城市环境质量的竞争性评价模型

城市化进程推动了经济的快速发展但也给城市环境质量带来了严重的挑战。为了推动城市环境保护工作,每年全国各地都对城市环境综合整治进行定量考核。首先分析了现有环境综合整治考核办法的不足,阐述建立竞争性评价模型的必要性。竞争性评价模型在指标集的取值范围内选取最优值建立一个虚拟最优城市,以虚拟最优城市为参照,引入优越指数概念,得出待评价城市的优越指数值,然后进行排序和评价。根据该模型对2004年全国18个计划单列市和重点城市的环境质量进行了综合评价,得到了合适的结果;最后总结了模型的特点及以后改进的方向。     

基于熵权物元可拓模型的福州市环境综合质量评价

本文针对城市环境总体质量评价的特点,采用物元可拓理论和熵权法构建了城市环境总体质量综合评判模型,并对福州市环境总体质量进行了评价,结果表明福州市2008年的环境综合质量状况良好.     

城市生态系统生态化综合评价——以长三角为例

在分析城市生态系统组成的基础上,讨论了城市生态系统生态化的内涵;采用层次结构模型构建了城市生态化评价指标体系;采集了长三角地区具有代表性的八城市2004年的相关数据,运用因子分析与层次分析相结合的方法,对其经济、社会、环境子系统及复合生态系统的发展状况进行了综合评价,结果表明:长三角八城市的生态化水平排序依次为苏州、上海、宁波、南京、杭州、无锡、常州、扬州。     

模糊综合评价在水环境质量综合评价中的应用研究

将模糊综合评价具体应用到水环境质量综合评价研究中 ,通过建立评价的因子集、评价集、隶属函数和权重集 ,实现对各水体样本的质量等级综合评判与排序。并对评价的权重集、取大取小算法和评价结果的最大隶属度原则进行了改进 ,取得较好的效果     

生态城市建设指标体系与综合评价研究

城市生态系统是社会、经济和自然三个子系统构成的复合生态系统。本文探讨了生态城市指标体系及其评价标准,并采用综合加权方法确定评价指标的权重,建立了生态城市评价的灰色关联度模型。结合南京生态城市系统的现状进行了综合评价,为南京生态城市发展战略的制定以及生态城市的管理提供决策指导。     

城市隧道机电系统模糊综合安全评价

本文对城市隧道机电系统安全指标进行了分析,应用模糊数学理论建立了模糊综合安全评价指标体系和模型,并以厦门云顶隧道为例,对该隧道机电系统进行了模糊综合安全评价,得出隧道机电系统安全运营状态,对提高城市隧道机电系统安全管理水平具有重要的意义.     

地下岩溶水环境质量评价模型研究

该文利用模糊数学和灰色理论的相关知识,根据地下岩溶水系统水化学动态特征和污染机理以及水文地质条件自身特点建立了地下岩溶水环境质量评价数学模型;并验证此模型,对西龙河峄山断层带水源地的地下岩溶水环境质量进行了综合评价。评价结果表明：该岩溶水系统大部分地区地下水的环境质量状况较好,局部地段较差,且地下水环境质量的分布特征与区域水文地质条件及水源地补给排泄关系具有较好的相关性。此结论与运用加权均值型指数评价法得到的结论相同,这说明此模型的建立是合理的,评价结果是完全可靠的。     

基于MAPGIS的福建省矿山地质环境综合评价分析

福建省矿业开发产生的环境地质问题主要有占用破坏土地、破坏地貌景观、水土流失、水土污染、水均衡破坏以及采空塌陷、岩溶塌陷、崩滑流矿山地质灾害等。矿山地质环境综合评价单元的划分采用正方形网格单元。选取矿山地质环境现状、地质环境条件、矿产资源开发利用规划、矿山生态环境恢复治理难易程度等作为评价因子。根据各因子对矿山地质环境质量影响存在重大差异及可分层次的实际情况,采用质量指数评价模型作为矿山地质环境综合评价模型。利用MAPGIS的空间分析功能,对整个系统进行综合评价。然后根据综合指数的大小,将全省圈定出28个区的矿山地质环境综合质量划分为严重区、较严重区和一般区。     

环境政策的综合影响评价模型系统及应用

研究和建立一套以可计算的均衡理论模型(CGE)为核心,同时与大气环境质量模型和健康影响模型(暴露-反应模型)连接,组成了环境政策综合评价模型,为综合评价环境政策产生的各类影响及其相互作用提供了一种评价方法.利用该模型系统,分析北京市采用能源环境税对北京市的大气环境、健康、经济发展和居民福利水平的影响.模型分析认为,北京市采用单一的能源环境税可以改善北京市的大气环境,但也将迟缓北京市的经济发展;如果北京市在采用能源环境税的同时进行绿色环境税收制度改革,则不但可以改善环境,而且可以促进北京市的可持续发展.     

基于P-S-R框架辽宁省2003年-2012年城市生态安全演变趋势研究

着眼于辽宁省经济发展与环境问题凸显的现状,基于压力-状态-响应(P-S-R)生态安全评价模型,选取辽宁省14个城市2003年-2012年的经济、社会与环境等25个指标数据进行生态安全综合评价,对生态安全演变趋势进行分析.结果表明:十年来辽宁省城市生态安全指数呈现整体上升趋势,生态安全综合评价指数基本与生态安全指数变化趋势相似,说明辽宁省生态安全状况正逐步改善,并且总体呈现发展趋势,辽宁省的生态安全建设取得一定进展.     

Distribution and ecological effect of mercury in Laogang landfill, Shanghai, China

Laogang landfill near Shanghai is the largest landfill in China, and receives about 10000 t of daily garbage per day, Samples of topsoil and plants were analyzed to evaluate mercury pollution from the landfill. For topsoil samples, there were significant correlations among total mercury （HgT）, combinative mercury （Hgc） and gaseous mercury （HgG）, and content of total organic carbon （TOC）, but, no significantly relationship was found between Hg content and filling time. Hg content changes in vertical profiles with time showed that the average Hgv of profiles 1992, 1996, and 2000 was similar, but their average HgG was quite different. HgT was significantly correlated with Hgc in profile 1992 and 2000, and Hgv was significantly correlated with Hg6 in profile 1996. HgG/Hgv ratio in profile samples decreased in the order of （HgG,/HgT）1992〉（HgG/HgT）1996〉〉（HgG/HgT）2000. A simple outline of Hg release in landfill could be drawn： with increasing of filling time, degradation undergoes different biodegradation, accordingly, gaseous mercury goes through small, more, and small proportion to total mercury. Distribution of Hg in plants was inhomogeneous, following the order of leaf〉root〉stem. The highest value of leaf may be associated with higher atmospheric Hg from landfill. Ligneous plants （e.g. Phyllostachys glanca, Prunus salicina and Ligustrum lucidum） are capable of enriching more Hg than herbaceous plants.     

EDTA-enhanced phytoremediation of lead contaminated soil by Bidens maximowicziana

Phytoremediation is a potential cleanup technology for the removal of heavy metals from contaminated soils.Bidens maximowicziana is a new Pb hyperaccumulator,which not only has remarkable tolerance to Pb but also extraordinary accumulation capacity for Pb.The maximum Pb concentration was 1509.3 mg/kg in roots and 2164.7 mg/kg in overground tissues.The Pb distribution order in the B. maximowicziana was:leaf>stem>root.The effect of amendments on phytoremediation was also studied.The mobility of soil Pb and the Pb concentrations in plants were both increased by EDTA application.Compared with CK(control check),EDTA application promoted translocation of Pb to overground parts of the plant.The Pb concentrations in overground parts of plants was increased from 24.23-680.56 mg/kg to 29.07-1905.57 mg/kg.This research demonstrated that B.maximowicziana appeared to be suitable for phytoremediation of Pb contaminated soil,especially,combination with EDTA.     

Decomposition of alachlor by ozonation and its mechanism

Decomposition and corresponding mechanism of alachlor, an endocrine disruptor in water by ozonation were investigated. Results showed that alachlor could not be completely mineralized by ozone alone. Many intermediates and final products were formed during the process, including aromatic compounds, aliphatic carboxylic acids, and inorganic ions. In evoluting these products, some of them with weak polarity were qualitatively identified by GC-MS. The information of inorganic ions suggested that the dechlorination was the first and the fastest step in the ozonation of alachlor.     

Enzymatic oxidation of aqueous pentachlorophenol

The influence of the nonionic surfactant Tween 80 on pentachlorophenol （PCP） oxidation catalyzed by horseradish peroxidase was studied. The surfactant was tested at concentrations below and above its critical micelle concentration （CMC）. Enhancement of PCP removal was observed at sub-CMCs. The presence of Tween 80 in the reaction mixture reduced enzyme inactivation which occurred through a combination of free radical attack and sorption by precipitated products. A simple first-order model was able to simulate time profiles for enzyme inactivation in the presence or absence of Tween 80. At supra-CMCs, the surfactant caused noticeable reductions in PCP removal, presumably through micelle partitioning of PCP which precluded the hydrophobic PCP molecule from interacting with the enzyme.     

基于综合水质标识指数和对应分析法的校园河道水质评价

以三峡大学的校园河道求索溪为研究对象,利用综合水质标识指数法确定求索溪水质类别,分析其水质时空变化规律,并利用对应分析法得出求索溪中不同监测点的主要污染因子.研究结果表明:求索溪整体的综合水质标识指数为7.423,整体水质为劣V类(地表水环境质量标准GB 3838-2002)且黑臭.从时间变化来看,求索溪4月份的水质最差,5月份次之,4、5月份所有监测点的水质都劣于V类且黑臭;8月份水质最好,水质为Ⅳ类;从空间分布来看,8个监测点综合水质标识指数均超过6.0,水质为劣V类,其中6号监测点的水质相对最好,监测点3号的水质相对最差;对应分析法得出求索溪的整体水体污染程度受总氮因子的影响最大,其次为总磷.该研究拟为求索溪及类似校园河道的水环境治理研究提供基础依据和参考.     

Effects of chitosan on growth of an aquatic plant (Hydrilla verticillata) in polluted waters with different chemical oxygen demands

Effects of chitosan on a submersed plant, Hydrilla verticillata, were investigated. Results indicated that H. venicillata could prevent ultrastructure phytotoxicities and oxidativereaction from polluted water with high chemical oxygen demand (COD). Superoxide dismutase (SOD) activity and malondialdehyde (MDA) contents in H. verticillata treated with 0.1% chitosan in wastewater increased with high COD (980 mg/L) and decreased with low COD (63 mg/L), respectively. Ultrastructural analysis showed that the stroma and grana of chloroplast basically remained normal. However, plant cells from the control experiment (untreated with chitosan) were vacuolated and the cell interval increased. The relict of protoplast moved to the center, with cells tending to disjoint. Our findings indicate that wastewater with high COD concentration can cause a substantial damage to submersed plant, nevertheless, chitosan probably could alleviate the membrane lipid peroxidization and ultrastructure phytotoxicities, and protect plant cells from stress of high COD concentration polluted water.     

Removal of cadmium using MnO2 loaded D301 resin

MnO2 loaded weak basic anion exchange resin D301 （Anion exchange resin, macroreticular weak basic styrene） as adsorbent has been prepared and applied to the removal of cadmium. The adsorption characteristics have been investigated with respect to effect of pH, equilibrium isotherms, removal kinetic data, and interference of the coexisting ions. The results indicated that the Cd^2＋ could be efficiently removed using MnO2 loaded D301 resin in the pH range of 3-8 from aqueous solutions with the co-existence of high concentration of alkali and alkaline-earth metals ions. The saturate adsorption capacity of the Cd^2＋ was 77.88 mg/g. The adsorption process followed the pseudo first-order kinetics. The equilibrium data obtained in this study accorded excellently with the Langmuir adsorption isotherm.     

Effect of coagulation pretreatment on the fouling of ultrafiltration membrane

The purpose of this study is to understand the effect and mechanism of preventing membrane fouling, by coagulation pretreatment, in terms of fractional component and molecular weight of natural organic matter （NOM）. A relatively higher molecular weight （MW） of hydrophobic compounds was responsible for a rapid decline in the ultrafiltration flux. Coagulation could effectively remove the hydrophobic organics, resulting in the increase of flux. It was found that a lower MW of neutral hydrophilic compounds, which could remove inadequately by coagulation, was responsible for the slow declining flux. The fluxes in the filtration of coagulated water and supernatant water were compared and the results showed that a lower MW of neutral hydrophilic compounds remained in the supernatant water after coagulation could be rejected by a membrane, resulting in fouling. It was also found that the coagulated flocs could absorb neutral hydrophilic compounds effectively. Therefore, with the coagulated flocs formed on the membrane surface, the flux decline could be improved.     

Penetration analysis of elements and bioleaching treatment of spent refractory for recycling

Acidithiobacillus ferrooxidans ATCC23270 and Acidithiobacillus thiooxidans TM-32 were used for bioleaching of spent refractories of aluminium and copper melting furnaces for their recycling.Firstly,penetration of elements into aluminium melting furnace refractory was investigated and it was found that up to 7 cm from surface was contaminated.Comparison on leaching efficiency by the strains ATCC23270 and TM-32 found that the strain ATCC23270 could treat larger amount of the refractories than the strain TM-32 could do.In the experiment of bioleaching of spent refractory aluminium melting furnace by the strain ATCC23270,high leaching efficiency were obtained on Al,Si,and Ca,and extremely low leaching performance was,however,shown on the rest of elements i.e.,Na,Mn,and Zn.Under the strain TM-32 use,relatively high leaching performance was recognized on Al,Si,Ca,Na,Mn,and Zn.In the experiment of bioleaching for spent refractory copper melting furnace,almost the same leaching trends were shown on Cu,Zn,Al,and Si under the strains ACTT23270 and TM-32 uses.     

Simultaneous removal of ammonium and phosphate by zeolite synthesized from coal fly ash as influenced by acid treatment

Zeolite synthesized from fly ash （ZFA） without modification is not efficient for the purification of NH4＋ and phosphate at low concentrations that occur in real effluents, despite the high potential removal capacity. To develop an effective technique to enhance the removal efficiency of ammonium and phosphate at low concentrations, ZFA was modified with acid treatment and the simultaneous removal of ammonium and phosphate in a wide range of concentration was investigated. It was seen that when compared with untreated ZFA, only the treatment by 0.01 mol/L of H2SO4 significantly improved the removal efficiency of ammonium at low initial concentrations. The behavior was well explained by the pH effect. Treatment by more concentrated H2SO4 led to the deterioration of the ZFA structure and a decrease in the cation exchange capacity. Treatment by 0.01 mol/L H2SO4 improved the removal efficiency of phosphate by ZFA at all initial P concentrations, while the treatment by concentrated H2SO4 （≥0.9 mol/L） resulted in a limited maximum phosphate immobilization capacity （PIC）. It was concluded that through a previous mild acid treatment （e.g. 0.01 mol/L of H2SO4）, ZFA can be used in the simultaneous removal of NH4＋ and P at low concentrations simulating real effluent.