境的影响。结果表明:①由于气候变化、人类活动尤其是土地利用变化等原因的影响,城郊区生态服务价值年际间变化很大,1994~2003年期间,在不考虑水域生态服务功能情况下（基于水域面积年际变化极小考虑）,城郊区生态服务价值在4.77×108~1.56×10⁹元间波动;②模拟了无土地利用变化情景下的生态服务价值,结果表明每年基于无土地利用变化情景下的生态服务价值明显低于基于土地利用变化情景下的生态服务价值;③运用土地利用变化环境效应指数计算模型计算了土地利用变化环境效应指数,结果表明都大于1,从1994年到2003年期间,土地利用变化环境效应指数除个别年份略有波动外,整体呈增加趋势,反映了土地利用变化对城郊区生态环境的影响是积极的。     

城市边缘区土地利用变化及其降噪效应研究

土地利用及生态环境效应是全球环境变化研究的重要组成部分。以深圳市福田红树林国家级自然保护区及其周边地区为例,基于多源遥感影像进行土地利用变化分析,进而评估边缘区的生态敏感性,然后采用数学模拟的方法研究边缘区对交通噪声衰减效应的影响。结果表明:研究区在1983—2010年间土地利用变化以基围鱼塘向建设和交通用地转化为主,交通用地给保护区带来严重的噪声污染;声屏障和陆地绿地建成后,保护区噪声影响的鸟类生存适宜区23.86%增加到54.32%,降噪效应非常明显。     

多情景模拟下的新疆生态系统服务价值评估

研究多情景下的新疆土地利用变化及生态系统服务价值（ESV）,探讨区域内最优的土地利用分布格局,对干旱区的可持续发展与土地利用规划具有重要意义。该研究耦合多目标优化和斑块生成土地利用模拟(PLUS)模型对自然发展情景、经济发展情景、生态优先情景、可持续发展情景4种情景下的土地利用需求及空间分布进行预测模拟,采用价值当量法计算新疆未来情景下的生态系统服务价值。结果表明：（1）2000-2020年,新疆土地利用类型以荒地为主,土地利用变化主要表现为耕地的增加和荒地的减少。2035年4种情景下的土地利用变化不同,空间模拟结果整体上扩张趋势一致,局部变化明显。（2）利用PLUS模型对新疆的土地利用变化模拟效果较好,Kappa系数均值达到0.899 1,总体精度均值达到0.954 8,可以有效模拟新疆2035年的土地利用空间格局。（3）2035年自然发展、经济发展、生态优先、可持续发展情景下的ESV分别为18 717.25、17 816.36、19 221.52、18 134.45亿元。加强草地、水域、林地、湿地等生态用地的保护,有利于提高ESV价值总量。可持续发展情景可作为兼顾生态保护和经济发展...     

深圳市土地利用/覆盖变化与生态环境安全分析

应用１９８０、１９８８、１９９４年的ＭＳＳ、ＴＭ资料,编制了相应时期深圳市土地利用／覆盖图,分析了近２０年来深圳市土地利用变化的时空分异规律。在此基础上,分析了土地利用变化与城市生态环境安全水平的关系。研究结果表明,深圳快速的城市化过程是引起土地利用变化的主要原因；土地利用中城镇用地的增加导致城市洪水的加剧和水土流失的增加；以乡镇为单元的环境污染的空间差异与对应区域城镇用地比例的大小呈明显的正相关关系,显著性水平达到０－００１,由此认为,在城市化过程中,确保相当数量的绿地对缓解城市生态环境问题有着不可替代的作用。     

土地利用／土地覆被变化对区域生态环境的影响

土地利用／土地覆被变化对区域生态环境的影响是土地利用／土地覆被变化研究的重要内容，本文分析了土地利用／土地覆被变化对区域气候，土壤，水量和水质的影响，土地利用／土地覆被变化通过改变地表发射率，温室气体和痕量气体的含量影响区域气候，土地利用／土地覆被变化影响着能量交换，水交换，侵蚀与堆积，生物循环和作物生产等土壤主要生态过程，不同土地利用方式和土地覆被类型的空间组合影响着土壤养分的迁移规律，土地利用     

近20年来黑河干流中游地区土地利用/覆被变化及驱动力定量研究

黑河干流水量统一调度实施后(即2000年以后),流域干流中游地区用水量在时空上进一步受到限制。为此,研究黑河干流中游地区土地利用/覆被变化过程及其驱动力,尤其是黑河水量统一调度以来的生态环境问题,对研究区可持续发展具有重要意义。研究表明:①研究区土地利用发生了较大变化,1985-2000年,耕地、林地、城乡工矿居民用地逐渐增加,而草地、水域、未利用土地不断减少,2000-2005年耕地、城乡工矿居民用地逐渐增加,而草地、林地、水域、未利用土地不断减少;②黑河流域干流水量统一调配以来,一方面研究区可用水量进一步减少,另一方面研究区耕地短时间增加较快,研究区生态环境有退化的迹象,草地、林地、水域面积呈现减少趋势,变化率分别为2.14%、7.36%和3.69%;③1985-2000年土地利用类型主要呈现耕地和城乡工矿居民用地、耕地和未利用土地之间的相互转换,草地转为耕地,2000-2005年,土地利用类型主要呈现未利用土地转为耕地,草地和耕地之间相互转换;④土地利用程度变化存在明显的区域差异,以甘州区变化最大;⑤研究区土地利用/覆被变化的主要驱动力为社会经济因子,包括人口增长、经济社会发展等,2000年黑河流域水量统一调配以后,中游可利用水量的约束直接影响着研究区的土地利用变化。     

Effects of two sludge application on fractionation and phytotoxicity of zinc and copper in the soil

The potential harm of heavy metals is a primary concern in application of sludge to the agricultural land. A pot experiment was conducted to evaluate the effect of two sludges on fractionation of Zn and Cu in soil and their phytotoxicity to pakchoi. The loamy soil was mixed with 0%, 20%, 40%, 60% and 80% (by weight) of digested sewage sludge (SS) and composted sludge (SC). The additions of both sludges caused a significant raise in all fractions, resulting in that exchangeable (EXCH) and organic bound (OM) became predominance of Zn and organic bound Cu occupied the largest portion. There was more available amount of Zn and Cu in SS treatments than SC treatments. During the pot experiment, the concentration of Zn in EXCH, carbonate (CAR) and OM and Cu in EXCH and OM fractions decreased in all treatments, so their bioavailability reduced. Germination rate and plant biomass decreased when the addition rate was high and the best yield appeared in 20% mixtures at the harvest of pakchoi. The two sludges increased tissue contents of Zn and Cu especially in the SS treatments. Zn in pakchoi was not only in relationship to ΔEXCH and ΔCAR forms but also in ΔOM forms in the sludge-soil mixtures. Tissue content of Cu in pakchoi grown on SC-soils could not be predicted by ΔEXCH. These correlation rates between Zn and Cu accumulation in pakchoi and variation of different fractions increased with time, which might indicate that sludges represented stronger impacts on the plant in long-term land application.     

Intraspecific differences in effects of co-contamination of cadmium and

A hydroponic experiment was carried out to study intraspecific differences in the effects of different concentrations of cadmium (Cd)(0-10 mg/L) and arsenate (As(V)) (0-8 mg/L) on the growth parameters and accumulation of Cd and As in six wheat varieties Jing-9428, Duokang-1, Jingdong-11, Jing-411, Jingdong-8 and Zhongmai-8. The endpoints of wheat seedlings, including seed germination,biomass, root length and shoot height, decreased with increasing the Cd and As concentrations. Significant differences in seed germination, biomass, root length, shoot height and the accumulation of Cd and As were observed between the treatments and among the varieties (p ＜ 0.05). The lethal dosage 50% were about 20, 80, 60, 60, 80 and 20 mg As/L for Jing-9428, Duokang-1, Jingdong-11,Jing-411, Jingdong-8 and Zhongmai-8, respectively, and the corresponding values for Cd were about 30, 80, 20, 40, 60 and 10 mg Cd/L, respectively. Among the six varieties, Duokang-1 was found to be the most resistant to Cd and As toxicity, and Zhongmai-8 was the most sensitive to Cd and As co-contamination. The resistance of the six varieties was found dependant on the seedling uptake of Cd and As. Duokang-1 was the most suitable for cultivation in Cd and As co-contaminated soils.     

Toxic effects of acetochlor, methamidophos and their combination on nifH gene in soil

Toxic effects of two agrochemicals on nifH gene in agricultural black soil were investigated using denaturing gradient gel electrophoresis （DGGE） and sequencing approaches in a microcosm experiment. Changes of soil nifH gene diversity and composition were examined following the application of acetochlor, methamidophos and their combination. Acetochlor reduced the nifH gene diversity （both in gene richness and diversity index values） and caused changes in the nifH gene composition. The effects of acetochlor on nifH gene were strengthened as the concentration of acetochlor increased. Cluster analysis of DGGE banding patterns showed that nifH gene composition which had been affected by low concentration of acetochlor （50 mg/kg） recovered firstly. Methamidophos reduced nifH gene richness that except at 4 weeks. The medium concentration of methamidophos （150 mg/kg） caused the most apparent changes in nifH gene diversity at the first week while the high concentration of methamidophos （250 mg/kg） produced prominent effects on nifH gene diversity in the following weeks. Cluster analysis showed that minimal changes of nifH gene composition were found at 1 week and maximal changes at 4 weeks. Toxic effects of acetochlor and methamidophos combination on nifH gene were also apparent. Different nifH genes （bands） responded differently to the impact of agrochemicals： four individual bands were eliminated by the application of the agrochemicals, five bands became predominant by the stimulation of the agrochemicals, and four bands showed strong resistance to the influence of the agrochemicals. Fifteen prominent bands were partially sequenced, yielding 15 different nifH sequences, which were used for phylogenetic reconstructions. All sequences were affiliated with the alpha- and beta-proteobacteria, showing higher similarity to eight different diazotrophic genera.     

Arsenic uptake by arbuscular mycorrhizal maize （Zea mays L.） grown in an arsenic-contaminated soil with added phosphorus

The effects of arbuscular mycorrhizal (AM) fungus (Glomus mosseae) and phosphorus (P) addition (100 mg/kg soil) on arsenic (As) uptake by maize plants (Zea mays L.) from an As-contaminated soil were examined in a glasshouse experiment.Non-mycorrhizal and zero-P addition controls were included.Plant biomass and concentrations and uptake of As,P,and other nutrients,AM colonization,root lengths,and hyphal length densities were determined.The results indicated that addition of P significantly inhibited root colonization and development of extraradical mycelium.Root length and dry weight both increased markedly with mycorrhizal colonization under the zero-P treatments,but shoot and root biomass of AM plants was depressed by P application.AM fungal inoculation decreased shoot As concentrations when no P was added,and shoot and root As concentrations of AM plants increased 2.6 and 1.4 times with P addition,respectively.Shoot and root uptake of P,Mn,Cu,and Zn increased,but shoot Fe uptake decreased by 44.6%,with inoculation, when P was added.P addition reduced shoot P,Fe,Mn,Cu,and Zn uptake of AM plants,but increased root Fe and Mn uptake of the nonmycorrhizal ones.AM colonization therefore appeared to enhance plant tolerance to As in low P soil,and have some potential for the phytostabilization of As-contaminated soil,however,P application may introduce additional environmental risk by increasing soil As mobility.     

Degradation of metabolites accumulated of benzo[a]pyrene by coupling Penicillium Chrysogenum with KMnO4

Several main metabolites of benzo[a]pyrene （BaP） formed by Penicillium chrysogenum, Benzo[a]pyrene-1,6-quinone （BP 1,6- quinone）, trans-7,8-dihydroxy-7,8-dihydrobenzo[a]pyrene （BP 7,8-diol）, 3-hydroxybenzo[a]pyrene （3-OHBP）, were identified by high-performance liquid chromatography （HPLC）. The three metabolites were liable to be accumulated and were hardly further metabolized because of their toxicity to microorganisms. However, their further degradation was essential for the complete degradation of BaP. To enhance their degradation, two methods, degradation by coupling Penicillium chrysogenum with KMnO4 and degradation only by Penicillium chrysogenum, were compared; Meanwhile, the parameters of degradation in the superior method were optimized. The results showed that （1） the method of coupling Penicillium chrysogenum with KMnO4 was better and was the first method to be used in the degradation of BaP and its metabolites; （2） the metabolite, BP 1,6-quinone was the most liable to be accumulated in pure cultures; （3） the effect of degradation was the best when the concentration of KMnO4 in the cultures was 0.01% （w/v）, concentration of the three compounds was 5 mg/L and pH was 6.2. Based on the experimental results, a novel concept with regard to the bioremediation of BaP-contaminated environment was discussed, considering the influence on environmental toxicity of the accumulated metabolites.     

Impact of atrazine and nitrogen fertilizers on the sorption of chlorotoluron in soil and model sorbents

Sorption of chlorotoluron in ammonium sulfate, urea and atrazine multi-solutes system was investigated by batch experiments. The results showed application of nitrogen fertilizers to the soil could affect the behavior of chlorotoluron. At the same concentration of N, sorption of chlorotoluron decreased as the concentration of atrazine increased on the day 0 and 6 in soil, respectively. The sorption of chlorotoluron increased from 0 to 6 d when soils were preincubated with deionized water, ammonium sulfate and urea solution for 6 d. That indicated incubation time was one of the most important factors for the sorption of chlorotoluron in nitrogen fertilizers treatments. The individual sorption isotherms of chlorotoluron in rubbery polymer and silica were strictly linear in single solute system, but there were competition sorption between pesticides or between pesticides and nitrogen fertilizers. That indicated the sorption taken place by concurrent solid-phase dissolution mechanism and sorption on the interface of water-organic matter or water-mineral matter.     

Distribution and ecological effect of mercury in Laogang landfill, Shanghai, China

Laogang landfill near Shanghai is the largest landfill in China, and receives about 10000 t of daily garbage per day, Samples of topsoil and plants were analyzed to evaluate mercury pollution from the landfill. For topsoil samples, there were significant correlations among total mercury （HgT）, combinative mercury （Hgc） and gaseous mercury （HgG）, and content of total organic carbon （TOC）, but, no significantly relationship was found between Hg content and filling time. Hg content changes in vertical profiles with time showed that the average Hgv of profiles 1992, 1996, and 2000 was similar, but their average HgG was quite different. HgT was significantly correlated with Hgc in profile 1992 and 2000, and Hgv was significantly correlated with Hg6 in profile 1996. HgG/Hgv ratio in profile samples decreased in the order of （HgG,/HgT）1992〉（HgG/HgT）1996〉〉（HgG/HgT）2000. A simple outline of Hg release in landfill could be drawn： with increasing of filling time, degradation undergoes different biodegradation, accordingly, gaseous mercury goes through small, more, and small proportion to total mercury. Distribution of Hg in plants was inhomogeneous, following the order of leaf〉root〉stem. The highest value of leaf may be associated with higher atmospheric Hg from landfill. Ligneous plants （e.g. Phyllostachys glanca, Prunus salicina and Ligustrum lucidum） are capable of enriching more Hg than herbaceous plants.     

EDTA-enhanced phytoremediation of lead contaminated soil by Bidens maximowicziana

Phytoremediation is a potential cleanup technology for the removal of heavy metals from contaminated soils.Bidens maximowicziana is a new Pb hyperaccumulator,which not only has remarkable tolerance to Pb but also extraordinary accumulation capacity for Pb.The maximum Pb concentration was 1509.3 mg/kg in roots and 2164.7 mg/kg in overground tissues.The Pb distribution order in the B. maximowicziana was:leaf>stem>root.The effect of amendments on phytoremediation was also studied.The mobility of soil Pb and the Pb concentrations in plants were both increased by EDTA application.Compared with CK(control check),EDTA application promoted translocation of Pb to overground parts of the plant.The Pb concentrations in overground parts of plants was increased from 24.23-680.56 mg/kg to 29.07-1905.57 mg/kg.This research demonstrated that B.maximowicziana appeared to be suitable for phytoremediation of Pb contaminated soil,especially,combination with EDTA.     

Decomposition of alachlor by ozonation and its mechanism

Decomposition and corresponding mechanism of alachlor, an endocrine disruptor in water by ozonation were investigated. Results showed that alachlor could not be completely mineralized by ozone alone. Many intermediates and final products were formed during the process, including aromatic compounds, aliphatic carboxylic acids, and inorganic ions. In evoluting these products, some of them with weak polarity were qualitatively identified by GC-MS. The information of inorganic ions suggested that the dechlorination was the first and the fastest step in the ozonation of alachlor.     

Enzymatic oxidation of aqueous pentachlorophenol

The influence of the nonionic surfactant Tween 80 on pentachlorophenol （PCP） oxidation catalyzed by horseradish peroxidase was studied. The surfactant was tested at concentrations below and above its critical micelle concentration （CMC）. Enhancement of PCP removal was observed at sub-CMCs. The presence of Tween 80 in the reaction mixture reduced enzyme inactivation which occurred through a combination of free radical attack and sorption by precipitated products. A simple first-order model was able to simulate time profiles for enzyme inactivation in the presence or absence of Tween 80. At supra-CMCs, the surfactant caused noticeable reductions in PCP removal, presumably through micelle partitioning of PCP which precluded the hydrophobic PCP molecule from interacting with the enzyme.