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1.
An experiments were carried out with treatments differing in nitrogen supply (0, 5 and 15 g N/m2) and CO2 levels (350 and 700 μmol/mol) using OTC (open top chamber) equipment to investigate the biomass of Calamagrostis angustifolia and soil active carbon contents after two years. The results showed that elevated CO2 concentration increased the biomass of C. angustifolia and the magnitude of response varied with each growth period. Elevated CO2 concentration has increased aboveground biomass by 16.7% and 17.6% during the jointing and heading periods and only 3.5% and 9.4% during dough and maturity periods. The increases in belowground biomass due to CO2 elevation was 26.5%, 34.0% and 28.7% during the heading, dough and maturity periods, respectively. The responses of biomass to enhanced CO2 concentrations are differed in N levels. Both the increase of aboveground biomass and belowground biomass were greater under high level of N supply (15 g N/m2). Elevated CO2 concentration also increased the allocation of biomass and carbon in root. Under elevated CO2 concentration, the average values of active carbon tended to increase. The increases of soil active soil contents followed the sequence of microbial biomass carbon (10.6%) > dissolved organic carbon (7.5%) > labile oxidable carbon (6.6%) > carbohydrate carbon (4.1%). Stepwise regressions indicated there were significant correlations between the soil active carbon contents and plant biomass. Particularly, microbial biomass carbon, labile oxidable carbon and carbohydrate carbon were found to be correlated with belowground biomass, while dissolved organic carbon has correlation with aboveground biomass. Therefore, increased biomass was regarded as the main driving force for the increase in soil active organic carbon under elevated CO2 concentration.  相似文献   

2.
Microalgae: a promising tool for carbon sequestration   总被引:1,自引:1,他引:0  
Increasing trends in global warming already evident, the likelihood of further rise continuing, and their impacts give urgency to addressing carbon sequestration technologies more coherently and effectively. Carbon dioxide (CO2) is responsible for over half the warming potential of all greenhouse gases (GHG), due to the dependence of world economies on fossil fuels. The processes involving CO2 capture and storage (CCS) are gaining attention as an alternative for reducing CO2 concentration in the ambient air. However, these technologies are considered as short-term solutions, as there are still concerns about the environmental sustainability of these processes. A promising technology could be the biological capture of CO2 using microalgae due to its unmatched advantages over higher plants and ocean fertilization. Microalgae are phototrophic microorganisms with simple nutritional requirements, and comprising the major primary producers on this planet. Specific pathways include autotrophic production via both open pond or closed photobioreactor (PBR) systems. Photosynthetic efficiency of microalgae ranged from 10?C20 % in comparison with 1?C2 % of most terrestrial plants. Some algal species, during their exponential growth, can double their biomass in periods as short as 3.5 hours. Moreover, advantage of being tolerant of high concentration of CO2 (flue gas), low light intensity requirements, environmentally sustainable, and co-producing added value products put these as the favoured organisms. Advantages of microalgae in comparison with other sequestration methodologies are discussed, which includes the cultivation systems, the key process parameters, wastewater treatment, harvesting and the novel bio-products produced by microalgal biomass.  相似文献   

3.
以上海市餐饮企业为例,研究了餐饮企业PM_(2.5)排放特征以及排放测算方法.按照单位灶头、单位时间、单位就餐人次这3种计算基准,获得了不同类型餐饮企业PM_(2.5)的排放因子,并在此基础上结合2014年上海市餐饮企业活动水平测算了PM_(2.5)的排放清单.结果表明,餐饮企业排放PM_(2.5)的浓度范围0.1~1.8 mg·m~(-3),甚至超过国家饮食业标准中关于油烟1mg·m~(-3)的排放限值;PM_(2.5)中OC质量贡献超过50%,OC/EC比值的变化范围为58.8~752.3,平均值为128.4,可作为餐饮排放的示踪特征.企业规模是影响餐饮企业PM_(2.5)排放因子的重要因素.按照灶头活动、餐饮作业时间以及就餐人次这3种方法计算得出的餐饮企业PM_(2.5)排放因子均表明,大型、中型企业明显高于小型和微型企业(食堂、快餐).基于上述3种排放因子,计算2014年上海PM_(2.5)排放量相对一致,表明本研究获得基于3种活动水平的排放因子比较可靠,未来可应用于其他城市餐饮企业排放清单的核算.  相似文献   

4.
Interest in renewable energy sources has increased in recent years due to environmental concerns about global warming and air pollution,reduced costs and improved efficiency of technologies.Under the European Union(EU)energy directive,biomass is a suitable renewable source.The aim of this study was to experimentally quantify and characterize the emission of particulate matter(PM_(2.5))resulting from the combustion of two biomass fuels(chipped residual biomass from pine and eucalypt),in a pilot-scale bubbling fluidized bed(BFB)combustor under distinct operating conditions.The variables evaluated were the stoichiometry and,in the case of eucalypt,the leaching of the fuel.The CO and PM_(2.5)emission factors were lower when the stoichiometry used in the experiments was higher(0.33±0.1 g CO/kg and 16.8±1.0 mg PM_(2.5)/kg,dry gases).The treatment of the fuel by leaching before its combustion has shown to promote higher PM_(2.5)emissions(55.2±2.5 mg/kg,as burned).Organic and elemental carbon represented 3.1 to 30 wt.% of the particle mass,while carbonate(CO_3~(2-))accounted for between 2.3 and 8.5 wt.%.The particulate mass was mainly composed of inorganic matter(71% to 86% of the PM_(2.5)mass).Compared to residential stoves,BFB combustion generated very high mass fractions of inorganic elements.Chloride was the water soluble ion in higher concentration in the PM_(2.5)emitted by the combustion of eucalypt,while calcium was the dominant water soluble ion in the case of pine.  相似文献   

5.
张晓伟 《环境科学与管理》2011,36(11):160-162,171
从实际的饮食业油烟监测出发,结合执行与实践《饮食业油烟排放标准》(GB18483-2001)过程中的各种体会,从采样位置、采样工况以及基准灶头数这三个方面,对饮食业油烟监测中存在的问题进行了探讨,并提出了相应的解决对策:油烟监测前,应确保采样位置的规范,必须对采样断面和位置进行优化选择;油烟监测中,应确保采样工况的正常,油烟净化设备务必处于正常工作状态,要派专人负责工况的监督,维持工况的稳定;在今后的标准修订中,建议对基准灶头数的折算方式予以明确,而不是目前按灶的总发热功率或排气罩灶面总投影面积两种方式并存。  相似文献   

6.
餐饮行业是重要的大气污染源,但人们对其实际存在状况、活动水平及排放量的了解有限.以菏泽市为例,采用逐户摸排的方式获得辖区内餐饮单位的基本状况,最终建立餐饮行业的大气污染物排放清单.结果表明:①菏泽市餐饮单位共9 259家,其中大型、中型、小型餐饮单位占比分别为4%、14%和82%,其分布与人口聚居及流动相关,空气质量数值模拟区域空气质量时应考虑这些因素.②餐饮单位的员工人数和餐位数均与表征单位规模的基准灶头数呈显著的相关关系,员工人数与基准灶头数的线性方程为y=2.5x1.3(R2为0.93),餐位数与基准灶头数的线性方程为y=23.0x1.5(R2为0.98),其丰富了表征餐饮单位规模的手段.③在全部被调查的餐饮单位中,安装油烟净化设备的仅占45%,大型、中型、小型餐饮单位安装油烟净化设备的占比分别为64%、59%、41%,其相应的油烟净化率算术平均值分别为52.8%、49.1%、32.1%,表明餐饮单位规模越大越重视油烟的净化.④菏泽市餐饮行业污染主要来自于油烟排放及燃料使用2个部分,其中,SO2、NOx、NH3和CO主要来源于燃料使用,而PM10、PM2.5、VOCs(挥发性有机物)、BC(黑碳)、OC(有机碳)则来源于燃料使用和油烟排放,并且油烟排放的贡献较高.⑤餐饮行业的能源结构中气体燃料占比(76%)较大,液体燃料、煤、生物质占比分别为6%、11%、7%,电能占比不足1%.研究显示,餐饮油烟排放控制的重点在于油烟净化设备的普及、能力维护及运行保障,因此有关部门需加强监管力度.   相似文献   

7.
This paper deals with design and performance of energy efficient biomass cookstove suitable for different fuel wood & briquetted fuel. It was tested with babul wood (Prosopis julliflora), goundnut (Arachis hypogaea) shell briquettes, sawdust briquettes and Cashew nut (Anacardium occidentale) shell. The stove was insulated by refractory cement (Insulyte -11U) to minimize heat losses. The stove has exhibited about 35% thermal efficiency. The CO and CO2 emission was in the range of 3–6 ppm and 17–25 ppm respectively. The stove works in the range of 1.53 to 1.76 kW of power rating. The maximum flame temperature was recorded as 763°C when Cashew nut (Anacardium occidentale) shell was used as feed stock.  相似文献   

8.
长三角地区秸秆燃烧排放因子与颗粒物成分谱研究   总被引:26,自引:12,他引:14  
为获取长三角地区秸秆燃烧污染物排放因子及其颗粒物成分谱,利用自行设计开发的开放式燃烧源排放测试系统,选取小麦、水稻、油菜、豆秸和薪柴等5类典型作物秸秆,分别采用露天焚烧和炉灶燃烧2种燃烧方式,实测其气态污染物和颗粒物排放特征.结果表明,露天燃烧各类秸秆的CO、NOx和PM2.5平均排放因子约为28.7、1.2和2.65 g·kg-1,由于炉灶氧含量相对较低,燃烧不充分,其污染物排放因子总体高于露天燃烧,分别为81.9、2.1和8.5 g·kg-1.各类秸秆中,油菜的排放水平相对较高.含碳组分(OC和EC)是生物质秸秆燃烧产生PM2.5的主要组成,在露天燃烧中OC和EC的质量分数分别占(38.92±13.93)%和(5.66±1.54)%;炉灶燃烧中OC和EC分别为(26.37±10.14)%和(18.97±10.76)%.Cl-、K+等水溶性离子也有较大贡献,在露天燃烧中分别为(13.27±6.82)%和(12.41±3.02)%;在炉灶燃烧中分别为(16.25±9.34)%和(13.62±7.91)%.小麦、水稻、油菜和豆秸等作物秸秆露天燃烧排放颗粒物的K+/OC值分别为0.30、0.52、0.49和0.15,这些特征值可用于判断长三角区域空气质量受秸秆燃烧排放影响的程度,为大气污染来源解析提供直接的判断依据.  相似文献   

9.
Amine scrubbing is the most developed technology for carbon dioxide (CO2) capture. Degradation of amine solvents due to the presence of high levels of oxygen and other impurities in flue gas causes increasing costs and deterioration in long term performance, and therefore purification of the solvents is needed to overcome these problems. This review presents the reclaiming of amine solvents used for post combustion CO2 capture (PCC). Thermal reclaiming, ion exchange, and electrodialysis, although principally developed for sour gas sweetening, have also been tested for CO2 capture from flue gas. The three technologies all have their strengths and weaknesses, and further development is needed to reduce energy usage and costs. An expected future trend for amine reclamation is to focus on process integration of the current reclaiming technologies into the PCC process in order to drive down costs.  相似文献   

10.
Polycyclic aromatic hydrocarbons(PAHs) are carcinogenic or mutagenic and are important toxic pollutants in the flue gas of boilers. Two industrial grade biomass boilers were selected to investigate the characteristics of particulate-bound PAHs: one biomass boiler retro-fitted from an oil boiler(BB1) and one specially designed(BB2) biomass boiler. One coal-fired boiler was also selected for comparison. By using a dilution tunnel system, particulate samples from boilers were collected and 10 PAH species were analyzed by gas chromatography–mass spectrometry(GC–MS). The total emission factors(EFs) of PAHs ranged from 0.0064 to0.0380 mg/kg, with an average of 0.0225 mg/kg, for the biomass boiler emission samples. The total PAH EFs for the tested coal-fired boiler were 1.8 times lower than the average value of the biomass boilers. The PAH diagnostic ratios for wood pellets and straw pellets were similar.The ratio of indeno(1,2,3-cd)pyrene/[indeno(1,2,3-cd)pyrene + benzo(g,h,i)perylene] for the two biomass boilers was lower than those of the reference data for other burning devices, which can probably be used as an indicator to distinguish the emission of biomass boilers from that of industrial coal-fired boilers and residential stoves. The toxic potential of the emission from wood pellet burning was higher than that from straw pellet burning, however both of them were much lower than residential stove exhausts.  相似文献   

11.
大气颗粒物源成分谱可以表征源排放颗粒物的理化特征,为受体模型开展来源解析研究提供基础数据.餐饮油烟排放是室内外环境大气污染的来源之一,当前餐饮源排放PM2.5的化学成分谱仍然缺乏.该研究分别在成都市、武汉市和天津市采集了29组6种餐饮源(居民烹饪、火锅店、烧烤店、职工食堂、中餐馆、商场综合餐饮)排放的PM2.5样品,分析无机元素、离子、碳、多环芳烃(PAHs)等化学组分,并构建了餐饮源排放颗粒物化学成分谱.结果表明:①餐饮源排放PM2.5化学成分中的主要组分为OC(有机碳)、EC(元素碳)、Ca、Al、Fe、NH4+、SO42-、NO3-、Na+、K+、Mg2+和Cl-,其中w(OC)最高,为41.67%~57.91%.②餐饮源排放PM2.5的PAHs中,3环和4环占比较高,其中芴(Flu)、菲(Phe)、荧蒽(Fla)、芘(Pyr)的质量分数相对其他物质较高.研究显示:餐饮源排放PM2.5中OC/EC约为15.99~67.61,在一定程度上可以用来表征餐饮源排放;Fla/(Fla+Pyr)和InP/(InP+BghiP)多集中在0.45~0.55之间,或可作为标识餐饮源的特征比值.   相似文献   

12.
基于重庆本地碳成分谱的PM2.5碳组分来源分析   总被引:13,自引:10,他引:3  
为了解重庆主城PM2.5中碳组分特征和来源,2012-05-02~2012-05-10日在商业区、工业区和居民区进行了PM2.5采样.利用TOR方法分析了8种碳组分,对3个不同功能区大气环境PM2.5以及燃煤尘、尾气尘(机动车尾气、船舶尾气、施工机械尾气)、生物质燃烧尘、餐饮油烟尘这6类源PM2.5中的8种碳组分进行了特征分析.在源的碳成分谱基础上,利用化学质量平衡(CMB)模型得到重庆本地PM2.5的碳来源指示组分,利用因子分析法解析出各类源对不同功能区内PM2.5碳组分的贡献率.结果表明,重庆地区燃煤尘、机动车尾气尘、船舶尾气尘、施工机械尾气尘、生物质燃烧尘、餐饮油烟尘的OC/EC值分别为6.3、3.0、1.9、1.4、12.7和31.3.EC2、EC3的高载荷指示柴油车尾气排放,OC2、OC3、OC4、OPC的高载荷指示燃煤排放,OC1、OC2、OC3、OC4、EC1指示汽油车尾气排放,OC3指示餐饮业排放,OPC指示生物质燃烧排放.商业区OC/PM2.5为17.4%,EC/PM2.5为6.9%,估算得到,二次有机碳(SOC)/OC为40.0%;工业区OC/PM2.5为15.5%,EC/PM2.5为6.6%,SOC/OC为37.4%;居民区OC/PM2.5为14.6%,EC/PM2.5为5.6%,SOC/OC为42.8%.工业区PM2.5中碳组分的主要来源为燃煤和汽油车尾气、柴油车尾气;商业区PM2.5中碳组分的主要来源为汽油车尾气、柴油车尾气和餐饮业油烟;居住区PM2.5中碳组分的主要来源为汽油车尾气、餐饮业油烟、柴油车尾气.  相似文献   

13.
民用燃煤源中多环芳烃排放因子实测及其影响因素研究   总被引:6,自引:5,他引:1  
海婷婷  陈颖军  王艳  田崇国  林田 《环境科学》2013,34(7):2533-2538
民用燃煤是我国目前关注较多的多环芳烃(polycyclic aromatic hydrocarbons,PAHs)排放源.根据我国民用燃煤所涉及的煤种、燃烧方式和炉灶类型,利用全流稀释采样系统对5种不同成熟度的煤种,分别以散块煤和蜂窝煤形式在3种炉灶类型中燃烧产生的烟气进行了采样和分析,初步获取了我国民用燃煤烟气中PAHs排放因子(EFPAHs)的实测数据.结果表明,烟煤的EFPAHs在块煤燃烧方式下的变化范围为1.1~3.9 mg.kg-1,在蜂窝煤燃烧方式下的变化范围为2.5~21.1 mg.kg-1,无烟煤的EFPAHs在块煤与蜂窝煤燃烧方式下分别为0.2 mg.kg-1与0.6 mg.kg-1.在民用燃煤的EFPAHs的各种影响因素中,煤的地质成熟度起主导作用,不同成熟度煤种的EFPAHs差异幅度高达1~2个数量级.其次是燃烧形态(块煤/蜂窝煤),主要表现为同一种地质成熟度的煤在蜂窝煤燃烧方式下排放的PAHs比块煤高2~6倍.炉灶类型的影响最小.  相似文献   

14.
为了考察将电厂烟气注入采空区实现防火与气体封存的可行性,采用自制的煤大样量吸附装置测定了常温、常压条件下塔山烟煤对各种烟气成分的饱和吸附量,并对烟煤在空气和烟气氛围下对氧气的吸附行为进行了研究. 结果表明:将电厂烟气注入井下采空区,每t煤可封存约1.20 m3的CO2,烟气中SO2和NO2可全部被烟煤封存;在物理吸附阶段,烟煤对CO2的吸附量分别为对N2吸附量的13倍,对O2吸附量的41倍;在常温、常压条件下,烟煤对N2和CO2的吸附为物理吸附,12 h已基本达到饱和状态,但烟煤对O2的吸附随着时间的增加逐渐由物理吸附转变为化学吸附,因此在较长时间内未能达到平衡状态. 通过不同气体氛围下烟煤吸附氧气量的数据分析发现,将电厂烟气注入到采空区,因烟煤对氧气的吸附量降低了29%,可有效抑制其自燃反应的进行. 研究显示,电厂烟气注入采空区可实现节能减排和灾害治理的统一.   相似文献   

15.
CO2减排和土壤污染修复是我国实现经济和环境可持续发展必须解决的两大难题.基于生物固碳对根际微环境的影响,本研究提出通过增施CO2强化土壤有机污染的植物修复过程,为同时解决CO2减排和土壤污染植物修复面临的困境提供新思路.在模拟的CO2增施环境中,以C3植物菜豆和C4植物玉米为供试植物,以氯氰菊酯为目标污染物,研究增施CO2对C3和C4植物根际氯氰菊酯残留浓度的影响.结果表明,增施CO2可显著增加C3植物菜豆的地上和地下干重,在氯氰菊酯添加浓度为0、20、40 mg.kg-1时地下干重分别比自然CO2水平时增加了54.3%、31.9%和30.0%.增施CO2提高了未添加氯氰菊酯土壤的菜豆根际微生物数量,但降低了添加氯氰菊酯土壤的菜豆根际微生物数量.增施CO2对未添加氯氰菊酯土壤的菜豆根际氯氰菊酯残留浓度没有显著影响,但降低了菜豆根际氯氰菊酯的残留浓度,分别比自然CO2水平时下降24.0%(20mg.kg-1)和16.9%(40 mg.kg-1).然而,对C4植物玉米而言,增施CO2对植物生物量、根际微生物、根际氯氰菊酯残留浓度下降没有明显促进作用,甚至有抑制作用.本实验表明,增施CO2降低了C3植物根际氯氰菊酯残留浓度,可以考虑将增施CO2作为C3植物修复土壤污染的强化措施,但对C4植物的影响还有待进一步研究.  相似文献   

16.
小球藻高效净化猪场废水厌氧发酵沼液研究   总被引:1,自引:0,他引:1  
为了净化脱除养猪场废水厌氧发酵沼液中的主要污染物,本文利用臭氧氧化对沼液灭菌并且降解其中的大分子有机物(效果优于高压蒸汽灭菌法),然后高效培养小球藻转化为生物质变废为宝.研究了通入不同体积浓度CO_2以及在沼液中补充部分营养盐对微藻生长净化沼液的影响.当CO_2体积浓度从2%逐渐增加到30%时,微藻生物质产量和脱除污染物效率先升后降,并在体积浓度为15%时达到峰值.当沼液中补充添加营养盐10 mg·L~(-1)磷和1 mg·L~(-1)铁时,微藻生物质产量相对未添加条件进一步提高了29.1%,达到了5.81 g·L~(-1),相应的COD、TN、NH_3-N、TP和抗生素替米考星等污染物脱除效率分别提高到88.5%、91.2%、93.6%、98.9%和90.7%.因此,小球藻可高效净化猪场厌氧发酵沼液同时生产高值生物质,具有良好的应用前景.  相似文献   

17.
Gas chromatography equipped with an electron capture detector (GC-ECD) has been widely used for measuring atmospheric N2O,but nonlinear response and the influence of atmospheric CO2 have been recognized as defects for quantification.An original GCECD method using N 2 as carrier gas was improved by introducing a small flow rate of CO2 makeup gas into the ECD,which could well remedy the above defects.The N2O signal of the improved method was 4-fold higher than that of the original method and the relative standard deviation was reduced from > 1% to 0.31%.N2O concentrations with different CO2 concentrations (172.2×10-6-1722×10-6mol/mol) measured by the improved GC-ECD method were in line with the actual N2O concentrations.However,the N2O concentrations detected by the original method were largely biased with a variation range of-4.5%~7%.The N2O fluxes between an agricultural field and the atmosphere measured by the original method were greatly overestimated in comparison with those measured by the improved method.Good linear correlation (R2=0.9996) between the response of the improved ECD and N2O concentrations (93×10-9-1966×10-9mol/mol) indicated that atmospheric N2O could be accurately quantified via a single standard gas.Atmospheric N2O concentrations comparatively measured by the improved method and a high precision GC-ECD method were in good agreement.  相似文献   

18.
The uncertainty in emission estimation is strongly associated with the variation in emission factor (EF),which could be influenced by a variety of factors such as fuel properties,stove type,fire management and even methods used in measurements.The impacts of these factors are complicated and often interact with each other.Controlled burning experiments were conducted to investigate the influences of fuel mass load,air supply and burning rate on the emissions and size distributions of carbonaceous particulate matter (PM) from indoor corn straw burning in a cooking stove.The results showed that the EFs of PM (EFPM),organic carbon (EFOC) and elemental carbon (EFEC) were independent of the fuel mass load.The differences among them under different burning rates or air supply amounts were also found to be insignificant (p > 0.05) in the tested circumstances.PM from the indoor corn straw burning was dominated by fine PM with diameter less than 2.1 μm,contributing 86.4%±3.9% of the total.The size distribution of PM was influenced by the burning rate and air supply conditions.On average,EF PM,EF OC and EF EC for corn straw burned in a residential cooking stove were (3.84±1.02),(0.846±0.895) and (0.391±0.350) g/kg,respectively.EF PM,EF OC and EF EC were found to be positively correlated with each other (p < 0.05),but they were not significantly correlated with the EF of co-emitted CO,suggesting that special attention should be paid to the use of CO as a surrogate for other incomplete combustion pollutants.  相似文献   

19.
Capturing flue gases often require multiple stages of scrubbing, increasing the capital and operating costs. So far, no attempt has been made to study the absorption characteristics of all the three gases (NO, SO2 and CO2) in a single stage absorption unit at alkaline pH conditions. We have attempted to capture all the three gases with a single wet scrubbing column. The absorption of all three gases with sodium carbonate solution promoted with oxidizers was investigated in a tall absorption column. The absorbance was found to be 100% for CO2, 30% for NO and 95% for SO2 respectively. The capture efficiency of sodium carbonate solution was increased by 40% for CO2 loading, with the addition of oxidizer. Absorption kinetics and reaction pathways of all the three gases were discussed individually in detail.  相似文献   

20.
无机碳源对栅藻LX1生长及油脂积累特性的影响   总被引:3,自引:2,他引:1  
李鑫  胡洪营  张玉平 《环境科学》2011,32(8):2260-2266
以二级出水为培养基,比较了对照组和补充碳源(Na2CO3、NaHCO3和CO2)组栅藻LX1的生长和油脂积累特性.培养14d,4组试验中栅藻LX1的生长及油脂积累特性均无显著差别,藻细胞生物量、油脂及三酰甘油酯产量分别为0.70~0.77、0.27~0.34和0.029~0.033 g.L-1,单位藻细胞油脂含量约为3...  相似文献   

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