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1.
实验室模拟和在东湖自来水厂现场比较研究了不同饮水消毒剂对水中指示菌、病毒的灭活和消毒副产物生成的影响 .结果显示 ,细菌对消毒剂的抵抗力比病毒低 .进一步研究表明 ,当病毒浓度为n(PFU)≈ 1× 10 5mL-1,能使脊髓灰质炎病毒 (PolioV)及大肠杆菌f2 噬菌体 (f2 )彻底灭活的各消毒剂最低浓度分别为 :有效氯 ρ(Cl) =16mg/L ,二氧化氯 ρ(ClO2 ) =8.0mg/L ,联合消毒剂 ρ(Cl+ClO2 ) =(5 .0 +5 .0 )mg/L ,臭氧 ρ(O3 ) =1.2 2mg/L ;有效氯 ρ(Cl) =8.5mg/L ,二氧化氯 ρ(ClO2 ) =5 .0mg/L ,联合消毒剂 ρ(Cl+ClO2 ) =(2 .5 +2 .5 )mg/L ,臭氧 ρ(O3 ) =0 .6 7mg/L .按以上阈浓度加氯消毒东湖源水 ,产生的CHCl3 大大高于其他消毒剂 .将水中有机抽提物进行Ames试验 ,结果显示 ,加氯消毒处理的水样致突变活性明显高于其他消毒剂处理的水样 .所获水样浓集物经GC/MS鉴定分析 ,共鉴定出 118种有机物 ,主要为多环芳烃、烷基苯、酞酸酯、烷基苯酚、醛、酮醇和烷烃类等 .主要成分酞酸酯类系美国环境保护署(EPA)确定的优先污染物 ,具有致突变、致癌、致畸作用 .表 6参 7  相似文献   

2.
部分重金属化合物对淡水发光菌的毒性研究   总被引:9,自引:1,他引:9  
应用微板毒性分析方法,分别测定了CdCl2·2.5H2O、CoSO4·5H2O、Cr(NO3)3·3H2O、Cu(NO3)2·3H2O、Fe(NO3)3·3H2O、MnCl2·9H2O、Na2SeO3、ZnSO4·7H2O、Ni(NO3)2·6H2O9种重金属离子化合物及其混合物对淡水发光菌—青海弧菌Q67(Vibrio-qinghaiensissp.—Q67)的发光抑制毒性.结果表明,9种重金属离子化合物对Q67的剂量-效应关系均可用Weibull或Logit模型有效描述.由拟合剂量-效应曲线得到这9种重金属离子化合物的半数效应浓度EC50的负对数值(-logEC50)分别为4.35、3.08、2.39、3.83、3.34、2.39、3.32、3.93和2.76,说明其毒性顺序为:CdCl2·2.5H2O>ZnSO4·7H2O>Cu(NO3)2·3H2O>Fe(NO3)3·3H2O>Na2SeO3>CoSO4·5H2O>Ni(NO3)2·6H2O>Cr(NO3)3·3H2O≈MnCl2·9H2O.为了研究重金属混合物的毒性规律,设计了4组等效应浓度(EC50、EC15、EC10和EC5)比混合物,测试了其混合物毒性,并应用剂量加和(DA)、独立作用(IA)原理及经典联合毒性评价方法进行了分析.DA与IA分析表明,所研究的4种混合物的毒性具有拮抗特征,而毒性单位法(TU)和混合指数法(MTI)的评价结果均为部分相加作用,相加指数法(AI)的评价结果则为拮抗作用.所选评价方法不同,混合物毒性评价结果可能也不同.  相似文献   

3.
为了研究稀土离子与氨基酸 (Pro)的相互作用 ,在pH≈ 3.5水溶液中合成了高氯酸八水·(脯氨酸 )合铱 (Ⅲ )铒 (Ⅲ ) ,获得了单晶 ,并经四圆衍射仪测定了结构 .配合物组成为C2 0 H52 Cl6ErN4 O4 0 Y ,属三斜晶系 ,P1空间群 .晶胞参数a =0 .986 0 (2 )°nm ,b =1.30 2 0 (5 )nm ,c=1.36 32 (5 )nm ,α =10 9.32 (3)° ,β=110 .19(2 )° ,γ =10 0 .96 (2 )°,V =1.45 6 (1)nm3,Z =1,Dc=1.6 6 3g/cm3,μ =2 .797mm-1,F(0 0 0 ) =72 9.配合物分子中 ,Y3 ‘、Er3 在相应位置上出现的几率各为 5 0 % ,相邻两个金属离子被两个以桥式双齿配位的Pro分子连接 ,每个金属离子除了与 4个羧基O配位外 ,还与 4个水分子的氧配位 ,配位数为 8,形成变形的四方反棱柱 .图 4表 3参 10  相似文献   

4.
采用钙镁试剂 (CLG) 示波计时电位法 ,分别在中性和碱性条件下直接检测天然水中的无机单核铝 [Ali]和总单核铝 [Ala]浓度 .并用该法测定了酸消化水样中的总铝 [AlT],由 [Ala]-[Ali]间接得到有机单核铝 [Alo],[AlT]-[Ala]得到酸溶态铝 [Alr],从而实现了水中五种Al形态的电化学测定 .实验结果表明 :在pH9 0的 0 5mol·1 - 1KCl+ 0 1mol·1 - 1Na2 B4 O7缓冲溶液中 ,CLG切口为Ep1=-0 75V ,加入铝后出现新切口 ,Ep2 =-0 90V ,检测线性范围为 8× 1 0 - 6— 4× 1 0 - 5mol·1 - 1,检测下限为 6× 1 0 - 7mol·1 - 1,在 3× 1 0 - 5mol·1 - 1Al时 ,相对标准偏差为 4 8% (n =1 0 ) .在中性条件下测定的是无机单核铝 ,而在碱性条件下则是总单核铝 (包括无机单核铝和有机单核铝两部分 ) .  相似文献   

5.
棒状链霉菌突变株CCRC11518-Ⅲ50克拉维酸发酵条件的研究   总被引:2,自引:0,他引:2  
通过单因子和多因子摇瓶正交优化试验,确定了克拉维酸产生菌棒状链霉菌突变株Streptomyces clavuligerusCCRC11518-Ⅲ50的三角瓶发酵条件.发酵培养基组成(ρ/g L-1):甘油30,大豆蛋白胨60,麦芽浸膏7.5,K2HPO4·3H2O 1.0,MgSO4·7H2O 2.0,FeSO4-7H2O 1.0;培养基初始pH 6.5;接种量15%;培养基装量20 mL/250 mL三角瓶;培养温度25℃;发酵时间72 h.克拉维酸效价由优化前的834.8 μg mL-1提高到1 082.615 μg mL-1,提高了29.7%.还在1 600 mL发酵罐中进行了初步放大试验.当接种量15%,通气量1:0.5,转速450 r min-1,25℃发酵60h克拉维酸效价达到高峰1 025 μg mL-1.图12表1参12  相似文献   

6.
微电解-生物膜法处理含Cr3+有机废水   总被引:7,自引:1,他引:7  
采用微电解 生物膜复合工艺处理含重金属离子的有机废水 ,在实验过程中 ,废水中的有机物由生物膜中的好氧微生物与厌氧微生物菌群作为营养源而消耗 ;重金属离子 (Cr3 +)则通过电沉积去除一部分 ,同时被生物膜吸收而去除 .实验结果表明 :在好氧条件下 ,培养、驯化后的复合微生物菌种分别经 4h与 1 2h可将废水中的葡萄糖从 1 0 0 0mg·l- 1降解到 2 0— 4 0mg·l- 1.对C6 H12 O6 含量为 5 0 0mg·l- 1,Cr3 +含量为1 0mg·l- 1的废水 ,经处理后 ,C6 H12 O6 含量为 1 5— 2 5mg·l- 1,Cr3 +含量为 1mg·l- 1以下 ,分别比单一的电沉积工艺与生物膜工艺Cr3 +去除率提高 2 5 %和 5 % .  相似文献   

7.
气溶胶水溶性有机物(WSOC)中二元羧酸的测定   总被引:5,自引:1,他引:5  
提出了BF3 /丁醇酯化衍生反应 GC/MS分析大气气溶胶水溶性有机物 (WSOC)中二元羧酸 (乙二酸、丙二酸和丁二酸 )的测定方法 .其相应酯化产物乙二酸二丁酯、丙二酸二丁酯和丁二酸二丁酯的线性范围为 1× 1 0 - 5mol·l- 1— 1× 1 0 - 2 mol·l- 1,精密度分别为 1 6 7% ,3 0 4 %和 5 2 8% ;最低检测限分别为 1 9× 1 0 - 7mol·l- 1,1 1×1 0 - 7mol·l- 1和 1 2 5× 1 0 - 6mol·l- 1.并实测了北京市秋、冬两季乙二酸、丙二酸和丁二酸的平均浓度水平 ,分别为 4 44ng·m- 3 ,4 0ng·m- 3 ,30 2ng·m- 3 .  相似文献   

8.
讨论了以FeSO4·7H2O和H2SO4为原料,以HNO3为催化剂通入空气氧化铁(Ⅱ)制备聚合硫酸铁的主要影响因素。实验表明:[SO42-]/[Fe]总=1.35~1.40为较合适的投料比例;HNO3的投料量约为原料FeSO4·7H2O投料的4%,反应温度为60~90℃,搅拌速度为400~600r/min,反应时间4h。反应后期pH基本不变;产品对活性大红溶液的净水处理结果较为满意,脱色率98.8%,COD的去除率为92%。  相似文献   

9.
微生物絮凝剂产生菌的筛选和优化以及在水处理中的应用   总被引:28,自引:0,他引:28  
从土壤中筛到1株絮凝剂产生菌BY-28,该菌产生的絮凝剂对高岭土悬浊液的絮凝活性较高且稳定,鉴定为多粘类芽孢杆菌Paenibacillus polymyxa BY-28.菌BY-28产絮凝剂的最佳培养基和培养条件为:葡萄糖2%,KH2PO40.4%,黄豆饼粉0.1%,MgSO4·7H2O 0.05%,CaCl2 0.05%,pH 7.0,30℃,180 r/min摇床培养2-3 d,产生具有高絮凝活性的絮凝剂.该絮凝剂对水中无机悬浮物和有机染料具有较高的去除率,尤其是能够有效地去除肌苷发酵液和肌苷生产废水中的菌体及悬浮物.图3表4参16  相似文献   

10.
在 2L高压间歇反应釜内 ,研究了乳化液废水湿式氧化 (WAO)的效果、影响因素及动力学特征 .结果表明 :温度、氧分压、进水浓度等操作条件对氧化效果有不同程度的影响 ,其中温度是关键的影响因素 .进水COD为 4 80 0 0mg·l- 1时 ,在 2 2 0℃ ,1 2 5倍理论供氧量的条件下 (氧分压为 1 2MPa) ,反应 2h ,去除率达 86% ,经拟合的反应动力学模型为 :-dCODdt =0 0 94 63exp ( -4 5 92 8× 1 0 3RT ) [COD]2 0 15[PO2 ]0 3 118-dTOCdt =0 3 770exp ( -4 7 84 1× 1 0 3RT ) [TOC]1 978[PO2 ]0 3 0 18表明湿式氧化处理乳化液废水的效果良好  相似文献   

11.
Conservation science is a crisis discipline in which the results of scientific enquiry must be made available quickly to those implementing management. We assessed the extent to which scientific research published since the year 2000 in 20 conservation science journals is publicly available. Of the 19,207 papers published, 1,667 (8.68%) are freely downloadable from an official repository. Moreover, only 938 papers (4.88%) meet the standard definition of open access in which material can be freely reused providing attribution to the authors is given. This compares poorly with a comparable set of 20 evolutionary biology journals, where 31.93% of papers are freely downloadable and 7.49% are open access. Seventeen of the 20 conservation journals offer an open access option, but fewer than 5% of the papers are available through open access. The cost of accessing the full body of conservation science runs into tens of thousands of dollars per year for institutional subscribers, and many conservation practitioners cannot access pay‐per‐view science through their workplace. However, important initiatives such as Research4Life are making science available to organizations in developing countries. We urge authors of conservation science to pay for open access on a per‐article basis or to choose publication in open access journals, taking care to ensure the license allows reuse for any purpose providing attribution is given. Currently, it would cost $51 million to make all conservation science published since 2000 freely available by paying the open access fees currently levied to authors. Publishers of conservation journals might consider more cost effective models for open access and conservation‐oriented organizations running journals could consider a broader range of options for open access to nonmembers such as sponsorship of open access via membership fees. Obtención de Acceso Abierto a la Ciencia de la Conservación  相似文献   

12.
Summary Interactions were studied among alkaloid-containing legumes (Erythrina corallodendrum andSpartium junceum) and non-toxic plants (Citrus sinensis, Cucurbita moschata andEuphorbia tirucalli), several polyphagous homopterans,Aphis craccivora (Aphididae),Icerya purchasi, I. aegyptiaca (Margarodidae),Lepidosaphes ulmi (Diaspididae) andPlanococcus citri (Pseudococcidae), and some major natural enemies of these homopterans. Significant reductions in survival due to negative effects of alkaloid containing as compared with non-alkaloidal plants were recorded for the predatorsRodolia cardinalis andChilocorus bipustulatus, but not forCryptolaemus montrouzieri (Coleoptera: Coccinellidae),Chrysoperla carnea (Neuroptera: Chrysopidae) andSympherobius sanctus (Neuroptera: Sympherobiidae). The development time of the larvae or pupae ofR. cardinalis, C. carnea andS. sanctus was longer on the toxic plants than on the non-toxic ones. The percentage of parasitism ofA. craccivora collected from the non-alkaloidal plantsVicia palaestina andMelilotus albus was much higher than that onS. junceum. The parasitoid complexes ofA. craccivora differed between both plant groups. The nutritive value of honeydew ofI. purchasi andA. craccivora, as expressed by the life span ofEncyrtus infelix (Hymenoptera: Encyrtidae) adults, was also investigated. Life spans were significantly longer when the wasps fed on honeydew produced on non-alkaloidal plants (C. sinensis andPittosporum tobira) than on alkaloid containing plants whenI. purchasi — but notA. craccivora — was the producer. It is suggested that the chemical defense ofE. corallodendrum andS. junceum is exploited by polyphagous phytophages to reduce predation. In nature, population growth and density of four of the investigated homopterans are conspicuously high when they developed on the alkaloid containing plant species, and very low on non-alkaloid plants. The efficiency of their natural enemies may be reduced by sequestration of alkaloids (or other toxic plant compounds) or their transfer into excreted honeydew. Therefore it is assumed that a generalist phytophagous homopteran may be protected from its natural enemies, although at different rates of efficiency, if it can safely sequester the host allelochemical when it develops on toxic species within its host range.  相似文献   

13.
Summary Two South American polyphagous leaf beetles,Diabrotica speciosa andCerotoma arcuata, selectively accumulated the bitter tasting compound 23,24-dihydrocucurbitacin D in their body after ingesting root tissues of cucurbit plants. Similarly, three Asian Cucurbitaceae-feeding specialists in the genusAulacophora were found to sequester the same compound. Cucurbitacin analogs were shown to deter feeding by a bird predator, indicating an allomonal role for these compounds in cucurbitacin-associated chrysomelid leaf beetles both of New and Old Worlds. The strong affinity to cucurbitacins, selective sequestration of the analogs and consequent protection from predators suggested an ecological adaptation mechanism developed in common among these two geographically isolated subtribes in the Luperini.  相似文献   

14.
Abstract: In East Africa fire and grazing by wild and domestic ungulates maintain savannas, and pastoralists historically set fires and herded livestock through the use of temporary corrals called bomas. In recent decades traditional pastoral practices have declined, and this may be affecting biodiversity. We investigated the effects of prescribed fires and bomas on savanna bird communities in East Africa during the first and second dry seasons of the year (respectively before and after the rains that mark the onset of breeding for most birds). We compared abundance, richness, and community composition on 9‐ha burned plots, recently abandoned bomas, and control plots in the undisturbed matrix habitat over a 3‐year period. Generally, recently burned areas and abandoned bomas attracted greater densities of birds and had different community assemblages than the surrounding matrix. The effects of disturbances were influenced by interactions between primary productivity, represented by the normalized difference vegetation index, and time. Bird densities were highest and a greater proportion of species was observed on burned plots in the months following the fires. Drought conditions equalized bird densities across treatments within 1 year, and individuals from a greater proportion of species were more commonly observed on abandoned bomas. Yearly fluctuations in abundance were less pronounced on bomas than on burns, which indicate that although fire may benefit birds in the short term, bomas may have a more‐lasting positive effect and provide resources during droughts. Several Palearctic migrants were attracted to burned plots regardless of rainfall, which indicates continued fire suppression may threaten their already‐declining populations. Most notably, the paucity of birds observed on the controls suggests that the current structure of the matrix developed as a result of fire suppression. Traditional pastoralism appears critical to the maintenance of avian diversity in these savannas.  相似文献   

15.
Abstract: The last century has seen the ascendance of a core economic model, which we will refer to as Walrasian economics. This model is driven by the psychological assumptions that humans act only in a self‐referential and narrowly rational way and that production can be described as a self‐contained circular flow between firms and households. These assumptions have critical implications for the way economics is used to inform conservation biology. Yet the Walrasian model is inconsistent with a large body of empirical evidence about actual human behavior, and it violates a number of basic physical laws. Research in behavioral science and neuroscience shows that humans are uniquely social animals and not self‐centered rational economic beings. Economic production is subject to physical laws including the laws of thermodynamics and mass balance. In addition, some contemporary economic theory, spurred by exciting new research in human behavior and a wealth of data about the negative global impact of the human economy on natural systems, is moving toward a world view that places consumption and production squarely in its behavioral and biophysical context. We argue that abandoning the straightjacket of the Walrasian core is essential to further progress in understanding the complex, coupled interactions between the human economy and the natural world. We call for a new framework for economic theory and policy that is consistent with observed human behavior, recognizes the complex and frequently irreversible interaction between human and natural systems, and directly confronts the cumulative negative effects of the human economy on the Earth's life support systems. Biophysical economics and ecological economics are two emerging economic frameworks in this movement.  相似文献   

16.
Effects of Coffee Management on Deforestation Rates and Forest Integrity   总被引:1,自引:0,他引:1  
Knowledge about how forest margins are utilized can be crucial for a general understanding of changes in forest cover, forest structure, and biodiversity across landscapes. We studied forest‐agriculture transitions in southwestern Ethiopia and hypothesized that the presence of coffee (Coffea arabica)decreases deforestation rates because of coffee's importance to local economies and its widespread occurrence in forests and forest margins. Using satellite images and elevation data, we compared changes in forest cover over 37 years (1973–2010) across elevations in 2 forest‐agriculture mosaic landscapes (1100 km2 around Bonga and 3000 km2 in Goma‐Gera). In the field in the Bonga area, we determined coffee cover and forest structure in 40 forest margins that differed in time since deforestation. Both the absolute and relative deforestation rates were lower at coffee‐growing elevations compared with at higher elevations (?10/20% vs. ?40/50% comparing relative rates at 1800 m asl and 2300–2500 m asl, respectively). Within the coffee‐growing elevation, the proportion of sites with high coffee cover (>20%) was significantly higher in stable margins (42% of sites that had been in the same location for the entire period) than in recently changed margins (0% of sites where expansion of annual crops had changed the margin). Disturbance level and forest structure did not differ between sites with 30% or 3% coffee. However, a growing body of literature on gradients of coffee management in Ethiopia reports coffee's negative effects on abundances of forest‐specialist species. Even if the presence of coffee slows down the conversion of forest to annual‐crop agriculture, there is a risk that an intensification of coffee management will still threaten forest biodiversity, including the genetic diversity of wild coffee. Conservation policy for Ethiopian forests thus needs to develop strategies that acknowledge that forests without coffee production may have higher deforestation risks than forests with coffee production and that forests with coffee production often have lower biodiversity value. Efectos de la Administración Cafetalera sobre las Tasas de Deforestación y la Integridad de los Bosques  相似文献   

17.
As drivers of terrestrial ecosystems, humans have replaced large carnivores in most areas, and human influence not only exerts striking ecological pressures on biodiversity at local scales but also has indirect effects in distant corners of the world. We suggest that the multibillion dollar cashmere industry creates economic motivations that link western fashion preferences for cashmere to land use in Central Asia. This penchant for stylish clothing, in turn, encourages herders to increase livestock production which affects persistence of over 6 endangered large mammals in these remote, arid ecosystems. We hypothesized that global trade in cashmere has strong negative effects on native large mammals of deserts and grassland where cashmere‐producing goats are raised. We used time series data, ecological snapshots of the biomass of native and domestic ungulates, and ecologically and behaviorally based fieldwork to test our hypothesis. In Mongolia increases in domestic goat production were associated with a 3‐fold increase in local profits for herders coexisting with endangered saiga (Saiga tatarica).That increasing domestic grazing pressure carries fitness consequences was inferred on the basis of an approximately 4‐fold difference in juvenile recruitment among blue sheep (Pseudois nayaur)in trans‐Himalayan India. Across 7 study areas in Mongolia, India, and China's Tibetan Plateau, native ungulate biomass is now <5% that of domestic species. Such trends suggest ecosystem degradation and decreased capacity for the persistence of native species, including at least 8 Asian endemic species: saiga, chiru (Pantholops hodgsoni), Bactrian camel (Camelus bactrianus), snow leopard(Panthera uncia), khulan(Equus hemionus), kiang (E. kiang), takhi (E. przewalski), and wild yak (Bos mutus). Our results suggest striking yet indirect and unintended actions that link trophic‐level effects to markets induced by the trade for cashmere. Globalización del Mercado de Cachemira y la Declinación de Mamíferos Mayores en Asia Central  相似文献   

18.
The high conservational value of the lichen-rich vegetation and landscape of the marine foreland Ørkenen on the isle of Anholt is treated from a Danish as well as a European perspective. The sensitivity of the lichen-rich vegetation to physical disturbance is emphasized. The impact of invasive species such asPinus mugo as well as the effect of atmospheric deposition of nutrients on the heaths at Anholt is described. Considerations related to the development of a management plan for Ørkenen are presented.  相似文献   

19.
Summary The attraction of Old World leaf beetles in the genusAulacophora to kairomones and parakairomones which are effective lures for New WorldDiabrotica andAcalymma were investigated. Beetles captured on sticky traps baited with single and multicomponent lures were no different from the control traps for two species ofAulacophora. Yellow colored traps and squash blossoms are attractive toAulacophora beetles which detect sub-microgram quantities of cucurbitacins on silica gel. Leaf feeding behavior and flight activity data are correlated with varietal preference of threeAulacophora species. The common response byDiabrotica andAulacophora to cucurbitacins reinforces the two groups' coevolutionary association with the Cucurbitaceae. The apparent lack of a common response toCucurbita blossom volatiles suggests recent evolutionary pathways are substantially different for these two groups of beetles.  相似文献   

20.
Invasive non-native species are important drivers of ecosystem change, yet the driving forces of biological invasions themselves are poorly understood. Such information is essential to ensure policies focus on the most relevant drivers, and that future scenarios capture the full range of potential outcomes for invasive non-native species. I carried out a bibliometric analysis of articles published from 2000 to 2020 that address either invasive non-native species or biodiversity and ecosystem services and that also mention 1 or more drivers of ecosystem change. I examined 5 indirect drivers (demographic, economic, governance, sociocultural, and technological) and 6 direct drivers (climate change, invasive non-native species, land-use or sea-use change, natural hazards, pollution, and resource extraction). Using the Web of Science core collection of citation indexes, I undertook searches of article titles and keywords and retrieved 27,462 articles addressing invasive non-native species and 110,087 articles dealing with biodiversity or ecosystem services. Most research to date on biological invasions as well as on biodiversity and ecosystem services has focused on anthropogenic direct drivers of ecosystem change rather than indirect drivers. Yet currently, less than 18% of articles addressing biological invasions examined drivers of ecosystem change, a similar level to that found over 20 years ago for biodiversity or ecosystem services. Knowledge of the drivers of biological invasions is limited, emphasizes tractable drivers over those that require an interdisciplinary approach, and is biased toward developed economies. Drivers generally deemed important for biological invasions, such as governance and resource extraction, accounted for less than 2% of research effort. The absence of a systematic understanding of the forces that drive invasive non-native species and how they interact means that attempts to mitigate or forecast biological invasions are likely to fail. To address biological invasions requires a much better orientation of national and international research on drivers in relation to both their actual importance as well as their policy relevance.  相似文献   

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