Cathode ray tube recycling

Lead and polybrominated flame retardants are the two hazardous materials that can be found in electronic appliances. Particularly, cathode ray tubes (CRT) contain leaded glasses. In a computer monitor, over 98% of the lead is in the CRT. This material is generally not accepted for reuse as a component; only those from televisions can be reused. However, this currently represents only a very small market. Envirocycle (a US company) has developed a process to recycle all glasses contained in CRTs; this process includes cleaning and sorting glass. The product obtained is used for the manufacture of new CRT glass. Some industries have used pulverized glass from CRTs in smelting processes as slagging material instead of sand or slag. In this paper, some environmental issues related to the recycling of computers and television sets, and CRTs from computers are presented and discussed. Different processes used to recycle CRTs are described along with an economic analysis.     

A review on the use of waste glasses in the production of cement and concrete

The use of recycled waste glasses in Portland cement and concrete has attracted a lot of interest worldwide due to the increased disposal costs and environmental concerns. Being amorphous and containing relatively large quantities of silicon and calcium, glass is, in theory, pozzolanic or even cementitious in nature when it is finely ground. Thus, it can be used as a cement replacement in Portland cement concrete. The use of crushed glasses as aggregates for Portland cement concrete does have some negative effect on properties of the concrete; however, practicle applicability can still be produced even using 100% crushed glass as aggregates. The main concerns for the use of crushed glasses as aggregates for Portland cement concrete is the expansion and cracking caused by the glass aggregates. This paper summarizes the progresses and points out the directions for the proper uses of waste glasses in Portland cement and concrete.     

Natural materials for treatment of industrial effluents: comparative study of the retention of Cd, Zn and Co by calcite and hydroxyapatite. Part I: batch experiments

This work explores the heavy metal retention capacity of materials developed from minerals that are abundant in nature, with low cost and minimum environmental impact. To accomplish this objective we have: (a) characterized commercial samples of calcite (CA) and hydroxyapatite (HAP)--including their surface properties (BET area, electrophoretic mobility, SEM, and X-ray energy dispersive spectroscopy); and, (b) qualified and quantified the interaction of Cd, Zn and Co with calcite (CaCO3) and hydroxyapatite [Ca5(PO4)3OH] through batch experiments, in a range of metal concentrations (4Zn>Co and Cd>Zn approximately Co, respectively. Retention increased with pCa and pH and could be modeled by: (a) a non-ideal ion exchange mechanism (Me/Ca) for the adsorption of Cd, Zn and Co onto CA; and, (b) a mechanism of non-ideal ion exchange and specific adsorption (Me/Ca and identical with PO4O-Me) in the case of HAP. The pH dependence is indirect in CA and is related to its solubility changes (pCa increases with pH, and so does sorption of Cd, Zn and Co). Both materials, HAP and CA, can be used for heavy metal retention. The former has better performance for water treatment due to its greater efficiency for the retention of Cd, Zn and Co (over two orders of magnitude per gram of material) and its lower solubility in a wide range of pH (6相似文献   

污染底泥掩蔽材料筛选综述

随着经济的高速发展,水体底泥污染已成为世界性的一个环境问题。掩蔽修复是一种修复效果明显,且工程造价较低的水体底泥修复技术,而掩蔽技术的关键在于掩蔽材料的选择。本文主要介绍了水泥、粉煤灰、沸石、方解石、铝盐等研究较为成熟的且具有应用前景的掩蔽材料,分析其各自的原理及优缺点。同时作者在文章中提出了一种新的掩蔽剂——净水厂改性污泥,对其的可行性进行了分析。并就掩蔽材料的选择的技术要求以及原则作出分析。     

An Evaluation of Several In-Lake Restoration Techniques to Improve the Water Quality Problem (Eutrophication) of Saint-Augustin Lake,Quebec, Canada

Increasing phosphorus (P) content and decreasing water quality of Saint-Augustin Lake, Quebec City, Canada, has led to implementation of an Integrated Watershed Management Plan to restore the lake. As a part of the plan, the effects of different restoration techniques on lake water quality and biological community (i.e., biological compatibility) were assessed during an isolated water enclosure study and laboratory microcosm assay, respectively. The restoration techniques include: (i) coagulation of P by alum only (20 mg L⁻¹), (ii) active capping of sediments using a calcite layer of 10 cm, and (iii) a complete method involving both alum coagulation and calcite capping. The results showed that the total P (TP) was greatly decreased (76–95 %) by alum + calcite, followed by calcite only (59–84 %). Secchi depth was 106 % greater and chlorophyll a concentrations were declined by 19–78 % in the enclosure which received both alum and calcite. Results of the biological compatibility test showed that total phytoplankton biomass declined by 31 % in microcosms composed of alum + calcite. No significant (P > 0.05) toxic effect was found on the survival of Daphnia magna and Hyalella azteca in both alum only and alum + calcite microcosms. Although the alum + calcite technique impaired the survival of Chironomus riparius, the midge emergence was much higher compared to alum only and control. Overall, the alum + calcite application was effective in controlling P release from sediment and lowering water column P concentrations, and thus improving the water quality and aquatic life of Saint-Augustin Lake. However, the TP concentrations are still higher than the critical limit (20 μg L⁻¹) for aquatic life and the water column remained in the eutrophic state even after treatment. Increased TP concentrations, to higher than ambient levels of the lake, in the water column of all four enclosures, due to bioturbation artefact triggered by the platform installation, likely cause insufficient dosages of alum and/or calcite applied and reduced their effectiveness.     

Quantitative,chemical, and mineralogical characterization of flue gas desulfurization by-products

The objective of this study was to demonstrate that simple fractionation and selective dissolution techniques can be used to provide detailed chemical and mineralogical analyses of flue gas desulfurization by-products. The material studied was a mine grout prepared as a 1:1 mixture (wt./wt.) of fly ash (FA) and filter cake (FC) with hydrated lime (50 g kg(-1)) added to improve handling. The hydrated lime was composed mostly of calcite (CaCO3), portlandite [Ca(OH)2], lime (CaO), and brucite [Mg(OH)2] (515, 321, 55, and 35 g kg(-1), respectively) and had low (<6 g kg(-1)) concentrations of most trace elements. The FC contained hannebachite (CaSO3 x 0.5H2O) (786 g kg(-1)) with smaller quantities (<10 g kg(-1)) of calcite, quartz (SiO2), brucite, and gypsum (CaSO4 x 2H2O). Except for B and Cu, trace element concentrations were comparable to those in the hydrated lime. The FA contained both magnetic (222 g kg(-1)) and nonmagnetic (778 g kg(-1)) fractions. The former was composed mostly of hematite (Fe2O3), magnetite (Fe3O4), and glass (272, 293, and 287 g kg(-1), respectively), whereas the latter was enriched in glass, quartz, and mullite (Al6Si2O13) (515, 243, and 140 g kg(-1), respectively). Etching with 1% HF showed that 60 to 100% of trace elements were concentrated in the glass, although some metals (Co, Cr, and Mn) were clearly enriched in the magnetic phase. The aged grout contained 147 g kg(-1) ettringite [Ca6Al2(SO4)3(OH)12 x 26H2O] in addition to 314 g kg(-1) hannebachite and 537 g kg(-1) insoluble phases (mullite, quartz, hematite, magnetite, and glass).     

高性能水刺玻纤复合滤料性能的研究

通过实验对比水刺类与针刺类玻纤复合滤料的机械性能、过滤性能，阐述了针刺玻纤复合滤料存在的缺陷及水刺玻纤复合滤料的技术优势。     

贵阳城市污水处理厂污泥生产轻质陶粒的研究

贵阳市小河污水处理厂以机械脱水污泥为原料，配以页岩、少量锯末及玻璃粉，摸拟贵州坤泰建材工贸有限公司粘土陶粒厂生产工艺，经练泥搅拌、挤压成球、预热焙烧（焙烧温度1050℃并保温30min）等各生产工序，成功生产出不同密度等级的普通轻质陶粒。     

Passive treatment of acid mine drainage with high metal concentrations using dispersed alkaline substrate

Passive treatment systems based on the dissolution of coarse calcite grains are widely used to remediate acid mine drainage (AMD). Unfortunately, they tolerate only low metal concentrations or acidity loads, because they are prone to passivation (loss of reactivity due to coating) and/or clogging (loss of permeability) by precipitates. To overcome these problems, a dispersed alkaline substrate (DAS) composed of a fine-grained alkaline reagent (calcite sand) mixed with a coarse inert matrix (wood chips) was developed. The small grains provide a large reactive surface and dissolve almost completely before the growing layer of precipitates passivates the substrate, whereas the dispersion of nuclei for precipitation on the inert surfaces retards clogging. Chemical and hydraulic performance of DAS was investigated in two laboratory columns fed at different flow rates with natural AMD of pH 2.3 to 3.5 and inflow net acidity 1350 to 2300 mg/L as CaCO(3). The DAS columns removed 900 to 1600 mg/L net acidity, 3 to 4.5 times more than conventional passive treatment systems. Regardless of the flow rate employed, Al, Fe(III), Cu, and Pb were virtually eliminated. Minor Zn, Ni, and Cd were removed at low flow rates. High acidity removal is possible because these metals accumulate intentionally in DAS, and their precipitation promotes further calcite dissolution. During 15 mo, DAS operated without clogging at 120 g acidity/m(2).d, four times the loading rate recommended for conventional passive systems; DAS may therefore be capable of treating AMD at sites where influent chemistry precludes the use of other passive systems.     

Packaging glass contained in the heavy residual fraction refused by Portuguese Mechanical and Biological Treatment plants

Mechanical and Biological Treatment (MBT) is an important strategy to manage Municipal Solid Waste (MSW) in Europe. The presence of recyclable materials on MSW depends on different factors such as inefficiencies in the Municipal Solid Waste collecting schemes and to the low level of citizenship environmental education. Among other products, MBT plants produce a residual fraction, named here as heavy residual fraction, that contains a significant amount of packaging glass which in Portugal is currently landfilled. This material is not recycled because it is heavily contaminated with other materials, preventing its processing in Material Recovery Facilities (MRF).In this paper the characterization, including particle size and composition, of the residual fraction of six Portuguese MBT plants is presented. The relevant variables that determine the heavy residual fraction characteristics were identified. It was observed that the MBTr particle size distribution is different and depends mainly on the place on the flowsheet where the MBTr exits the process, which is determined by the type of biological process and by the aperture of the last screen where the product passes through. The content in glass varies from 33 to 83%. These values are mainly related with the upstream glass sorting and with the efficiency of the recovery of the organic fraction which is the glass main contaminant. The second main contaminant is “stones”.The quantity of glass contained in this product in all the plants that will be in operation in Portugal in 2014 was estimated. The work shows that if all the 48,000 of glass could be recovered the Portuguese recycling rate would increase by 4.4%.     

聚酰胺及其改性材料自然老化行为研究及预测

在自然环境(武汉)下进行了两年半的老化曝晒实验,随着老化时间的增长,聚酰胺材料的吸水率逐渐增加,力学性能下降,表面出现了不同程度的裂纹.通过吸水率测试和力学性能的比较,发现环境湿度影响聚酰胺老化过程中力学性能变化,湿度越大,材料力学性能下降越快;改性后,即添加了玻璃纤维后的聚酰胺,能够在一定程度下减缓材料老化行为.对材...     

Some barriers to the use of materials recovered from municipal solid waste

Municipal solid waste (MSW) contains materials which could be put to good use, yet it continues to be discarded, which suggests that it contains little or nothing of value under current conditions. This paper discusses the technical reasons for the lack of commercial interest in recovering materials from MSW. After examining the nature of the salvage industry and trends in the use of materials, the paper considers the characteristics of secondary materials, the properties required of them, and the scope for increased salvage activity. The market prospects are described for waste paper, ferrous and non- ferrous scrap, glass and polymers.     

The raw material supply of the European Community : The importance of secondary raw materials

The availability and security of raw materials supply have taken on a new political dimension within the last few years. These issues influence the economic and political rank of nations, affecting their independence, their standards of living and the competitive position of their industries. The importance of raw materials supply will continue to grow, for both the developed industrial and the developing countries. The European Community depends on external sources for 50–100% of most of its raw materials. Although the degree of dependence varies considerably from commodity to commodity, sources are not diversified enough to guarantee supply. Yet 1700–2000 million tons of waste are generated annually in the Community, containing substances of potential value—including metals, glass, rubber, textiles, oil, plastics—of which 70– 80% are tipped. This represents a loss of materials as far as they could be reused economically. This article argues that efforts should be made to recover and reuse the maximum possible of these resources to reduce the Community's dependence on, and improve its security of, raw materials supplies, and to lower the balance of payments burden.     

重点污染源PM_(2.5)防控技术的经济性探讨

论述了除尘设备滤料的发展及合理使用的重要性,指出重点行业采用PM2.5污染防治技术,要进行科学对比,择优选用高性能的滤料及经济节约型的过滤除尘系统;通过应用实例,介绍了机械振打玻纤扁袋式除尘器的应用效果。     

Photocatalytic activity of titanium dioxide modified concrete materials – Influence of utilizing recycled glass cullets as aggregates

Combining the use of photocatalysts with cementitious materials is an important development in the field of photocatalytic air pollution mitigation. This paper presents the results of a systematic study on assessing the effectiveness of pollutant degradation by concrete surface layers that incorporate a photocatalytic material – Titanium Dioxide. The photocatalytic activity of the concrete samples was determined by photocatalytic oxidation of nitric oxide (NO) in the laboratory. Recycled glass cullets, derived from crushed waste beverage bottles, were used to replace sand in preparing the concrete surface layers. Factors, which may affect the pollutant removal performance of the concrete layers including glass color, aggregate size and curing age, were investigated. The results show a significant enhancement of the photocatalytic activity due to the use of glass cullets as aggregates in the concrete layers. The samples fabricated with clear glass cullets exhibited threefold NO removal efficiency compared to the samples fabricated with river sand. The light transmittance property of glass was postulated to account for the efficiency improvement, which was confirmed by a separate simulation study. But the influence of the size of glass cullets was not evident. In addition, the photocatalytic activity of concrete surface layers decreased with curing age, showing a loss of 20% photocatalytic activity after 56-day curing.     

Engineering properties of asphalt concrete made with recycled glass

Taiwan is an island nation with high population density: 23 million people living in a total land area of 30 000 sq. km. The island has transformed from an agricultural society to an industrial one in the past three decades. Coming with the transformation is a cumulated waste problem. Taiwan produces nearly 5 million tons of waste each year, of which 10% is of glass materials. Bureau of Highway Department funded a research program to investigate ways of recycling the glass waste. This report presents information on the program and laboratory/field test data. Materials used in the test program included 85/100 asphalt, Type II modified asphalt, and treated glass waste. Four glass contents: 0, 5, 10, and 15%, in terms of the total aggregate weight, were used in the mixture designs for casting series of 10 cm diameter by 6.35 cm disk specimens. Tests including Marshall stability value, dry/wet moisture damage, skid resistance, light reflection, water permeability, and compaction were carried out in accordance with the ASTM and AASHTO procedures. The test results reveal that glass waste is a viable material for asphalt concrete that has been widely used in pavement that offers profound engineering and economic advantages.     

新型玻纤／P84复合针刺毡的开发及应用

阐述了玻纤／P84复合毡过滤材料的研制过程、技术方法、使用效果及其应用。玻纤／P84复合针刺毡既要满足高性能、低成本的生产要求，还要适应不断提高的环保要求及复杂工况的要求。     

建筑废弃物再生利用的可行性技术研究综述

建材行业的发展为城市化建设提供了重要保障,在我国城市化快速发展、建筑材料需求旺盛的带动下,建材行业发展强劲,但大多属于高能耗高污染行业,加之城市拆迁改造产生大量建筑废弃物,环境压力十分巨大,必须加强建筑废弃物的环境管理。对建筑废弃物再利用、再循环以及减少建筑废弃物是解决建筑行业环境问题的重要方式,实施这些仍有很大的提升空间。本文回顾了近年来建筑废弃物再生利用方面的各种可行性技术。主要是针对沥青、砖、混凝土、金属、玻璃等几种物质再生利用的可行性技术进行综述,为未来建筑废弃物再生利用领域提供参考。     

Adsorption of carbon dioxide on alkali-modified zeolite 13X adsorbents

Shaped zeolite 13X adsorbent with kaolin as binder was hydrothermally modified in sodium hydroxide solution to improve its adsorption performance. The characterization of the product by XRD, N₂ adsorption–desorption and water vapour adsorption displayed that kaolin component in zeolite adsorbent can be converted into zeolite during the alkali treatment, resulting in the modified adsorbent consisting entirely of effectual adsorption composition. Compared with the unmodified adsorbent, the modified adsorbent exhibited higher adsorption capacity and uptake rate for carbon dioxide, because of the increase of effective adsorption surface and the decrease of diffusion resistance owing to conversion of kaolin binder into zeolite. The model parameters of isotherms and the isosteric heats calculated by the Clausius–Clapeyron equation for CO₂ adsorption showed the stronger interaction of adsorbate–adsorbent and the higher degree of heterogeneity of adsorption centers in modified than unmodified adsorbents.     

Electronic waste recycling: A review of U.S. infrastructure and technology options

The useful life of consumer electronic devices is relatively short, and decreasing as a result of rapid changes in equipment features and capabilities. This creates a large waste stream of obsolete electronic equipment, electronic waste (e-waste).Even though there are conventional disposal methods for e-waste, these methods have disadvantages from both the economic and environmental viewpoints. As a result, new e-waste management options need to be considered, for example, recycling. But electronic recycling has a short history, so there is not yet a solid infrastructure in place.In this paper, the first half describes trends in the amount of e-waste, existing recycling programs, and collection methods. The second half describes various methods available to recover materials from e-waste. In particular, various recycling technologies for the glass, plastics, and metals found in e-waste are discussed. For glass, glass-to-glass recycling and glass-to-lead recycling technologies are presented. For plastics, chemical (feedstock) recycling, mechanical recycling, and thermal recycling methods are analyzed. Recovery processes for copper, lead, and precious metals such as silver, gold, platinum, and palladium are reviewed. These processes are described and compared on the basis of available technologies, resources, and material input–output systems.