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脉冲电晕放电降解CH2Cl2的初步研究 总被引:13,自引:0,他引:13
对高压脉冲电晕放电降解CH2Cl2进行初步研究,比较了正负脉冲电晕降解的活性,正脉冲电晕优于负脉冲电晕。探讨了脉冲形成电容Cp之值及反应器的电晕线材料对降解反应活性的影响。为进一步提高室温下CH2Cl2的降解,在反应器中加入BaTiO3为催化剂,在高压脉冲电场下,BaTiO3受激产生局部电晕,增强了电晕放电流性,提高了反应活性,CH2Cl2的转化率达90%以上。 相似文献
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快速测定废水中CODcr的方法 总被引:2,自引:0,他引:2
以CuSO4-KAl(SO4)2-NaMoO4作催化剂,在H2SO4-H3PO4体系中快速测定废水CODcr新方法,回流时间由标准法的2h缩短至0.5h,以AgNO3-CrK(SO4)代替Hg2SO4消除CI^-干扰,避免汞的污染。 相似文献
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絮凝法处理纸浆漂白废水的研究 总被引:4,自引:0,他引:4
研究了无机絮凝剂PAC,PSA,PES,MgCl2,CaO及其与有机高分子絮凝剂CGA复全使用对两种不同工艺漂白废水的混凝处理特性,结果表明,水质1CODcr,AOX去除率分别为63.2%,45.3%,水质2CODcr,AOX去除率达73.1¥%,53.4%。化钙与碳酸钠具有相同的降解AOX能力,硫离子在中性pH条件下可显著提高AOX的去除率。 相似文献
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为揭示中国自然背景地区臭氧浓度变化特征,并以其为自然背景值指导人为活动导致的臭氧污染控制工作,该研究通过汇总统计中国15个典型自然背景地区与337个地级及以上城市2016—2020年环境空气臭氧自动监测数据,比较分析中国自然背景地区臭氧浓度的年度、季节、日内变化规律与空间分布规律. 结果表明:2016—2020年,中国自然背景地区臭氧年均浓度明显高于城市区域,但臭氧日最大8小时平均浓度的第90百分位数(简称“臭氧年90百分位浓度”)明显低于城市,自然背景地区和城市区域臭氧年均浓度同步快速提升,年均增长分别为1.5和2.0 μg/m3. 中国自然背景地区臭氧浓度季节性变化规律与城市区域存在较大差异,自然背景地区臭氧平均浓度最高值出现在春季,夏、秋、冬三季臭氧平均浓度差异不明显,与东亚环太平洋背景地区臭氧浓度季节性变化规律(春季最高、夏季最低)存在明显差异. 部分自然背景地区受人为活动排放的影响较小,臭氧浓度不存在明显的日内峰谷差,全天臭氧浓度基本保持相同水平;部分自然背景地区可能受邻近城市人为活动排放的臭氧前体物影响,臭氧浓度日内变化规律与邻近城市较为一致,存在明显的日内峰谷差. 研究显示,中国自然背景地区臭氧浓度变化规律与城市区域存在显著差异,臭氧浓度年均值升高迅速,部分自然背景地区臭氧浓度变化规律可能受邻近城市人为活动排放的臭氧前体物传输的影响. 相似文献
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Material conversion from paper sludge ash (PSA) in NaOH solution was attempted to synthesize the adsorbent for removal of
inorganic pollutants, such as Pb2+, NH4
+ and PO4
3?? from aqueous solution. PSA of 0.5 g was added into 10 mL of 3 mol/L NaOH
solution, and then heated at 80, 120, and 160°C for 6–48 hr to obtain the product. PSA mainly composed of two crystalline phases,
gehlenite (Ca2Al2SiO7) and anorthite (CaAl2Si2O8), and amorphous phase. Hydroxysodalite (Na6Al6Si6O24 8H2O) was formed at
80°C, and anorthite dissolved, whereas gehlenite remained una ected. Katoite (Ca3Al2SiO4(OH)8) was formed over 120°C, and
hydroxycancrinite (Na8(OH)2Al6Si6O24 2H2O) was formed at 160°C, due to the dissolution of both gehlenite and anorthite. Specific
surface areas of the products were almost same and were higher than that of raw ash. Cation exchange capacities (CECs) of the products
were also higher than that of raw ash, and CEC obtained at lower temperature was higher. Removal abilities of products for Pb2+, NH4
+,
and PO4
3?? were higher than that of raw ash.With increasing reaction temperature, the removal e ciencies of Pb2+ and NH4
+ decreased
due to the decrease of CEC of the product, while removal e ciency for PO4
3?? was almost same. The concentrations of Si and Al in the
solution and the crystalline phases in the solid during the reaction explain the formation of the product phases at each temperature. 相似文献
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The relationship of the ozone generation and the heating power, corona wire surface temperature, discharge electrode and netting electrode was studied during the negative corona discharge. The experimental results showed that the ozone concentration reduced with applied voltage decrease. With heating power increase, the ozone concentration of unit current decreased at exponential rate and it almost change no longer over 0.40 W. Under given temperature, the lower the applied voltage was, the smaller the ozone concentration was; while under given applied voltages, only over 11 kV could decrease with the surface temperature increase. The ozone concentration decreased with the lengthening of corona wire, and could reduced to 10 ppb under experimental condition of 14.2 kV; it also decreased with the shortening of wire diarmeter,and could decrease 67% at best in the given condition. Moreover, it decreased with the increasing size of netting electrode mesh. At the anion current of 1.65 μA, the ozone concentration of 5.0 x 5.0 cm^2 is only 41% of that of 3.3 x 3.3 cm^2 . 相似文献
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生物质燃烧对东南亚及中国南方对流层臭氧含量影响的模拟研究 总被引:11,自引:0,他引:11
利用区域气候和大气化学模式系统,对2000年春季生物质燃烧排放影响东南亚及中国南部地区对流层臭氧含量进行模拟研究.结果表明,春季东南亚和南亚的生物质燃烧不仅影响源区对流层臭氧含量,而且对处于环流下游的中国南部地区也有显著作用;燃烧源区主要影响对流层低层,下游地区则影响对流层中低层.在源区引起的对流层臭氧总浓度增加达2.1×10-1g/m2,对下游的中国南部地区增加量为9.0~12.0×10-2g/m2;源区大气低层1000~900hPa的臭氧含量可增加36×10-9m3/m3 以上,而在中国南部750~700hPa高度上空的增加达15×10-9m3/m3. 相似文献
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利用2007~2010年北京地区3500m高空内飞机探测的大气污染物(NOx、SO2 、CO和O3)数据资料,分析其时空分布特征.结果表明: 在4~11月期间,NOx、SO2和CO月均值有比较明显的一致性变化规律,NOx、SO2 和CO月均值随高度增加而减小,而O3月均值随高度增加,出现先增大后减小的变化规律.温度较高月份(7~10月)值较小,而温度较低月份(4~6月、11月)值较大,但O3月均值季节变化规律为夏季5~9月的较大,春秋季4月、10~11月的较小.不同的高度大气污染物浓度白天逐时变化并不一致,其变化率是1500m以下的比1500~3500m的明显高.北京地区大气污染物区域分布特征是,除城区四环明显较高外,城区正北面、西南面(北京-保定方向)、东南面(北京-天津方向)较高,西北面(北京-张家口方向)较低. 相似文献
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