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1.
In this study, the distribution of airborne manganese (Mn) bound with particulate matters (PM) was investigated using data sets collected from 15 major cities in Korea over a 16-year time span (1991–2006). The mean Mn concentration measured from all the major cities in Korea throughout the entire study period was 71 ng m?3, while the annual mean values of different cities ranged from 10.5 ng m?3 in Yeosu (2003) to 615 ng m?3 in Wonju (2006). The Mn levels were considerably larger in industrialized areas than in other land-use types. The Mn concentrations in the major industrial cities of Pohang, Incheon, and Ansan averaged 255, 98.2, and 84.6 ng m?3, respectively; these values were far higher than those measured typically at most cities, e.g., 20–60 ng m?3. Seasonal patterns characterized by the peak occurrence in spring and the noticeable drop in summer reflected the effects of the massive PM inflow from China (spring) and effective washout by summer monsoon in East Asia, respectively. Examination of Mn data over a long-term period indicated that the temporal trends of Mn seen in most cities were fairly constant through time since the 1990s, although some abnormalities were observed in cities of strong man-made activities (e.g., Pohang and Wonju). In light of the severity of airborne Mn pollution in many urban areas, it is desirable to establish an abatement strategy that can help effectively reduce Mn levels.  相似文献   

2.
The distribution of environmental pollutant, sulphur, over Kano municipality was monitored on the basis of the chemical analysis of Scots Pine (Pinus sylvestris L.) needles collected from randomly selected sampling points over the period 1995–1996. Of the five zones in which the municipal area was subdivided, two could be regarded as least polluted, two as moderately polluted and one zone as heavily polluted. The mean value of all measurements in the metropolis amounted to 1940 gg–1 S with a co-efficient of variation of 38 percent.  相似文献   

3.
The present study was carried out to determine the impacts of SO2, NO x , SPM and RSPM, the most common air pollutants, generated mainly due to industries and vehicles, on some biochemical parameters and yield in wheat and mustard plants during 2006. The concentration of SO2, NO x , SPM and RSPM was determined at the polluted sites across the seasons, which ranged between 14.29–18.10, 20.81–22.43, 483.65–500.85 and 160.67–171.18 μg m−3, respectively. The wheat and mustard plants grown at polluted sites showed significant reduction in chlorophyll ‘a’, chlorophyll ‘b’, total chlorophyll, carotenoid, ascorbic acid, pH, relative water content and yield. The data were further analyzed using a two way ANOVA. It is concluded that the ambient air pollutants have a potential adverse impact on biochemical parameters, which further leads to a reduction in the yield of wheat and mustard crops.  相似文献   

4.
Lake Apopka in Florida, USA, is a large (area=124 km2), hypertrophic (mean total phosphorus=0.220 g/m3; mean chlorophylla=60 mg/m3) lake, with a large sedimentary store of available P (1635 × 106 g P). Phosphorus loading from floodplain farms (132 × 106 g P/yr) has been the primary cause of eutrophication. Assuming elimination of farm P loading, the Vollenweider model predicts a decline in equilibrium P concentration from 0.270 to 0.024 g/m3, if the P sedimentation coefficient (σ) remains constant. It is likely, however, that the value for σ will fall with the elimination of farm loading due to unabated internal P loading from the sediments. Under a worst-case scenario (σ=0), the model predicts that exportation of P from the lake via wetland filtration will greatly accelerate the lake's recovery. Recirculation of lake water through a 21-km2, created wetland and elimination of farm P loading is projected to result in a negative P balance for the lake (−23 × 106 g P/yr) leading to depletion of P stores in the lake in about 60 yr. The estimated cost of the project, $20 million, is less than 3% of the estimated cost of dredging. A 3.65-km2 demonstration project is underway to test and refine the wetland filtration technique. We believe the technique could be cost-effective for other hypertrophic lakes.  相似文献   

5.
Urbanization has a great impact on urban evapotranspiration. Water evaporation inside buildings is an important part of urban water vapor resources and a crucial core of urban hydrological processes. The systematic studies on building water evaporation (BWE) are mostly the method of experimental monitoring. This study proposed a new method to simulate and estimate water evaporation flux inside buildings in urban areas. Based on the nighttime light data and urban per capita gross domestic product (GDP), a new modeling system was built to simulate the total BWE. Building area was calculated using the nighttime light data. And the BWE coefficient Df was estimated according to the important indicator of economic development per capita GDP value. Then the water evaporation inside urban buildings and the spatial distribution of water evaporation inside buildings in typical cities could be obtained. The results showed that the total amount of water evaporation inside buildings in China's urban areas was 24.5 billion m3. Among the 31 provincial capitals in China, Shanghai had the largest BWE of 1.08 billion m3. The minimum water evaporation of buildings in Lhasa was 20.0 million m3. Studies of BWE can assess urban water budgets, support on-demand allocation of water resources, and provide a fundamental understanding of the relationship between water resources and energy heat island effects in urban areas.  相似文献   

6.
This study examined the relative influence of nutrients (nitrogen and phosphorus) and habitat on algal biomass in five agricultural regions of the United States. Sites were selected to capture a range of nutrient conditions, with 136 sites distributed over five study areas. Samples were collected in either 2003 or 2004, and analyzed for nutrients (nitrogen and phosphorous) and algal biomass (chlorophyll a). Chlorophyll a was measured in three types of samples, fine-grained benthic material (CHLFG), coarse-grained stable substrate as in rock or wood (CHLCG), and water column (CHLS). Stream and riparian habitat were characterized at each site. TP ranged from 0.004–2.69 mg/l and TN from 0.15–21.5 mg/l, with TN concentrations highest in Nebraska and Indiana streams and TP highest in Nebraska. Benthic algal biomass ranged from 0.47–615 mg/m2, with higher values generally associated with coarse-grained substrate. Seston chlorophyll ranged from 0.2–73.1 μg/l, with highest concentrations in Nebraska. Regression models were developed to predict algal biomass as a function of TP and/or TN. Seven models were statistically significant, six for TP and one for TN; r 2 values ranged from 0.03 to 0.44. No significant regression models could be developed for the two study areas in the Midwest. Model performance increased when stream habitat variables were incorporated, with 12 significant models and an increase in the r 2 values (0.16–0.54). Water temperature and percent riparian canopy cover were the most important physical variables in the models. While models that predict algal chlorophyll a as a function of nutrients can be useful, model strength is commonly low due to the overriding influence of stream habitat. Results from our study are presented in context of a nutrient-algal biomass conceptual model.  相似文献   

7.
The relationship between specific particulate emission control and ambient levels of some PM10 components (Zn, As, Pb, Cs, Tl) was evaluated. To this end, the industrial area of Castellón (Eastern Spain) was selected, where around 40% of the EU glazed ceramic tiles and a high proportion of EU ceramic frits are produced. The PM10 emissions from the ceramic processes were calculated over the period 2000–2006, taking into account the degree of implementation of corrective measures throughout the study period. Abatement systems were implemented in the majority of the fusion kilns for frit manufacture in the area as a result of the application of the Directive 1996/61/EC, leading to a marked decrease in PM10 emissions. By contrast, emissions from tile manufacture remained relatively constant because of the few changes in the implementation of corrective measures. On the other hand, ambient PM10 levels and composition measurements were carried out from 2002 to 2006. A high correlation between PM10 emissions from frit manufacture and ambient levels of Zn, As, Pb and Cs (R2 from 0.61 to 0.98) was observed. On the basis of these results, the potential impact of the implementation of corrective measures to reduce emissions from tile manufacture was quantified, resulting in a possible decrease of 3–5 μg/m3 and 2 μg/m3 in ambient mineral PM10 (on an annual basis) in urban and suburban areas, respectively. This relatively simple methodology allows us to estimate the direct effect of a reduction in primary particulate emissions on ambient levels of key particulate components, and to make a preliminary quantification of the possibilities of air quality improvement by means of further emission reduction. Therefore, it is a useful tool for developing future air quality plans in the study area and in other industrialised areas.  相似文献   

8.
Here we report N2O emission results for freshwater marshes isolated from human activities at the Sanjiang Experimental Station of Marsh Wetland Ecology in northeastern China. These results are important for us to understand N2O emission in natural processes in undisturbed freshwater marsh. Two adjacent plots of Deyeuxia angustifolia freshwater marsh with different water regimes, i.e., seasonally waterlogged (SW) and not- waterlogged (NW), were chosen for gas sampling, and soil and biomass studies. Emissions of N2O from NW plots were obviously higher than from the SW plots. Daily maximum N2O flux was observed at 13 o′clock and the seasonal maximum occurred in end July to early August. The annual average N2O emissions from the NW marsh were 4.45 μg m−2 h−1 in 2002 and 6.85 μg m−2 h−1 in 2003 during growing season. The SW marsh was overall a sink for N2O with corresponding annual emissions of −1.00 μg m−2 h−1 for 2002 and −0.76 μg m−2 h−1 for 2003. There were significant correlations between N2O fluxes and temperatures of both air and 5-cm-depth soil. The range of soil redox potential 200–400 mV appeared to be optimum for N2O flux. Besides temperature and plant biomass, the freeze–thaw process is also an important factor for N2O emission burst. Our results show that the freshwater marsh isolated from human activity in northeastern China is not a major source of N2O.  相似文献   

9.
For this study, particulates or particulate matter (PM) and carbon monoxide (CO) levels were monitored at different sections on the production floor of a scrap metal recycling factory. A Met‐One GT331 dust monitor and A Toxi‐Rae gas monitor were used to measure PM and CO concentrations, respectively. The 24‐hr averaging period concentrations of particulate matter having diameters of 2.5 microns or less in diameter (PM2.5), particulate matter having diameters of 10 microns or less in diameter (PM10), and total suspended particulates (TSP) within the plant ranged between 8.3 and 50.4 μg/m3, 12.0 and 151.3 μg/m3, and 30.0 and 285.0 μg/m3, respectively, while the maximum 8‐hr concentration of CO within the plant was 20.5 parts per million (ppm). The United States’ Environmental Protection Agency (US EPA) limits for PM2.5, PM10, and CO were exceeded only in the area around the furnace. Nigeria's Federal Ministry of Environment (FMENV), the World Health Organization (WHO), and the World Bank statutory limit for TSP were also exceeded in the area around the furnace. Toxicity potentials (TP) of the investigated pollutants were greater than 1.0 around the furnace, indicating that work spaces in proximity to the furnace could expose workers to adverse health conditions.  相似文献   

10.
Nine heavy metals were estimated in lichen, Phaeophyscia hispidula (Ach.) Moberg, collected from 12 different sites of Dehradun, capital city, to analyze the air quality of Uttarakhand. Total metal concentration was the highest at Mohkampur Railway Crossing, Hardwar Road (42,505 μg g−1). Dela Ram Chowk, located in the center of the city, also had higher metal concentration, 34,317 μg g−1, with maximum concentration of Pb at 12,433 μg g−1, while Nalapani forest area had minimum total metal concentration (1,873 μg g−1) as well as minimum Pb level at 66.6 μg g−1, indicating anthropogenic activity, mainly vehicular activity, responsible for the increase in metal concentration in the ambient environment. In comparison with the earlier years 2004 and 2006, air pollution as indicated by similar lichen shows a considerable increase in the total metal concentration (especially Pb) in the ambient air of Dehradun city, which may be attributed to exponential rise in the traffic activity in the last 5 years.  相似文献   

11.
The relationship between nutrient removal and loading rate was examined using data from five forested wetlands in Louisiana that have received secondarily treated effluent from 3 to 60 years. Loading rates ranged from 0.65 to 26.80 g/m2/yr for total nitrogen and 0.18 to 8.96 g/m2/yr for total phosphorus. At loading rates below 20 g/m2/yr, total nitrogen concentrations in surface waters of Louisiana forested wetlands were reduced to background concentrations (i.e., ≤3 mg/l). Similarly, at loading rates below 2 g/m2/yr, total phosphorus concentrations were also generally reduced to background concentrations (i.e., ≤1 mg/l). These data demonstrate that freshwater forested wetlands can reduce nutrient concentrations in treated effluent to background concentrations present in relatively undisturbed wetlands. An understanding of the relationship between loading rates and nutrient removal in natural wetlands is important, particularly in Louisiana where discharges of fresh water are being used in ecosystem restoration.  相似文献   

12.
A data analysis of three major Korean cities was conducted to assess roadside inhalable particulate matter 10 μm or smaller in aerodynamic diameter (PM10), including temporal and meteorological variations, over a recent period of 4 to 6 years. The yearly roadside PM10 concentrations presented a well-defined increasing trend or no trend depending on the roadside monitoring station. Most mean values exceeded or approximated the Korean standard of 70 μg/m3 per year for PM10. A representative roadside diurnal trend was characterized by a distinct morning maximum. In most cases, the Sunday roadside concentrations were similar to or somewhat lower than the weekday concentrations, and the PM10 concentrations presented a well-defined seasonal variation, with the maximum concentration in March. The monthly maximum concentrations observed in March were most likely attributable to Asian dust storms. In two metropolitan cities (Seoul and Busan), the frequency of days with roadside PM10 concentrations exceeding the standard of 150μg/m3 per 24 h was much lower for the roadside monitoring stations than for the residential monitoring station, whereas in the third city (Daegu), this result was reversed. Interestingly, the average maximum concentrations observed for the roadside sites in Seoul and Busan during March were higher than those for the residential sites, suggesting that the roadside concentrations responded more to the dust storms than the residential areas. The relationship between the pollutant concentrations and five important meteorological parameters (solar radiation, wind speed, air temperature, relative humidity, and precipitation) showed that the number and type of meteorological variables included in the equations varied according to the monitoring station or season. Finally, the current results confirmed that attention should be given to the PM10 exposure of residents living near roadways.  相似文献   

13.
《环境质量管理》2018,27(4):155-162
Ambient air pollution by vehicular emissions is underestimated, especially in the major cities of Nigeria. The buildup of the emissions in the atmosphere is a major health concern. This study estimated the emissions of gaseous criteria air pollutants (CAPs) from the road transport system in the Lagos metropolis from the year 2004 to 2007. The study also determined the ground‐level concentrations of these pollutants for the years under review. Estimation of the emission rates of all types of vehicles was performed using an emission factor approach, while the ground‐level concentrations of the CAPs were determined using the Industrial Source Complex Short Term 3 view model. The results showed that the mean concentrations of carbon monoxide in the ambient air were 26,741.12, 31,675.95, 54,515.48, and 72,388.09 micrograms per cubic meter (μg/m3) for years 2004, 2005, 2006, and 2007, respectively, while the estimated concentrations for oxides of nitrogen were 1,377.91 μg/m3 for year 2004, and 1,620.76, 2,897.33, and 3,839.68 μg/m3, respectively, for the years 2005, 2006, and 2007. The estimated concentrations of sulfur dioxide during the study period were 51,354.16, 57,244.76, 113,083.26, and 136,332.01 μg/m3 for 2004, 2005, 2006, and 2007, respectively. For volatile organic compounds, the estimated concentrations were 3,839.68, 6,839.65, 7,067.62, and 8,431.35 μg/m3 for years 2004, 2005, 2006, and 2007, respectively. The results also show that the maximum ground‐level concentrations were highest along the roadside, and the average CAPs concentrations and cumulative exposure concentrations that were estimated throughout the study period are a major health concern, as these concentrations are several times higher than international limits.  相似文献   

14.
Crab samples, both male and female specie, were purchased from fishermen at the Ojo Rivers, Lagos, Nigeria. The samples separated into abdomen, muscle tissue, and thorax were oven dried at 80°C for 3 days. The dried samples were then pulverized in a clean acid-washed mortar and pestle. Approximately 1.00 g each of the pulverized samples was weighed and Zn, Cr, Pb, and Cd were determined in the solution of the aqua regia digested samples by means of AAS (Buck Scientific 210 GVP model). The results obtained showed Zn metal to be consistently higher in all the female parts compared to the male with values of 12.92 ± 3.65 μg/g to 16.03 ± 1.08 μg/g and 9.33 ± 1.77 μg/g to 15.75 ± 1.02 μg/g, respectively. Mean values of 0.39 ± 0.09 μg/g and 0.22 ± 0.02 μg/g cadmium were found in the abdomen and tissue of the male crab as against 0.35 ± 0.07 μg/g and 0.17 ± 0.07 μg/g in the female crab. The tissues of both species have comparable value of chromium. Lead was below the detection limit of 0.05 μg/g in the tissues of male crab but the female tissue contained 0.83 ± 0.13 μg/g and in other parts identified, lead was consistently higher than the 2.00 μg/g permissible level of WHO in foods. A simple pair t-test did not demonstrate any significant difference in the distribution of metals between the male and female crabs. The coefficient of variation (CV) calculated for each metal with respect to the studied parts showed Pb to be widely distributed (56.23–89.54%) while Cr did not vary widely (4.17–8.20%).  相似文献   

15.
The objective of this research was to determine the spatial distributions of childhood lead poisoning and soil lead contamination in urban Tijuana. The Bocco–Sanchez model of point-source emissions was evaluated in terms of validity and reliability. We compared the model's predicted vulnerable populations with observed cases of childhood lead poisoning in Tijuana, identified fixed point sources in the field, and analyzed 76 soil samples from 14 sites. The soil lead results were compared to the blood lead analyses performed on Tijuana children whose blood lead levels were ≥10 μg/dL, who reported that they did not use lead-glazed ceramics for cooking or storing food (n = 63). Using GIS, predicted vs observed risk areas were assessed by examining spatial patterns, including the distribution of cases per designated risk area. Chi-square analysis of expected vs observed values did not differ significantly at the p = 0.02 level, showing that the model was strikingly accurate in predicting the distribution of subjects with elevated blood lead. Results reveal that while point sources are significant, other sources of lead exposure are also important. The relative public health risk from exposure to lead in an urban setting may be assessed by distinguishing among sources of exposure and associating concentrations to blood lead levels. The results represent an iterative approach in environmental health research by linking environmental and human biomarker lead concentrations and using these results to validate an environmental model of risk to lead exposure.  相似文献   

16.
Samples of some popular brands of canned sardines in soybean oil in the Nigerian market were analyzed for levels of cadmium, lead, iron, cobalt, nickel, manganese, chromium, copper and zinc after wet digestion with acids by graphite furnace atomic absorption spectrophotometry. The mean concentrations for the metals in the different brands were as follows: cadmium 0.11–0.26 μg/g, iron 8.04–48.18 μg/g, cobalt 0.01–7.23 μg/g, nickel 0.04–3.26 μg/g, manganese 0.64–1.37 μg/g, chromium 0.01–0.10 μg/g, copper 0.10 μg/g and zinc 0.09–4.63 μg/g. Significant differences were observed in the heavy metal levels in the different brands of canned sardines except for copper and chromium. Cadmium, nickel and lead exceeded statutory safe limits.  相似文献   

17.
Large scale rainwater harvesting (LSRWH) is a promising alternative to address security and flood issues in urban areas. The development and planning of a LSRWH for an eco-community involves comprehensive site-planning, systems planning and design, which includes the rainwater source collection (roof) to the storage tank, the distribution and allocation system. This paper describes a new technique for designing a LSRWH for a community of 200 houses with an average of 4 persons per house and an average total daily water demand of 160 m3. It was found that the optimal size storage tank for a 20,000 m2 roof area is 160 m3 with a 60% reliability. The application of this model to the case study revealed a significant water saving up to 58% .The total cost for this system is 443,861 USD over a life-span of 25 years.  相似文献   

18.
Poor vegetation cover is generally considered to be a major factor causing soil erosion on the Loess Plateau in China. It has been argued that tree planting restoration is ineffective, and natural re-vegetation is an alternative ecological solution for restoring abandoned cropland and controlling soil erosion. The aims of this study were to investigate the characteristics of soil seed banks and to assess the natural restoration potential of abandoned cropland in the hilly-gullied Loess Plateau. The soil seed bank was identified by the germination method with the soil samples, which were collected at four sampling times (April, August, and October 2005 and August 2006) from 12 plots abandoned 3–30 years prior to sampling. The seed bank densities of all of the samples in the 0–10 cm soil layer varied from 1,067 ± 225 to 14,967 ± 1,606 seeds m−2. Fifty-one species (24 annual and 27 perennial species) belonging to 18 families were identified, and 39% of these species belonged to the families Compositae and Gramineae. The pioneer species Artemisia scoparia dominated the seed bank, with an average seed density of 3,722 seeds m−2, and accounted for 74.4% of the seeds in the bank. The local dominant species (such as Lespedeza davurica, Artemisia gmelinii, Bothriochloa ischaemun and Stipa bungeana) of the later succession stages also existed at densities varying from 17 to 1, 383 seeds m−2. The combination of soil seed bank characteristics, reproductive traits of the species, the specific landscape conditions indicates that the potential to restoring the abandoned croplands in the hilly-gullied Loess Plateau via natural re-vegetation could be substantial.  相似文献   

19.
Urban forests are popular recreation areas in Europe. Several of these temperate broad-leaved forests also have a high conservation value due to sustainable management over many centuries. Recreational activities, particularly the use of fireplaces, can cause extensive damage to soil, ground vegetation, shrubs, and trees. Firewood collection depletes woody debris, leading to a loss of habitat for specialized organisms. We examined the effects of fireplace use on forest vegetation and the amount of woody debris by comparing disturbed and control plots in suburban forests in northwestern Switzerland. At frequently used fireplaces, we found reduced species densities in the ground vegetation and shrub layer and changes in plant species composition due to human trampling within an area of 150–200 m2. Picnicking and grilling also reduced the height and changed the age structure of shrubs and young trees. The amount of woody debris was lower in disturbed plots than in control plots. Pieces of wood with a diameter of 0.6–7.6 cm were preferentially collected by fireplace users. The reduction in woody debris volume extended up to a distance of 16 m from the fire ring, covering an area of 800 m2 at each picnic site. In order to preserve the ecological integrity of urban forests and to maintain their attractiveness as important recreation areas, we suggest depositing logging residues to be used as firewood and to restrict visitor movements near picnic sites.  相似文献   

20.
Logging has been a much maligned feature of frontier development in the Amazon. Most discussions ignore the fact that logging can be part of a renewable, environmentally benign, and broadly equitable economic activity in these remote places. We estimate there to be some 4.5 ± 1.35 billion m3 of commercial timber volume in the Brazilian Amazon today, of which 1.2 billion m3 is currently profitable to harvest, with a total potential stumpage value of $15.4 billion. A successful forest sector in the Brazilian Amazon will integrate timber harvesting on private lands and on unprotected and unsettled government lands with timber concessions on public lands. If a legal, productive, timber industry can be established outside of protected areas, it will deliver environmental benefits in synergy with those provided by the region’s network of protected areas, the latter of which we estimate to have an opportunity cost from lost timber revenues of $2.3 billion over 30 years. Indeed, on all land accessible to harvesting, the timber industry could produce an average of more than 16 million m3 per year over a 30-year harvest cycle—entirely outside of current protected areas—providing $4.8 billion in returns to landowners and generating $1.8 billion in sawnwood sales tax revenue. This level of harvest could be profitably complemented with an additional 10% from logging concessions on National Forests. This advance, however, should be realized only through widespread adoption of reduced impact logging techniques.  相似文献   

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