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The use of computational fluid dynamics (CFD) models to simulate LNG vapor dispersion scenarios has been growing steadily over the last few years, with applications to LNG spills on land as well as on water. Before a CFD model may be used to predict the vapor dispersion hazard distances for a hypothetical LNG spill scenario, it is necessary for the model to be validated with respect to relevant experimental data. As part of a joint-industry project aimed at validating the CFD methodology, the LNG vapor source term, including the turbulence level associated with the evaporation process vapors was quantified for one of the Falcon tests.This paper presents the method that was used to quantify the turbulent intensity of evaporating LNG, by analyzing the video images of one of the Falcon tests, which involved LNG spills onto a water pond. The measured rate of LNG pool growth and spreading and the quantified turbulence intensity that were obtained from the image analysis were used as the LNG vapor source term in the CFD model to simulate the Falcon-1 LNG spill test. Several CFD simulations were performed, using a vaporization flux of 0.127 kg/m2 s, radial and outward spreading velocities of 1.53 and 0.55 m/s respectively, and a range of turbulence kinetic energy values between 2.9 and 28.8 m2/s2. The resulting growth and spread of the vapor cloud within the impounded area and outside of it were found to match the observed behavior and the experimental measured data.The results of the analysis presented in this paper demonstrate that a detailed and accurate definition of the LNG vapor source term is critical in order for any vapor cloud dispersion simulation to provide useful and reliable results.  相似文献   

3.
Deflagration explosions of coal dust clouds and flammable gases are a major safety concern in coal mining industry. Accidental fire and explosion caused by coal dust cloud can impose substantial losses and damages to people and properties in underground coal mines. Hybrid mixtures of methane and coal dust have the potential to reduce the minimum activation energy of a combustion reaction. In this study the Minimum Explosion Concentration (MEC), Over Pressure Rise (OPR), deflagration index for gas and dust hybrid mixtures (Kst) and explosive region of hybrid fuel mixtures present in Ventilation Air Methane (VAM) were investigated. Experiments were carried out according to the ASTM E1226-12 guideline utilising a 20 L spherical shape apparatus specifically designed for this purpose.Resultsobtained from this study have shown that the presence of methane significantly affects explosion characteristics of coal dust clouds. Dilute concentrations of methane, 0.75–1.25%, resulted in coal dust clouds OPR increasing from 0.3 bar to 2.2 bar and boosting the Kst value from 10 bar m s−1 to 25 bar m s−1. The explosion characteristics were also affected by the ignitors’ energy; for instance, for a coal dust cloud concentration of 50 g m−3 the OPR recorded was 0.09 bar when a 1 kJ chemical ignitor was used, while, 0.75 bar (OPR) was recorded when a 10 kJ chemical ignitor was used.For the first time, new explosion regions were identified for diluted methane-coal dust cloud mixtures when using 1, 5 and 10 kJ ignitors. Finally, the Le-Chatelier mixing rule was modified to predict the lower explosion limit of methane-coal dust cloud hybrid mixtures considering the energy of the ignitors.  相似文献   

4.
A series of medium-scale experiments on vented hydrogen deflagration was carried out at the KIT test side in a chamber of 1 × 1 × 1 m3 size with different vent areas. The experimental program was divided in three series: (1) uniform hydrogen–air mixtures; (2) stratified hydrogen–air mixtures within the enclosure; (3) a layer deflagration of uniform mixture. Different uniform hydrogen–air mixtures from 7 to 18% hydrogen were tested with variable vent areas 0.01–1.0 m2. One test was done for rich mixture with 50% H2. To vary a gradient of concentration, all the experiments with a stratified hydrogen–air mixtures had about 4%H2 at the bottom and 10 to 25% H2 at the top of the enclosure. Measurement system consisted of a set of pressure sensors and thermocouples inside and outside the enclosure. Four cameras combined with a schlieren system (BOS) for visual observation of combustion process through transparent sidewalls were used. Four experiments were selected as benchmark experiments to compare them with four times larger scale FM Global tests (Bauwens et al., 2011) and to provide experimental data for further CFD modelling. The nature of external explosion leading to the multiple pressure peak structure was investigated in details. Current work addresses knowledge gaps regarding indoor hydrogen accumulations and vented deflagrations. The experiments carried out within this work attend to contribute the data for improved criteria for hydrogen–air mixture and enclosure parameters to avoid unacceptable explosion overpressure. Based on theoretical analysis and current experimental data a further vent sizing technology for hydrogen deflagrations in confined spaces should be developed, taking into account the peculiarities of hydrogen–air mixture deflagrations in presence of obstacles, concentration gradients of hydrogen–air mixtures, dimensions of a layer of flammable cloud, vent inertia, etc.  相似文献   

5.
CFD-based simulation of dense gas dispersion in presence of obstacles   总被引:1,自引:0,他引:1  
Quantification of spatial and temporal concentration profiles of vapor clouds resulting from accidental loss of containment of toxic and/or flammable substances is of great importance as correct prediction of spatial and temporal profiles can not only help in designing mitigation/prevention equipment such as gas detection alarms and shutdown procedures but also help decide on modifications that may help prevent any escalation of the event.The most commonly used models - SLAB (Ermak, 1990), HEGADAS (Colenbrander, 1980), DEGADIS (Spicer & Havens, 1989), HGSYSTEM (Witlox & McFarlane, 1994), PHAST (DNV, 2007), ALOHA (EPA & NOAA, 2007), SCIPUFF (Sykes, Parker, Henn, & Chowdhury, 2007), TRACE (SAFER Systems, 2009), etc. - for simulation of dense gas dispersion consider the dispersion over a flat featureless plain and are unable to consider the effect of presence of obstacles in the path of dispersing medium. In this context, computational fluid dynamics (CFD) has been recognized as a potent tool for realistic estimation of consequence of accidental loss of containment because of its ability to take into account the effect of complex terrain and obstacles present in the path of dispersing fluid.The key to a successful application of CFD in dispersion simulation lies in the accuracy with which the effect of turbulence generated due to the presence of obstacles is assessed. Hence a correct choice of the most appropriate turbulence model is crucial to a successful implementation of CFD in the modeling and simulation of dispersion of toxic and/or flammable substances.In this paper an attempt has been made to employ CFD in the assessment of heavy gas dispersion in presence of obstacles. For this purpose several turbulence models were studied for simulating the experiments conducted earlier by Health and Safety Executive, (HSE) U.K. at Thorney Island, USA (Lees, 2005). From the various experiments done at that time, the findings of Trial 26 have been used by us to see which turbulence model enables the best fit of the CFD simulation with the actual findings. It is found that the realizable k-? model was the most apt and enabled the closest prediction of the actual findings in terms of spatial and temporal concentration profiles. It was also able to capture the phenomenon of gravity slumping associated with dense gas dispersion.  相似文献   

6.
A dispersion of fine particles in the air is needed for a dust explosion to occur since an explosion is the fast combustion of particles in the air. When particles are poorly dispersed, agglomerated, or their concentration is low, the combustion velocity decreases, and deflagration would not occur. The combustion rate is strictly related to dust concentration. Therefore, the maximum explosion pressure rise occurs at dust concentration close to stoichiometric. Conversely, Minimum Explosion Concentration (MEC) is the lower limit at which self-sustained combustion and a pressure rise are possible. Dust explosion tests are designed to reproduce the dispersion and generation of dust clouds in industrial ambiences by using dispersion devices activated by pressurised air pulses. The resulting dust cloud, which has a marked transient character, is considered representative of real clouds by current standards. Over time, several studies have been carried out to optimise these devices (e.g. to reduce the inhomogeneity of the cloud in the 20 L sphere). The Minimum Ignition Energy (MIE) of dust is measured using the Mike3 modified Hartmann tube, where the ignition attempt is made 60–180 ms after dust dispersion regardless of dust characteristics.This work investigates the dust clouds’ actual behaviour inside the modified Hartmann tube before ignition using high-velocity video movies and a new image post-treatment method called Image Subtraction Method (ISM). Movies are recorded with high-speed cameras at a framerate of 2000 fps and elaborated with an on-purpose developed LabVIEW® code. Concentration (mass per volume) and dispersion pressure are varied to evaluate their effect on dust clouds. Maise starch, iron powder and silica powder are chosen to investigate the effect of particle density and size on the cloud structure and turbulence. This approach will help to investigate the structure of the dust cloud, the shape and size of the particle lumps and the change in dust concentration over time. In addition, information on the actual concentration and cloud turbulence at the ignition location and delay time were obtained, which may help identify the local turbulence scale and widen the characterisation of the cloud generated in the Hartmann tube.  相似文献   

7.
The majority of experimental tests done on combustible dusts are performed in constant volume vessels that have limited or no optical access. Over the years, McGill University has been developing alternative experimental techniques based on direct observation of dust flames, yielding reliable fundamental parameters such as flame burning velocity, temperature and structure. The present work describes two new experimental set-ups allowing direct observation of isobaric and freely propagating dust flames at two sufficiently different scales to test the influence of scale on dust flame phenomena. In the laboratory-scale experiments, a few grams of aluminum powder are dispersed in transparent, 30 cm diameter latex balloons that allow for full visualization of the spherical flame propagation. In the field experiments, about 1 kg of aluminum powder is dispersed by a short pulse of air, forming a conical dust cloud with a total volume of about 5 m3. High-speed digital imaging is used to record the particle dispersal and flame propagation in both configurations. In the small-scale laboratory tests, the measured flame speed is found to be about 2.0 ± 0.2 m/s in fuel-rich aluminium clouds. The burning velocity, calculated by dividing the measured flame speed by the expansion factor deduced from thermodynamic equilibrium calculations, correlates well with the previously measured burning velocity of about 22–24 cm/s from Bunsen dust flames. Flame speeds observed in field experiments with large-scale clouds, however, are found to be much higher, in the range of 12 ± 2 m/s. Estimations are presented that show that the presumably greater role of radiative heat transfer in larger-scale aluminium flames is insufficient to explain the six-fold increase in flame speed. The role of residual large-eddy turbulence, as well as the frozen-turbulence effect leading to large-scale dust concentration fluctuations that cause flame folding, are discussed as two possible sources for the greater flame speed.  相似文献   

8.
A dispersion model validation study is presented for atmospheric releases of dense-phase carbon dioxide (CO2). Predictions from an integral model and two different Computational Fluid Dynamics (CFD) models are compared to data from field-scale experiments conducted by INERIS, as part of the EU-funded CO2PipeHaz project.The experiments studied consist of a 2 m3 vessel fitted with a short pipe, from which CO2 was discharged into the atmosphere through either a 6 mm or 25 mm diameter orifice. Comparisons are made to measured temperatures and concentrations in the multi-phase CO2 jets.The integral dispersion model tested is DNV Phast and the two CFD models are ANSYS-CFX and a research and development version of FLACS, both of which adopt a Lagrangian particle-tracking approach to simulate the sublimating solid CO2 particles in the jet. Source conditions for the CFD models are taken from a sophisticated near-field CFD model developed by the University of Leeds that simulates the multi-phase, compressible flow in the expansion region of the CO2 jet, close to the orifice.Overall, the predicted concentrations from the various models are found to be in reasonable agreement with the measurements, but generally in poorer agreement than has been reported previously for similar dispersion models in other dense-phase CO2 release experiments. The ANSYS-CFX model is shown to be sensitive to the way in which the source conditions are prescribed, while FLACS shows some sensitivity to the solid CO2 particle size. Difficulties in interpreting the results from one of the tests, which featured some time-varying phenomena, are also discussed.The study provides useful insight into the coupling of near- and far-field dispersion models, and the strengths and weaknesses of different modelling approaches. These findings contribute to the assessment of potential hazards presented by Carbon Capture and Storage (CCS) infrastructure.  相似文献   

9.
Two-phase CFD (Computational Fluid Dynamics) model for characterising the spill-over/dispersion of peroxy-fuels is presented. The model is independent of type and burning rate of the spilled/dispersed fuel and considers only overflow Reynolds number (Re) to characterise the spill/dispersion behaviour. Additional simulations are performed for LNG (Liquified Natural Gas) dispersion and it is found that the model can be used for different fuels within a defined range of Re. Different scenarios with Re = 100 to 3 × 105 are investigated covering a wide range of mass flow rates, opening sizes and viscosities. Depending on Lower Flammability Limits (LFL) of the fuels spill/dispersion (vapour cloud) diameters (DCFD) and heights (hCFD) are predicted. A generalised correlation between DCFD and Re is established to predict the dispersion occurring at varying scales. The model is validated by: (1) conducting an extensive grid independent study; (2) comparing the results with the existing analytical methods and (3) comparing against the standard field test data on LNG dispersions.  相似文献   

10.
In order to better assess the hazards of explosion accidents, propane-air mixture deflagrations were conducted in a large-scale straight rectangular chamber (with a cross-section of 1.5 m × 1.5 m, length of 10 m, and total volume of 22.5 m3). The effect of initial volume, ignition position, and initial restraints on the explosion characteristics of the propane-air mixtures was investigated. The explosion overpressure, flame propagation, and flame speed were obtained and the computational fluid dynamics (CFD) software was used to simulate the flame-propagation process and field flow for auxiliary analysis. The hazards of large-scale propagation explosion under weak and strong constraints were evaluated and the different phases of flame propagation under weak and strong constraints were discriminated. Results indicate that the hazards caused by propane deflagration under weak constraint are mainly caused by flame spread. And the maximum overpressure under strong constraint appeared at the front part of the chamber under the large-scale condition, which is consistent with the previous small-scale test. Moreover, the simulations of flame structures under weak and strong constraint are in good agreement with experimental results, which furthers the understanding of large-scale propane deflagration under different initial conditions in large-scale spaces and provides basic data for three-dimensional CFD model improvement.  相似文献   

11.
Liquefied petroleum gas (LPG) has potential pool fire risks due to its flammability. The configuration of pool fires plays a significant role when applying the solid flame model or point source model to assess the risks from heat radiation. However, no existing correlations can precisely predict the configuration of large LPG (100% propane) pool fires. To enhance the fundamental understanding on how pool diameter and wind velocity can influence the configuration of large LPG pool fires, an experimentally validated Computational Fluid Dynamics (CFD) model is employed to simulate fires using different burning rate models. Fire temperature profiles, flame heights, and flame tilts predicted by the CFD model were compared with empirical models and experimental data. Accordingly, new correlations for flame height and flame tilt as functions of pool diameter D and wind velocity uw have been developed. The comparisons demonstrate that the new correlations have the best overall accuracy in the prediction of flame height and tilt for large LPG pool fires under different conditions (10 m ≤ D ≤ 20 m, 0 ≤ uw ≤ 3 m·s−1).  相似文献   

12.
Measurements of flammability and explosion parameters for dust/air mixtures require uniform dispersion of the dust cloud inside the test vessel. In a previous work, we showed that, in the standard 20 L sphere, the dust injection system does not allow generation of a uniform cloud, but rather high gradients of dust concentration are established. In this work, we used a previously validated three-dimensional CFD model to simulate the dust dispersion inside the 20 L sphere at different dust nominal concentrations (and fixed dust diameter). Results of numerical simulations have shown that, as the dust nominal concentration is increased, sedimentation prevails and, thus, when ignition is provided, the dust is mainly concentrated at the vessel walls.  相似文献   

13.
Using water curtain system to forced mitigate ammonia vapor cloud has been proven to be an effective measure. Currently, no engineering guidelines for designing an effective water curtain system are available, due to lack of understanding of complex interactions between ammonia vapor cloud and water droplets, especially the understanding of ammonia absorption into water droplets. This paper presents numerical calculations to reproduce the continuous ammonia release dispersion with and without the mitigating influence of a downwind water curtain using computational fluid dynamic (CFD) software ANSYS Fluent 14.0. The turbulence models kɛ and RNG were used to simulate the ammonia cloud dispersion without downwind water curtain. The simulated results were compared with literature using the statistical performance indicators. The RNG model represents better agreement with the experimental data and the kɛ model generates a slightly lesser result. The RNG model coupled with Lagrangian discrete phase model (DPM) was used to simulate the dilution effectiveness of the water curtain system. The ammonia absorption was taken into account by means of user-defined functions (UDF). The simulated effectiveness of water curtains has good agreements with the experimental results. The effectiveness of water mitigation system with and without the ammonia absorption was compared. The results display that the effectiveness mainly depends on the strong air entrainment enhanced by water droplets movement and the ammonia absorption also enhances the effectiveness of water curtain mitigation system. The study indicates that the CFD code can be satisfactorily applied in design criteria for an effective mitigation system.  相似文献   

14.
Dust explosion severities are closely associated with dust dispersion behaviors. To characterize the dispersion process of dust cloud, visualization experiments were conducted by using a transparent Siwek 20-L chamber. Dispersion processes of typical carbonaceous dust were recorded by a high-speed camera and, with the image processing technique, the qualitative analysis based on the transmission of dust cloud was carried out. Results have evidenced the three consecutive stages of dust dispersion process: the fast injection stage of dust particles, the stabilization stage and the sedimentation stage of dust cloud. The motion of dust particles and the variations of dust cloud in space and time can be clearly distinguished. In the stabilization stage, the good uniformity of dust dispersion is achieved when the deviation of transmission data at different locations reaches to the minimum value. Under different nominal dust concentrations, the time periods for dust dispersion stabilization are found to be significantly different, suggesting that different dust concentrations should correspond to different ignition delay in order to accurately measure the explosion characteristics in the Siwek 20-L chamber. Moreover, it is found that the decrease trend of transmission with increasing nominal dust concentration will become gradually leveling off, different from the inversely proportional relationship according to the Bouguer's law, and this indicates that the actual dust concentration will be lower than the nominal concentration or the dust cannot be fully dispersed at the case of high dust concentration. According to the experiment, when the nominal dust concentration exceeds to 1000 g/m3, the transmission will no longer vary visibly.  相似文献   

15.
Explosibility studies of hybrid methane/air/cork dust mixtures were carried out in a near-spherical 22.7 L explosibility test chamber, using 2500 J pyrotechnic ignitors. The suspension dust burned as methane/air/dust clouds and the uniformity of the cork dust dispersion inside the chamber was evaluated through optical dust probes and during the explosion the pressure and the temperature evolution inside the reactor were measured. Tested dust particles had mass median diameter of 71.3 μm and the covered dust cloud concentration was up to 550 g/m3. Measured explosions parameters included minimum explosion concentration, maximum explosion pressures and maximum rate of pressure rise. The cork dust explosion behavior in hybrid methane/air mixtures was studied for atmospheres with 1.98 and 3.5% (v/v) of methane. The effect of methane content on the explosions characteristic parameters was evaluated. The conclusion is that the risk and explosion danger rises with the increase of methane concentration characterized by the reduction of the minimum dust explosion concentration, as methane content increases in the atmosphere. The maximum explosion pressure is not very much sensitive to the methane content and only for the system with 3.5% (v/v) of methane it was observed an increase of maximum rate of pressure rise, when compared with the value obtained for the air/dust system.  相似文献   

16.
The aim of this work is to determine the influence of operating parameters such as the dispersion pressure, the ignition delay and height on the dust flammability. A Computational Fluid Dynamics (CFD) simulation, based on an Euler–Lagrange approach, was developed with Ansys Fluent™ and validated experimentally. Such analysis will facilitate the choice of the most conservative conditions for a flammability test. This paper is focused on a case study performed on wheat starch with the modified Hartmann tube. The dispersion process of the powder was studied with granulometric analyses performed in situ and high speed videos. Tests were performed with injections at gas pressure ranging from 3 to 6 bars and the evolution of the particle size distribution (PSD) was recorded at different ignition heights (5, 10 and 15 cm over the dispersion nozzle). The observations highlighted the presence of agglomeration/deagglomeration processes and dust segregation. Besides, a CFD simulation analysis was aimed at evaluating the impact of a set of parameters on the PSD and the local turbulence, which are closely linked to some flammability parameters. For this computational analysis, the CFD simulation was coupled with a collision treatment based on a Discrete Element Method (DEM) in order to consider the cohesive behavior of the combustible dust. Thus the results suggest performing the injection of the gases at approximately 5 bars for the flammability tests of wheat starch in order to obtain the finest PSD at a given ignition height. It is also shown that the finest PSD are obtained at 5 cm over the dispersion nozzle. However, the local instabilities and turbulence levels are so high during the first stages of the dispersion that the flame growth can be disturbed for short ignition delays. Moreover, the stabilization of the bulk of the dust cloud requires longer periods of time when the ignition sources are located at 15 cm. As a result, the recommended height to perform a flammability test is 10 cm in this case. Finally, this study proposes some tools that might improve the procedure of dust flammability testing.  相似文献   

17.
The downstream as well as the upstream oil and gas industry has for a number of years been aware of the potential for flame acceleration and overpressure generation due to obstacles in gas clouds caused by leaks of flammable substances. To a large extent the obstacles were mainly considered to be equipment, piping, structure etc. typically found in many installations. For landbased installations there may however also be a potential for flame acceleration in regions of vegetation, like trees and bushes. This is likely to have been the case for the Buncefield explosion that occurred in 2005 (Buncefield Major Incident Investigation Board, 2008), which led to the work described in the present paper. The study contains both a numerical and an experimental part and was performed in the period 2006–2008 (Bakke and Brewerton, 2008, Van Wingerden and Wilkins, 2008).The numerical analysis consisted of modelling the Buncefield tank farm and the surrounding area with FLACS. The site itself was not significantly congested and it was not expected to give rise to high overpressures in case of a hydrocarbon leak. However, alongside the roads surrounding the site (Buncefield Lane and Cherry Tree Lane), dense vegetation in the form of trees and bushes was included in the model. This was based on a site survey (which was documented by video) performed in the summer of 2006.A large, shallow, heavier-than-air gas cloud was defined to cover part of the site and surroundings. Upon ignition a flame was established in the gas cloud. This flame accelerated through the trees along the surrounding roads, and resulted in high overpressures of several barg being generated by FLACS. This is to the authors’ knowledge the first time a possible effect of vegetation on explosions has been demonstrated by 3D analyses.As a consequence of these results, and since the software had been validated against typical industrial congestion rather than dense vegetation, a set of experiments to try to demonstrate if these effects were physical was carried out as well. The test volume consisted of a plastic tunnel, 20 m long with a semi-circular cross-section 3.2 m in diameter allowing for representing lanes of vegetation. The total volume of the tent was approximately 80.4 m3. The experimental programme involved different degrees of vegetation size, vegetation density (blocking ratio) and number of vegetation lanes (over the full length of the tunnel). The experiments were performed with stoichiometric propane–air mixtures resulting in continuously accelerating flames over the full length of the tunnel for some of the scenarios investigated.The main conclusions of the study are that trees can have an influence on flame acceleration in gas–air clouds, and that advanced models such as FLACS can be used to study such influence. More research is needed, however, because even if FLACS predicts flame acceleration in dense vegetation, no evidence exists that applying the code to trees rather than rigid obstacles provides results of acceptable accuracy.  相似文献   

18.
The explosion and deflagration-to-detonation transition (DDT) in epoxy propane (E.P.) vapor/air mixture clouds under weak ignition conditions has been studied in an experimental tube of diameter 199 mm and length 29.6 m. E.P. vapor clouds were formed by injecting liquid E.P. into the experimental tube and evaporating of the fine E.P. droplets. The dimension and the evaporating process of the E.P. droplet were measured and analyzed. The E.P. vapor/air mixture clouds were ignited by an electric spark with an ignition energy of 40 J. The characteristics and the stages of the DDT process in the E.P. vapor/air mixtures have been studied and analyzed. A self-sustained detonation wave formed, as was evident from the existence of a transverse wave and a cellular structure. Moreover, a retonation wave formed during the DDT process in the E.P. vapor/air mixture. The influence of the E.P. vapor concentration on the DDT process has been studied. The minimum E.P. vapor concentration for the occurrence of the DDT in the E.P. vapor/air mixture has been evaluated and the variation of DDT distance with E.P. vapor concentration has been analyzed.  相似文献   

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20.
To be able to perform proper consequence modelling as a part of a risk assessment, it is essential to be able to model the physical processes well. Simplified tools for dispersion and explosion predictions are generally not very useful. CFD tools have the potential to model the relevant physics and predict well, but without proper user guidelines based on extensive validation work, very mixed prediction capability can be expected. In this article, recent dispersion validation effort for the CFD tool FLACS–HYDROGEN is presented. A range of different experiments is simulated, including low-momentum releases in a garage, subsonic jets in a garage with stratification effects and subsequent slow diffusion, low momentum and subsonic horizontal jets influenced by buoyancy, and free jets from high-pressure vessels. LH2 releases are also considered. Some of the simulations are performed as blind predictions.  相似文献   

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