废弃手机回收处理系统生命周期能耗与碳足迹分析

以废弃手机为研究对象,采用生命周期评价方法分析了当前我国废弃手机回收处理系统的能耗和碳足迹.研究结果表明,废弃手机回收处理全生命周期能耗与碳足迹分别为-1069.86MJ和-60.38kg CO_2-eq.再生材料产出是废弃手机回收处理生命周期能耗和碳足迹最主要的贡献来源,其对能耗和碳足迹的贡献分别为88.3%和96.8%.敏感性分析显示,提高互联网在线回收平台的日回收量及拆解部件和元器件的再使用比例,可有效降低废弃手机回收处理系统的生命周期能耗和碳足迹.     

砖混和剪力墙结构住宅建筑碳足迹对比研究

通过对厦门大学职工砖混结构和剪力墙结构住宅住户的调查,将住宅建筑生命周期分为建材生产、建材运输、建筑建造、建筑使用、建筑拆除和废旧建材处理6个阶段,计算了2种建筑结构不同生命周期阶段的碳排放,结果显示:2种建筑碳足迹都为2.3 t/m2左右,砖混结构的人均碳足迹高于剪力墙结构,分别为67.98 t/m2和64.47 t/m2;2种住宅绝大部分的碳排放来自建材生产和建筑使用两阶段,剪力墙结构住宅在建材生产阶段碳排放量为0.673 4 t/m2,是砖混结构的2倍多;剪力墙结构住宅使用期间的碳排放量为1.59 t/m2,为砖混结构的81.2%。剪力墙结构住宅建材生产和建筑使用碳排放占建筑全生命周期碳排放的比例分别为29.28%和69.13%,砖混结构住宅则为14.01%和84.81%。研究结果可为发展低碳建筑提供科学依据。     

基于LCA的建材生产能耗及污染物排放清单分析

利用生命周期方法,通过清单建模及计算,分析了12种建材产品生产的生命周期能耗与大气污染物排放.清单分析包括能源上游阶段、运输阶段和建材生产阶段;同时考虑了直接能耗、直接污染物排放以及间接能耗、间接污染物排放;并使用“迭代”法对能源上游阶段进行清单分析.清单输出结果表明:钢材生产的生命周期总能耗和CO₂排放量最大,分别为34.83 GJ/t和3 493 kg/t;草砖生产的生命周期总能耗和CO₂排放量最小,分别为0.14 GJ/t和11 kg/t,说明其环境友好性最佳.      

基于生命周期评价EI99法的水泥窑共处置废弃农药分析

以废弃农药为研究对象,应用生命周期评价法从人类健康(HH)、生态系统质量(EQ)和资源(R)3个角度对水泥窑共处置和焚烧炉处置的环境影响做出定性和定量评估.结果表明,废弃农药在水泥窑中共处置更具环境合理性.在水泥窑共处置和焚烧炉处置中,功能单位(1t)废弃农药总环境负荷(也称为环境影响潜值)分别为-27.5和0.379Pt,前者的环境负荷比后者减少了7360%,人类健康(HH)、生态系统质量(EQ)和资源(R)等各指标分别减少372%、5840%、-40.0%.废弃农药水泥窑共处置在原/燃料的获取阶段可避免57.4%的环境负荷,是降低水泥窑共处置环境影响的关键环节.焚烧和电力生产阶段的污染排放对焚烧炉处置中各指标都有很高的贡献率.二英、苯、重金属是水泥窑共处置废弃农药的主要影响因子;NOx和粉尘对焚烧系统的影响较大.     

基于混合生命周期评价的不同坝型温室气体排放对比分析

为了研究不同坝型对环境造成的影响,采用混合生命周期评价方法定量分析并比较同规模的重力坝和堆石坝水电枢纽布置在全生命周期内的温室气体排放.研究基于糯扎渡工程实例,生命周期考虑材料设备生产阶段、运输阶段、施工阶段和运行维护阶段.结果表明:重力坝方案和堆石坝方案生命周期温室气体排放量分别为1145.49×104和815.85×104t(以CO2当量计),重力坝比堆石坝多排放40.4%.其中,重力坝在生产、运输和运行阶段的碳足迹比堆石坝大,但堆石坝在施工阶段的碳足迹比重力坝大.运行阶段的温室气体排放量占全生命周期碳足迹的比例最大,其次是材料设备生产阶段、施工阶段和运输阶段.糯扎渡水电工程的碳排放因子明显低于火电碳排放因子,合理开展水电建设,是实现我国"十二五"规划碳减排目标的有效途径.     

家用空调碳足迹及其关键影响因素分析

我国居民家庭空调拥有量迅速增加,其生命周期中产生的温室效应也日益受到关注.本文依据国际标准PAS 2050,采用RCEES 2012和Ecoinvent 2.1数据库,并运用SimaPro 7.1软件计算了中国典型家用空调的碳足迹.主要结论为:家用空调生命周期中使用阶段用电产生的碳足迹最大,占67%;制冷剂的泄漏是除电力使用外第二大碳足迹贡献因素,产生了23%的碳足迹;生产制造阶段和废物处理阶段的碳足迹分别占16%和-6%.敏感性分析表明,空调日使用时间、空调年使用季节和制冷剂的泄漏比例是家用空调碳足迹的关键影响因素.     

水泥窑协同处置工业废弃物的生命周期评价

以废白土、废催化剂和污染土壤等工业废弃物为研究对象,运用生命周期评价(LCA)方法,对水泥窑协同处置废弃物的环境影响进行评价.通过建立生产过程输入、输出清单,从全球变暖潜值、资源消耗潜值、人体毒性潜值等方面,基于Gabi5.0软件进行建模与计算,对水泥窑常规生产工艺与协同处置工业废弃物工艺产生的环境影响进行比较.结果表明:功能单位(1 t)水泥的生产过程中,常规生产工艺和协同处置工艺的环境影响潜值分别为5.78×10~(-11)和5.61×10~(-11),协同处置工艺使得全生命周期环境影响潜值降低了2.94%;水泥生产过程最主要的环境影响是全球变暖和人体毒性,其中,协同处置工艺下这两种环境影响分别降低了0.80%和1.80%,资源消耗相比常规生产降低了11.1%;从全生命周期看,水泥生产中熟料煅烧阶段对环境的影响最大,协同处置工艺下熟料煅烧阶段的环境影响相比常规生产降低了8.0%.协同处置工艺相比常规生产工艺有更好的环境效益.     

基于非线性规划的冬小麦生产碳足迹优化研究

农田是重要的温室气体人为排放源,在全球气候变化研究中占有重要的地位.碳足迹是评估农作物生产生命周期温室气体排放的有力工具.因此,本研究以我国典型冬小麦生长区山西省晋中市为例,采用生命周期评价的方法估算该区单位质量小麦生产的碳足迹,并在此基础上用非线性规划的方法对冬小麦生产碳足迹进行优化,旨在寻求小麦增产减排的途径.结果表明,研究区在传统的耕作方式下,生产1 t小麦的碳足迹为1357.28 kg(以CO2当量计),其中,生长阶段的温室气体排放的碳足迹和尿素生产环节所占比例较大.通过优化尿素与有机肥的施用量,可将研究区生产1 t小麦的碳足迹降低到469.99 kg,同时使单位面积产量增加9.13%.本文结果与相关研究差异较大,可能与氮肥施用量及N2O排放系数的取值有关.本研究对于了解冬小麦生产的综合碳排放情况,探索农业增产减排途径等方面具有重要意义.     

中国湿巾代谢分析及环境影响评估

为评估湿巾塑料消耗及污染现状,比较不同材质湿巾环境影响表现,开展了中国湿巾"生产-使用-废弃处置"全过程物质流分析,通过市场调研获知湿巾材质分布,开展全国消费者问卷调查获知废弃湿巾流向.对不同材质湿巾开展全生命周期环境影响评价,系统比较评估其环境影响.结果表明,"70%聚酯纤维+30%粘胶纤维"混合材质湿巾是中国最为常见的湿巾类型,2019年中国湿巾用塑量达41万t,经消费者使用丢弃后约有18.9%直接泄露进入自然环境.在焚烧、填埋处置方式中,全粘胶纤维湿巾全生命周期综合环境影响比全聚酯纤维湿巾低38%,前者水污染突出但资源消耗、毒性风险优势明显;在直接泄露方式中,全粘胶纤维湿巾可避免聚酯纤维泄露后崩解为微塑料纤维的环境风险.     

基于混合生命周期评价的小型灌溉泵站碳排放核算方法研究

小型灌溉泵站是农田灌溉的重要基础设施,单座规模较小但数量庞大,从“双碳”角度对其开展全生命周期的碳排放核算分析对实现其可持续发展和促进高效供水具有重要意义。基于碳足迹理论,采用混合生命周期分析法,将灌溉泵站全生命周期分为材料设备生产、材料设备运输、建设施工、运行维护和拆除报废5个阶段,分析了灌溉泵站在建设、运行、管理整个过程中的碳排放规律,构建了小型灌溉泵站碳排放模型核算方法,包括核算原理、研究思路、计算流程和核算公式等。选择了6处不同地区小型灌溉泵站开展了碳排放核算方法的实例分析,结果显示：6处灌溉泵站的碳排放总量分别为402.87,34.30,849.37,140.93,1645.56,312.89 t CO₂e,年单位灌溉面积的碳排放系数分别为331,147,681,144,202,126 kg CO₂e/(hm²·a);各个阶段的碳排放量具有较大差异,总体来看运行维护阶段(62.57%)和材料设备生产阶段(26.64%)排放量最大,建设施工阶段(5.32%)、拆除报废阶段(4.78%)、材料设备运阶段输(0.69...     

Distribution and ecological effect of mercury in Laogang landfill, Shanghai, China

Laogang landfill near Shanghai is the largest landfill in China, and receives about 10000 t of daily garbage per day, Samples of topsoil and plants were analyzed to evaluate mercury pollution from the landfill. For topsoil samples, there were significant correlations among total mercury （HgT）, combinative mercury （Hgc） and gaseous mercury （HgG）, and content of total organic carbon （TOC）, but, no significantly relationship was found between Hg content and filling time. Hg content changes in vertical profiles with time showed that the average Hgv of profiles 1992, 1996, and 2000 was similar, but their average HgG was quite different. HgT was significantly correlated with Hgc in profile 1992 and 2000, and Hgv was significantly correlated with Hg6 in profile 1996. HgG/Hgv ratio in profile samples decreased in the order of （HgG,/HgT）1992〉（HgG/HgT）1996〉〉（HgG/HgT）2000. A simple outline of Hg release in landfill could be drawn： with increasing of filling time, degradation undergoes different biodegradation, accordingly, gaseous mercury goes through small, more, and small proportion to total mercury. Distribution of Hg in plants was inhomogeneous, following the order of leaf〉root〉stem. The highest value of leaf may be associated with higher atmospheric Hg from landfill. Ligneous plants （e.g. Phyllostachys glanca, Prunus salicina and Ligustrum lucidum） are capable of enriching more Hg than herbaceous plants.     

EDTA-enhanced phytoremediation of lead contaminated soil by Bidens maximowicziana

Phytoremediation is a potential cleanup technology for the removal of heavy metals from contaminated soils.Bidens maximowicziana is a new Pb hyperaccumulator,which not only has remarkable tolerance to Pb but also extraordinary accumulation capacity for Pb.The maximum Pb concentration was 1509.3 mg/kg in roots and 2164.7 mg/kg in overground tissues.The Pb distribution order in the B. maximowicziana was:leaf>stem>root.The effect of amendments on phytoremediation was also studied.The mobility of soil Pb and the Pb concentrations in plants were both increased by EDTA application.Compared with CK(control check),EDTA application promoted translocation of Pb to overground parts of the plant.The Pb concentrations in overground parts of plants was increased from 24.23-680.56 mg/kg to 29.07-1905.57 mg/kg.This research demonstrated that B.maximowicziana appeared to be suitable for phytoremediation of Pb contaminated soil,especially,combination with EDTA.     

Decomposition of alachlor by ozonation and its mechanism

Decomposition and corresponding mechanism of alachlor, an endocrine disruptor in water by ozonation were investigated. Results showed that alachlor could not be completely mineralized by ozone alone. Many intermediates and final products were formed during the process, including aromatic compounds, aliphatic carboxylic acids, and inorganic ions. In evoluting these products, some of them with weak polarity were qualitatively identified by GC-MS. The information of inorganic ions suggested that the dechlorination was the first and the fastest step in the ozonation of alachlor.     

Enzymatic oxidation of aqueous pentachlorophenol

The influence of the nonionic surfactant Tween 80 on pentachlorophenol （PCP） oxidation catalyzed by horseradish peroxidase was studied. The surfactant was tested at concentrations below and above its critical micelle concentration （CMC）. Enhancement of PCP removal was observed at sub-CMCs. The presence of Tween 80 in the reaction mixture reduced enzyme inactivation which occurred through a combination of free radical attack and sorption by precipitated products. A simple first-order model was able to simulate time profiles for enzyme inactivation in the presence or absence of Tween 80. At supra-CMCs, the surfactant caused noticeable reductions in PCP removal, presumably through micelle partitioning of PCP which precluded the hydrophobic PCP molecule from interacting with the enzyme.     

基于综合水质标识指数和对应分析法的校园河道水质评价

以三峡大学的校园河道求索溪为研究对象,利用综合水质标识指数法确定求索溪水质类别,分析其水质时空变化规律,并利用对应分析法得出求索溪中不同监测点的主要污染因子.研究结果表明:求索溪整体的综合水质标识指数为7.423,整体水质为劣V类(地表水环境质量标准GB 3838-2002)且黑臭.从时间变化来看,求索溪4月份的水质最差,5月份次之,4、5月份所有监测点的水质都劣于V类且黑臭;8月份水质最好,水质为Ⅳ类;从空间分布来看,8个监测点综合水质标识指数均超过6.0,水质为劣V类,其中6号监测点的水质相对最好,监测点3号的水质相对最差;对应分析法得出求索溪的整体水体污染程度受总氮因子的影响最大,其次为总磷.该研究拟为求索溪及类似校园河道的水环境治理研究提供基础依据和参考.     

Effects of chitosan on growth of an aquatic plant (Hydrilla verticillata) in polluted waters with different chemical oxygen demands

Effects of chitosan on a submersed plant, Hydrilla verticillata, were investigated. Results indicated that H. venicillata could prevent ultrastructure phytotoxicities and oxidativereaction from polluted water with high chemical oxygen demand (COD). Superoxide dismutase (SOD) activity and malondialdehyde (MDA) contents in H. verticillata treated with 0.1% chitosan in wastewater increased with high COD (980 mg/L) and decreased with low COD (63 mg/L), respectively. Ultrastructural analysis showed that the stroma and grana of chloroplast basically remained normal. However, plant cells from the control experiment (untreated with chitosan) were vacuolated and the cell interval increased. The relict of protoplast moved to the center, with cells tending to disjoint. Our findings indicate that wastewater with high COD concentration can cause a substantial damage to submersed plant, nevertheless, chitosan probably could alleviate the membrane lipid peroxidization and ultrastructure phytotoxicities, and protect plant cells from stress of high COD concentration polluted water.     

Removal of cadmium using MnO2 loaded D301 resin

MnO2 loaded weak basic anion exchange resin D301 （Anion exchange resin, macroreticular weak basic styrene） as adsorbent has been prepared and applied to the removal of cadmium. The adsorption characteristics have been investigated with respect to effect of pH, equilibrium isotherms, removal kinetic data, and interference of the coexisting ions. The results indicated that the Cd^2＋ could be efficiently removed using MnO2 loaded D301 resin in the pH range of 3-8 from aqueous solutions with the co-existence of high concentration of alkali and alkaline-earth metals ions. The saturate adsorption capacity of the Cd^2＋ was 77.88 mg/g. The adsorption process followed the pseudo first-order kinetics. The equilibrium data obtained in this study accorded excellently with the Langmuir adsorption isotherm.     

Effect of coagulation pretreatment on the fouling of ultrafiltration membrane

The purpose of this study is to understand the effect and mechanism of preventing membrane fouling, by coagulation pretreatment, in terms of fractional component and molecular weight of natural organic matter （NOM）. A relatively higher molecular weight （MW） of hydrophobic compounds was responsible for a rapid decline in the ultrafiltration flux. Coagulation could effectively remove the hydrophobic organics, resulting in the increase of flux. It was found that a lower MW of neutral hydrophilic compounds, which could remove inadequately by coagulation, was responsible for the slow declining flux. The fluxes in the filtration of coagulated water and supernatant water were compared and the results showed that a lower MW of neutral hydrophilic compounds remained in the supernatant water after coagulation could be rejected by a membrane, resulting in fouling. It was also found that the coagulated flocs could absorb neutral hydrophilic compounds effectively. Therefore, with the coagulated flocs formed on the membrane surface, the flux decline could be improved.     

Penetration analysis of elements and bioleaching treatment of spent refractory for recycling

Acidithiobacillus ferrooxidans ATCC23270 and Acidithiobacillus thiooxidans TM-32 were used for bioleaching of spent refractories of aluminium and copper melting furnaces for their recycling.Firstly,penetration of elements into aluminium melting furnace refractory was investigated and it was found that up to 7 cm from surface was contaminated.Comparison on leaching efficiency by the strains ATCC23270 and TM-32 found that the strain ATCC23270 could treat larger amount of the refractories than the strain TM-32 could do.In the experiment of bioleaching of spent refractory aluminium melting furnace by the strain ATCC23270,high leaching efficiency were obtained on Al,Si,and Ca,and extremely low leaching performance was,however,shown on the rest of elements i.e.,Na,Mn,and Zn.Under the strain TM-32 use,relatively high leaching performance was recognized on Al,Si,Ca,Na,Mn,and Zn.In the experiment of bioleaching for spent refractory copper melting furnace,almost the same leaching trends were shown on Cu,Zn,Al,and Si under the strains ACTT23270 and TM-32 uses.     

Simultaneous removal of ammonium and phosphate by zeolite synthesized from coal fly ash as influenced by acid treatment

Zeolite synthesized from fly ash （ZFA） without modification is not efficient for the purification of NH4＋ and phosphate at low concentrations that occur in real effluents, despite the high potential removal capacity. To develop an effective technique to enhance the removal efficiency of ammonium and phosphate at low concentrations, ZFA was modified with acid treatment and the simultaneous removal of ammonium and phosphate in a wide range of concentration was investigated. It was seen that when compared with untreated ZFA, only the treatment by 0.01 mol/L of H2SO4 significantly improved the removal efficiency of ammonium at low initial concentrations. The behavior was well explained by the pH effect. Treatment by more concentrated H2SO4 led to the deterioration of the ZFA structure and a decrease in the cation exchange capacity. Treatment by 0.01 mol/L H2SO4 improved the removal efficiency of phosphate by ZFA at all initial P concentrations, while the treatment by concentrated H2SO4 （≥0.9 mol/L） resulted in a limited maximum phosphate immobilization capacity （PIC）. It was concluded that through a previous mild acid treatment （e.g. 0.01 mol/L of H2SO4）, ZFA can be used in the simultaneous removal of NH4＋ and P at low concentrations simulating real effluent.